☆ 4.7 Review

Recent Developments in Selenylation and Thiolation of Alkenes via Three-component Reactions

ADVANCED SYNTHESIS & CATALYSIS (2023)

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Photoinduced Vicinal 1,2-Difunctionalization of Olefins for the Synthesis of Alkyl Sulfonamides

Anasheh Sookezian et al.

Summary: Alkyl sulfonamides are important bioactive molecules. Traditional syntheses usually require multiple steps and harsh reaction conditions. Photochemical methods have been limited in terms of the number of substituents that can be introduced onto an olefin. However, a new radical/polar crossover (RPC) method is introduced in this study, which allows for the first multicomponent 1,2-difunctionalization reaction with a sulfonamide moiety and a second reaction partner. This protocol, demonstrated on various olefins, employs different commercial sulfamoyl chlorides and organotrifluoroborates as coupling partners.

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Three-Component Oxychalcogenation of Alkenes under Metal-Free Conditions: A Tetrabutylammonium Tribromide-Catalyzed System

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Summary: A three-component oxychalcogenation reaction is achieved in this study, using alkenes, diselenides/thiophenols, and H2O/alcohols as reactants. Tetrabutylammonium tribromide (TBATB) and dimethylsulfoxide (DMSO) are employed as the catalyst and terminal oxidant, respectively, enabling the difunctionalization transformation. This metal-free reaction system shows excellent functional group compatibility and provides a unified and practical approach to access beta-hydroxyl or beta-alkoxy organochalcogenides.

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The Shuttle of Sulfur Dioxide: Iridium/Copper‐Cocatalyzed Trifluoromethylfluorosulfonylation of Alkenes

Yi‐Fei Yang et al.

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Article Chemistry, Multidisciplinary

Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes

Yi Yu et al.

Summary: Both sulfur and fluorine play crucial roles in organic synthesis, the life science, and materials science. This study presents a highly selective electrochemical vicinal fluorosulfenylation and fluorosulfoxidation reactions of alkenes, made possible by the precise control of electrode potential. Preliminary mechanistic investigations reveal that the fluorosulfenylation reaction proceeds through a radical-polar crossover mechanism involving an episulfonium ion intermediate. Subsequent electrochemical oxidation easily converts fluorosulfides to fluorosulfoxides under higher applied potential in the presence of adventitious H2O.

CHINESE CHEMICAL LETTERS (2022)

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Article Chemistry, Multidisciplinary

Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal-Metallaaromatic Catalytic System

Fei-Hu Cui et al.

Summary: The design of organometallic catalysts plays a crucial role in the development of catalytic reactions. In this study, a heterometallic [Os-Cu] complex with characteristics of bimetallics, metal-laaromatics, and pincer complexes is described as a highly effective catalyst for selective amino- and oxyselenation of unactivated alkenes.

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Article Chemistry, Organic

Electrochemical fluorosulfonylation of alkenes to access vicinal fluorinated sulfones derivatives

Bin Zhao et al.

Summary: In this study, a practical and efficient method for fluorosulfonylation of various alkenes has been reported. This method uses sulfonyl radical sources and cost-effective fluorination reagents under mild conditions. The protocol is environmentally friendly, as it eliminates the need for chemical oxidants and transition metal catalysts, and it can tolerate different substituents, resulting in excellent synthesis yields.

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Sustainable Production of Bioactive Molecules from C-Lignin-Derived Propenylcatechol

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Summary: Catechyl lignin (C-lignin) is a promising biopolymer for the synthesis of bioactive molecules. Diversified transformations of propenylcatechol, a depolymerized product of C-lignin, were reported, resulting in the preparation of functional molecular skeletons for pharmaceuticals and bioactive molecules. The study demonstrated the low carbon footprint and high-quality production of bioactive molecules from C-lignin.

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Summary: The transformation of carbon monoxide and ethylene into high value-added chemicals, particularly multifunctionalized compounds, is economically significant. A palladium-catalyzed thiocarbonylative 1,2-difunctionalization of ethylene was developed, resulting in successful conversion of organic disulfides into beta-thiopropionate thioesters with good yields.

