期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 32, 页码 10104-10107出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b06185
关键词
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资金
- 973 Program [2014CB845605, 2013CB933200]
- NSFC [21521061, 21331006, 21273238]
- Chinese Academy of Sciences [XDB20000000]
- Youth Innovation Promotion Association, CAS [2014265]
- Chunmiao Project of the Haixi Institute of the Chinese Academy of Sciences [CMZX-2014-004]
Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) With high metal loadings. The solubility of the composite and the size of the MNPs can be controlled by varying the ratio of the precursors to the supports. The soluble PCPs can serve as a platform to homogenize heterogeneous MNPs catalysts, which exhibited excellent activity and recyclability in C -H activation and Suzuki reactions. This strategy combines the advantages of homogeneous and heterogeneous catalysis and may bring new inspiration to catalysis.
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