期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 8, 页码 2480-2483出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b11311
关键词
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资金
- CREST, JST
- Grants-in-Aid for Scientific Research [24685011, 15K21222] Funding Source: KAKEN
A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >10(3)) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.
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