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Article Chemistry, Organic

Visible-Light-Induced Three-Component Selenofunctionalization of Alkenes: An Aerobic Selenol Oxidation Approach

Dilip Patil et al.

Summary: A photocatalyst-free visible-light-induced selenofunctionalization method for alkenes has been developed using various nucleophiles. The homolytic scission of diselenides under visible-light conditions and the aerobic selenol oxidation to diselenides enable the successful implementation of a three-component selenofunctionalization under visible light irradiation in open-air conditions. Mechanistic studies have revealed the crucial role of oxygen content in the reaction medium, controlling the electron transfer process from carbon-based radicals to either molecular oxygen or selenyl radicals.

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Synthesis of β-Arylseleno Sulfoximines: A Metal-Free Three-Component Reaction Mediated by Tetrabutylammonium Tribromide

Xiaoman Li et al.

Summary: In this study, a tetrabutylammonium tribromide-mediated three-component reaction of alkenes, diselenides, and sulfoximines was established, providing a direct and metal-free access to diverse beta-arylseleno sulfoximine derivatives. This regioselective sulfoximido-selenization protocol proceeds efficiently under mild and ambient conditions with generally good yields. The strategy is characterized by step and atom economy, practicability, a broad substrate scope, and gram-scale synthesis.

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Synthesis of ?-Thiolated-?-arylated Ketones Enabled by Photoredox and N-Heterocyclic Carbene-Catalyzed Radical Relay of Alkenes with Disulfides and Aldehydes

Hai-Wu Du et al.

Summary: A straightforward method to access beta-thiolated ketones from aldehydes, alkenes, and disulfides using the combination of photocatalysis and N-heterocyclic carbene catalysis is reported. The sequential radical addition to alkenes and subsequent radical-radical coupling cascade process simultaneously forge C-S and C-C bonds. The method exhibits a broad functional group tolerance.

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Photoredox and Copper-Catalyzed Sulfonylphosphorothiolation of Alkenes toward β-Sulfonyl Phosphorothioates

Pengbo Zhang et al.

Summary: A photoredox and copper-catalyzed sulfonylphosphorothiolation of alkenes has been developed, allowing the synthesis of a wide range of decorated beta-sulfonyl phosphorothioates. The reaction shows good functional group tolerance and can be conveniently used for late-stage modification of bioactive molecules and gram-scale synthesis.

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Summary: An environmentally friendly and efficient electrochemical fluoroselenation reaction of olefins has been developed, allowing for the ready synthesis of a diverse array of beta-fluoroselenides. The reaction conditions are mild, tolerating a wide range of substrates in excellent yields and selectivity, and can be easily extended to gram-scale preparation of vicinal fluoroselenides.

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You-Qin Jiang et al.

Summary: This study reports the intermolecular carboselenenylation of easily accessible alkenes using diselenides and N-fluorobenzenesulfonimide (NFSI) under metal-free and mild conditions. Preliminary mechanistic studies demonstrate that the oxidation of diselenide by NFSI generates an active selenenyl cationic radical species through a single electron-transfer process, initiating the intermolecular carboselenenylation of olefins and forming key Se-C and C-C bonds. Under optimized conditions, a wide range of structurally and functionally diverse selenoether derivatives can be obtained with high yields.

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Light-Induced Iron-Catalyzed Trifluoromethylative Thiolation of Alkenes

Xiaonan Zhang et al.

Summary: A series of novel trifluoromethylative thiolation reactions were successfully achieved using visible light and iron salts as catalysts, resulting in moderate to good yields of 1,2-bis(trifluoromethylated) compounds. These reactions proceed in an atom-economical manner with a broad substrate scope, and are tolerant of biologically active chemicals, making them potentially useful for late-stage modification in pharmaceutical discovery. Additionally, the desired products were successfully synthesized on a gram scale using flow-setup synthesis, demonstrating the synthetic power of these reactions in industrial applications.

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Recent Advances in Light-Induced Selenylation

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Tarik Hafdhi Abdtawfeeq et al.

Summary: This review discusses recent developments in the direct selenosulfonylation of unsaturated compounds, which can form two new carbon-sulfur and carbon-selenium bonds in a single operation. The reactions are classified based on the type of starting unsaturated compound and product, leading to three main sections on the selenosulfonylation of alkenes, alkynes, and allenes.

