期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 20, 页码 6571-6576出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b02372
关键词
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资金
- Singapore National Research Foundation [R-143-000-477-281, R-143-000-606-281]
- Ministry of Education (MOE) of Singapore [R-143-000-613-112]
We present here an unprecedented cobalt-catalyzed enantioselective vinylation of alpha-ketoesters, isatins, and imines to deliver a range of synthetically useful allylic alcohols and amines in high enantiopurity. This method employs commercially available and easy to handle catalysts and reagents and exhibits a high degree of practicality. The efficiency, selectivity, and operational simplicity of this catalytic system coupled with the substrate generality render this method a valuable tool in organic synthesis.
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