期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 11, 页码 3671-3674出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b01428
关键词
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资金
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319, CTQ2013-42106-P]
- European Research Council [321066]
- AGAUR [2014 SGR 818]
- ICIQ Foundation
- COFUND postdoctoral fellowship (Marie Curie program)
The total synthesis of lundurines A-C has been accomplished in racemic and enantiopure forms in 11-13 and 12-14 steps, respectively, without protection/deprotection of functional groups, by a novel tandem double condensation/Claisen rearrangement, a gold(I)-catalyzed alkyne hydroarylation, a cyclopropanation-via formal [3 + 2] cycloaddition/nitrogen extrusion, and a remarkable olefin migration through a vinylcyclopropane retro-ene/ene reaction that streamlines the endgame.
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