RSC ADVANCES (2022)

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Review Chemistry, Organic

Recent advances in thiolation via sulfur electrophiles

Ya-Feng Wei et al.

Summary: Umpolung of thiols has become a common strategy for the synthesis of S-containing compounds. Various sulfur electrophiles have been designed and applied for thiolation reactions. New catalyst systems and methodologies have been developed to meet different demands for regio- and stereoselectivity.

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Yi Yu et al.

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Electrochemical multi-component reaction of potassium metabisulfite with alkenes and alcohols enabling synthesis of sulfonate esters

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Radical Aminoselenation of Styrenes: Facile Access to β-Amido-selenides

Yin Yifan et al.

Summary: An efficient protocol for intermolecular amidoselenation of alkenes using diphenyl diselenides and alkyl amines has been developed, yielding a series of beta-amido-selenides in high yields under copper salt and PIDA conditions. Preliminary experimental results supported the involvement of active selenide radical species, suggesting a radical pathway for the reaction.

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Oxy- and aminoselenation of alkenes utilizing an isolable selenenyl iodide

Satoru Kuwano et al.

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Xin Zhang et al.

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Electrophilic Thiocyanato Reagent Assisted Oxa-Michael/Thiocyanation of α,β-Unsaturated Ketones

Zhenda Fu et al.

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Electrochemical Radical Selenylation of Alkenes and Arenes via Se-Se Bond Activation

Li Sun et al.

Summary: A novel electrochemical radical selenylation reaction was reported for the transformation of alkenes and activated arenes without the need for external oxidants. This method successfully yielded a variety of selenoethers with potential applications in biological chemistry, showcasing regioselectivity and atom-economic features.

ORGANIC LETTERS (2021)

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Copper and Photocatalytic Radical Relay Enabling Fluoroalkylphosphorothiolation of Alkenes: Modular Synthesis of Fluorine-Containing S-Alkyl Phosphorothioates and Phosphorodithioates

Pengbo Zhang et al.

Summary: A photoredox and copper-catalyzed fluoroalkylphos-phorothiolation of activated and unactivated alkenes was reported, allowing the construction of a wide variety of S-alkyl phosphorothioates and phosphorodithioates under mild conditions with good functional group tolerance. This modular reaction system was also successfully applied to the late-stage functionalization of bioactive molecules.

ORGANIC LETTERS (2021)

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Iodosobenzene-Mediated Three-Component Selenofunctionalization of Olefins

Zhi-Peng Liang et al.

Summary: A three-component reaction using a commercially available hypervalent iodine(III) reagent, PhIO, was developed for the synthesis of vicinally functionalized selenoderivatives under ambient conditions with excellent yields and high diastereoselectivity. The reaction displayed high levels of functional group compatibility and is suitable for late-stage functionalization of styrenefunctionalized biomolecules. Preliminary investigations on the mechanism of the reaction were also presented.

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Chiral Selenide-Catalyzed, Highly Regio- and Enantioselective Intermolecular Thioarylation of Alkenes with Phenols

Yuanyuan Zhang et al.

Summary: The enantioselective electrophilic three-component thioarylation of alkenes using chiral selenide catalysis with free phenols as arylating sources has been disclosed. Various chiral phenols were obtained in high regio-, enantio-, and diastereoselectivities. Mechanistic studies showed that the transformation proceeded through carbon nucleophilic attack to give the products rather than the intramolecular rearrangement of phenolic ether intermediates.

ACS CATALYSIS (2021)

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Recent Advances in Multicomponent Reactions with Organic and Inorganic Sulfur Compounds

Qinqin Tang et al.

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t-BuOK-promoted methylthiolation of aryl fluorides with dimethyldisulfide under transition-metal-free and mild conditions

Dayun Huang et al.

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SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Transition-Metal-Free Intermolecular Chlorodifluoromethylthiolation of Alkenes and Alkynes

Wan-Qiang Yuan et al.

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Chao Xu et al.

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Zhan-Yong Wang et al.

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Chao Xu et al.

