期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 9, 页码 2885-2888出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b10945
关键词
-
资金
- National NSF of China [21432005, 21321061]
We have disclosed for the first time the copper-promoted C equivalent to N triple bond cleavage of coordinated cyanide anion under a dioxygen atmosphere, which enables a nitrogen transfer to various aldehydes. Mechanistic study of this unprecedented transformation suggests that the single electron-transfer process could be involved in the overall course. This protocol provides a new cleavage pattern for the cyanide ion and would eventually lead to a more useful synthetic pathway to nitriles from aldehydes.
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