期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 38, 页码 12348-12351出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b07984
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资金
- National NSF of China [21172062, 21273066, 21273067, 21573065]
- NSF of Hunan Province [2016JJ1017]
A Cu-catalyzed selective aerobic heterocoupling of terminal alkynes is disclosed, which enables the synthesis of a broad range of unsymmetrical 1,3-diynes in good to excellent yields. The results disprove the long-held belief that homocouplings are exclusively favored in the GlaserHay reaction.
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