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ACS APPLIED BIO MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Diamine-mediated N-2-selective beta-selenoalkylation of triazoles with alkenes

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CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Organic

Electrochemical Aminoselenation and Oxyselenation of Styrenes with Hydrogen Evolution

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ORGANIC LETTERS (2019)

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Article Chemistry, Organic

Copper-Catalyzed Synthesis of S-Aryl Dithiocarbamates from Tetraalkylthiuram Disulfides and Aryl Iodides in Water

Xiang-mei Wu et al.

SYNLETT (2019)

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Article Chemistry, Physical

Enantioselective Construction of Chiral Sulfides via Catalytic Electrophilic Azidothiolation and Oxythiolation of N-Allyl Sulfonamides

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ACS CATALYSIS (2019)

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Article Nanoscience & Nanotechnology

Multifunctional S-Nitroso-N-acetylpenicillamine-Incorporated Medical-Grade Polymer with Selenium Interface for Biomedical Applications

Arnab Mondal et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Enantioselective, Lewis Base-Catalyzed, Intermolecular Sulfenoamination of Alkenes

Aaron Roth et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Organic

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Bradley B. Gilbert et al.

TETRAHEDRON (2019)

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Article Chemistry, Organic

Copper-Catalyzed Regioselective Aminothiolation of Aromatic and Aliphatic Alkenes with N-Fluorobenzenesulfonimide and Thiols through Three-Component Radical Coupling

Masayuki Iwasaki et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Catalytic, Enantioselective syn-Diamination of Alkenes

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Organic

Photoredox-Catalyzed Intermolecular Radical Arylthiocyanation/Arylselenocyanation of Alkenes: Access to Aryl-Substituted Alkylthiocyanates/Alkylselenocyanates

Injamam Ul Hogue et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

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Review Chemistry, Organic

Synthetic Approaches to Organoselenium Derivatives with Antimicrobial and Anti-Biofilm Activity

Iris Di Leo et al.

MINI-REVIEWS IN ORGANIC CHEMISTRY (2019)

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Review Chemistry, Applied

Stereoselective Haliranium, Thiiranium and Seleniranium Ion-Triggered Friedel-Crafts-Type Alkylations for Polyene Cyclizations

Biswajit Maji

ADVANCED SYNTHESIS & CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Three- component difluoroalkylation- thiolation of alkenes by iron- facilitated visible- light photoredox catalysis

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CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Organic

Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes

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JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Organic

Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate

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JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Organic

Fe2O3-Promoted Intermolecular Chlorotrifluoromethylthiolation of Alkenes

Yimin Jia et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Organic

Copper-Catalyzed Oxidative Trifunctionalization of Olefins: An Access to Functionalized beta-Keto Thiosulfones

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JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Copper-mediated sulfonylation of aryl iodides and bromides with arylsulfonyl hydrazides in PEG-400

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NEW JOURNAL OF CHEMISTRY (2018)

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Article Chemistry, Organic

Iodine-Mediated Vicinal Difunctionalization of Alkenes: A Convenient Method for Building C-Se and C-S Bonds

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SYNLETT (2018)

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Article Chemistry, Multidisciplinary

Engaging sulfinate salts via Ni/photoredox dual catalysis enables facile Csp2-SO2R coupling

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CHEMICAL SCIENCE (2018)

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Article Chemistry, Organic

Eco-Friendly Selenoamidation of Alkenes with Sulfamides and Organoseleniums: Rapid access to β-Amidoselenides

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ASIAN JOURNAL OF ORGANIC CHEMISTRY (2018)

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Review Chemistry, Multidisciplinary

Analysis of US FDA-Approved Drugs Containing Sulfur Atoms

Kevin A. Scott et al.

TOPICS IN CURRENT CHEMISTRY (2018)

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Review Chemistry, Multidisciplinary

Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

Guanyinsheng Qiu et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Chemistry, Organic

Copper-Catalyzed Synthesis of beta-Azido Sulfonates or Fluorinated Alkanes: Divergent Reactivity of Sodium Sulfinates

Yang Xiong et al.

