期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 42, 页码 13770-13773出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05482
关键词
-
资金
- KAUST
Thiols and phosphines are the most widely used organic ligands to attain atomically precise metal nanoclusters (NCs). Here, we used simple hydrides (e.g., H-) as ligands along with phosphines, such as triphenylphosphine (TPP), 1,2-bis(diphenylphosphino)ethane [DPPE], and tris(4-fluorophenyl)phosphine [TFPP] to design and synthesize a new class of hydride-rich silver NCs. This class includes [Ag18H16(TPP)(10)](2+), [Ag25H22(DPPE)(8)](3+), and [Ag26H22(TFPP)(13)](2+). Our work reveals a new family of atomically precise NCs protected by H- ligands and labile phosphines, with potentially more accessible active metal sites for functionalization and provides a new set of stable NC sizes with simpler ligand-metal bonding for researchers to explore both experimentally and computationally.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据