期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 25, 页码 7856-7859出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b04538
关键词
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资金
- National Natural Science Foundation of China [11190023, 90922002]
- Fundamental Research Funds for the Central Universities of China
We report the synthesis, crystal structure, and physical properties of a quinary iron arsenide fluoride, KCa2Fe4As4F2. The new compound crystallizes in a body centered tetragonal lattice (space group I4/mmm, a = 3.8684(2) angstrom, c = 31.007(1) angstrom, Z = 2) that contains double Fe2As2 conducting layers separated by insulating Ca2F2 layers. Our measurements of electrical resistivity, direct current magnetic susceptibility, and heat capacity demonstrate bulk superconductivity at 33 K in KCa2Fe4As4F2.
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