期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 27, 页码 8356-8359出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b04232
关键词
-
资金
- NSF [CHE-1359809]
- Alexander von Humboldt foundation
- Keck Foundation
A room-temperature stable (phosphino)phosphinidene reacts with carbon monoxide, stable singlet carbenes, including the poor pi-accepting imidazol-2-ylidene, and phosphines giving rise to the corresponding phosphaketene, phosphinidene-carbene and phosphinidene-phosphine adducts, respectively. Whereas the electronic ground-state calculations indicate a PP multiple bond character in which the terminal phosphorus is negatively charged, the observed reactivity clearly indicates that (phosphino)phosphinidenes are electrophilic as expected for an electron-deficient species. This is further demonstrated by competition experiments as well as by the results of Fukui function calculations.
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