期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 20, 页码 6662-6669出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b03686
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资金
- MEXT [24109012, 26288019]
- Research Grants Council of Hong Kong [HKUST603313, CUHK7/CRF/12G]
- CREST from JST
- Science Research Promotion Fund
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [26288019, 24109012] Funding Source: KAKEN
In the absence of transition metal catalysts, the unsymmetrical diborane(4), pinB-BMes(2), reacted with alkynes to afford diborylalkenes. The isomer ratio of the products could be controlled via temperature, solvent, and additive(s). A reaction mechanism was proposed on the basis of two isolated intermediates, and this reaction could furthermore be applied to synthesize a luminescent molecule.
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