期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 39, 页码 12751-12754出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b08100
关键词
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资金
- MOST of China [2015CB932303]
- NNSF of China [21420102001, 21131005, 21390390, 21227001, 21333008]
- iChEM, Xiamen University
- Academy of Finland [266492, 294217]
In this work, a facile ion-pairing strategy for asymmetric synthesis of optically active negatively charged chiral metal nanoparticles using chiral ammonium cations is demonstrated. A new thiolated chiral three-concentric shell cluster, [Ag28Cu12(SR)(24)](4-), was first synthesized as a racemic mixture and characterized by single-crystal X-ray structure determination. Mass spectrometric measurements revealed relatively strong ion-pairing interactions between the anionic nanocluster and ammonium cations. Inspired by this observation, the as-prepared racemic mixture was separated into enantiomers by employing chiral quaternary ammonium salts as chiral resolution agents. Subsequently, direct asymmetric synthesis of optically active enantiomers of [Ag28Cu12(SR)(24)](4-) was achieved by using appropriate chiral ammonium cations (such as N-benzylcinchoninium vs N-benzylcinchonidinium) in the cluster synthesis. These simple strategies, ion pairing enantioseparation and direct asymmetric synthesis using chiral counterions, may be of general use in preparing chiral metal nanoparticles.
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