期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 39, 页码 12763-12766出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b08104
关键词
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资金
- Royal Society
- Leverhulme Trust [RPG-2015-248]
- ERC [FluorFix: 677367]
Addition of the carbon-fluorine bond of a series of perfluorinated and, polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.
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