期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 28, 页码 8781-8788出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b03439
关键词
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资金
- Federal Ministry of Education and Research (BMBF)
- State of Mecklenburg-Vorpommern
Novel heterogeneous cobalt-based catalysts have been prepared by pyrolysis of cobalt complexes with nitrogen ligands on different inorganic supports. The activity and selectivity of the resulting materials in the hydrogenation of nitriles and carbonyl compounds is strongly influenced by the modification of the support and the nitrogen-containing ligand. The optimal catalyst system ([Co(OAc)(2)/Phen@alpha-Al2O3]-800 = Cat. E) allows for efficient reduction of both aromatic and aliphatic nitriles including industrially relevant dinitriles to primary amines under mild conditions. The generality and practicability of this system is further demonstrated in the hydrogenation of diverse aliphatic, aromatic, and heterocyclic ketones as well as aldehydes, which are readily reduced to the corresponding alcohols.
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