期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 13, 页码 4354-4357出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b01970
关键词
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资金
- CREST, JST
Photocatalytic systems developed from complexes with only abundant metals, i.e., Cu-I(dmp)(P)(2)(+) (dmp = 2,9-dimethyl-1,10-phenanthroline; P = phosphine ligand) as a redox photosensitizer and Fe-II(dmp)(2)(NCS)(2) as a catalyst, produced CO as the main product by visible light irradiation. The best photocatalysis was obtained using a Cu-I complex with a tetradentate dmp ligand tethering two phosphine groups, where the turnover number and quantum yield of CO formation were 273 and 6.7%, respectively.
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