期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 38, 页码 12316-12319出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b06847
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资金
- School of Physical Sciences at the University of California Irvine
- Chao Family Comprehensive Cancer Center
- National Science Foundation [DGE-1321846]
A catalytic formal ene reaction between ketone-derived silyl enol ethers and terminal alkynes is described. This transformation is uniquely capable of bimolecular assembly of 2-siloxy-1,4-dienes and can be used to access beta,gamma-unsaturated ketones containing quaternary carbons in the alpha-position
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