期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 13, 页码 4298-4301出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b13519
关键词
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资金
- Israel Science Foundation
- MINERVA Foundation
- Kimmel Center for molecular design
- Planning and Budgeting Committee (PBC) of the Council for Higher Education in Israel
The catalytic dehydrogenative coupling of alcohols and amines to form aldimines represents an environmentally benign methodology in organic chemistry. This has been accomplished in recent years mainly with precious-metal-based catalysts. We present the dehydrogenative coupling of alcohols and amines to form imines and H-2 that is catalyzed, for the first time, by a complex of the earth-abundant Mn. Detailed mechanistic study was carried out with the aid of NMR spectroscopy, intermediate isolation, and X-ray analysis.
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