期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 20, 页码 6416-6419出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b03931
关键词
-
资金
- NIH [F32-GM109569, R01-GM100143]
A modular Cu/ABNO catalyst system has been identified that enables efficient aerobic oxidative coupling of alcohols and amines to amides. All four permutations of benzylic/aliphatic alcohols and primary/secondary amines are viable in this reaction, enabling broad access to secondary and tertiary amides. The reactions exhibit excellent functional group compatibility and are complete within 30 min-3 h at rt. All components of the catalyst system are commercially available.
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