期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 3, 页码 790-793出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b12579
关键词
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资金
- EPSRC
- Leverhulme Trust
- EPSRC [EP/M005062/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/M005062/1] Funding Source: researchfish
A metal-free CH-CH-type coupling of arenes and alkynes, mediated by a multifunctional sulfoxide directing group, exploits nonprefunctionalized coupling partners, proceeds under mild conditions, is operationally simple, and exhibits high functional group tolerance. The products of the CH-CH coupling are highly versatile, and the metal-free process can be used for the construction and late-stage modification of important molecular scaffolds.
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