ORGANIC LETTERS (2018)

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Article Chemistry, Organic

Oxidative radical phosphonotrifluoromethylthiolation of unactivated alkenes with alkyl phosphonate, silver(I) trifluoromethanethiolate and potassium persulfate

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TETRAHEDRON (2018)

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Article Chemistry, Organic

Ag-catalyzed sulfonylation-peroxidation of alkenes with sulfonyl hydrazides and T-hydro

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TETRAHEDRON LETTERS (2018)

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Article Chemistry, Organic

Direct halosulfenylation of benzo[b]furans: a metal-free synthesis of 3-halo-2-thiobenzo[b]furans

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ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

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Selenium-Containing Polymer@Metal-Organic Frameworks Nanocomposites as an Efficient Multiresponsive Drug Delivery System

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ADVANCED FUNCTIONAL MATERIALS (2017)

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Article Chemistry, Organic

Trifluoromethylselenolation and Fluoroalkylselenolation of Alkenes by Electrophilic Addition

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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

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Base-mediated tandem sulfonylation and oximation of alkenes in water

Bin Wang et al.

GREEN CHEMISTRY (2017)

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Article Chemistry, Organic

A novel metal-free amidosulfenylation of alkenes leading to β-azolyl sulfides

Kai Sun et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2017)

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Article Chemistry, Organic

Three-component difunctionalization of alkenes leading to β-acetamido sulfides and β-acetoxy sulfides

Dingyi Wang et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2017)

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Article Chemistry, Physical

Oxidative Alkene Functionalizations via Selenium-π-Acid Catalysis

Stefan Ortgies et al.

ACS CATALYSIS (2017)

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Article Chemistry, Organic

tert-Butyl nitrite-mediated vicinal sulfoximation of alkenes with sulfinic acids: a highly efficient approach toward α-sulfonyl ketoximes

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ORGANIC CHEMISTRY FRONTIERS (2017)

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Article Chemistry, Multidisciplinary

Visible-Light-Driven Iron-Promoted Thiocarboxylation of Styrenes and Acrylates with CO2

Jian-Heng Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Review Chemistry, Multidisciplinary

Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance

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CHEMICAL REVIEWS (2017)

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Article Chemistry, Multidisciplinary

Amidoselenation and Amidotelluration of Alkenes using Oxygen as Terminal Oxidant

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CHEMISTRY-AN ASIAN JOURNAL (2017)

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Article Chemistry, Applied

Catalyst-Free Isothiocyanatoalkylthiation of Styrenes with (Alkylthio)pyrrolidine-2,5-diones and Trimethylsilyl Isothiocyanate

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ADVANCED SYNTHESIS & CATALYSIS (2016)

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Article Chemistry, Applied

Iron-Catalyzed Azidoalkylthiation of Alkenes with Trimethylsilyl Azide and 1-(Alkylthio)pyrrolidine-2,5-diones

Jipan Yu et al.

ADVANCED SYNTHESIS & CATALYSIS (2016)

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Article Chemistry, Multidisciplinary

Peroxodisulfate-mediated selenoamination of alkenes yielding amidoselenide-containing sulfamides and azoles

Kai Sun et al.

CHEMICAL COMMUNICATIONS (2016)

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Review Chemistry, Medicinal

Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry

Minghao Feng et al.

CURRENT TOPICS IN MEDICINAL CHEMISTRY (2016)

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Article Chemistry, Organic

Three-component oxysulfenydation reaction: two simple and convenient approaches to β-alkoxy sulfides

Dingyi Wang et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2016)

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Article Chemistry, Organic

Metal-Free, DTBP-Mediated Methylthiolation of Arylboronic Acids with Dimethyldisulfide

Xiang-mei Wu et al.

SYNLETT (2016)

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Article Nanoscience & Nanotechnology

Donor-Acceptor Small Molecules for Organic Photovoltaics: Single-Atom Substitution (Se or S)

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ACS APPLIED MATERIALS & INTERFACES (2015)

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Review Chemistry, Inorganic & Nuclear

Organoselenium compounds as fluorescent probes

Snigdha Panda et al.

COORDINATION CHEMISTRY REVIEWS (2015)

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Article Chemistry, Medicinal

Selenoacyclovir and Selenoganciclovir: Discovery of a New Template for Antiviral Agents

Pramod K. Sahu et al.

JOURNAL OF MEDICINAL CHEMISTRY (2015)

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Article Chemistry, Organic

Catalytic Chalcogenylation under Greener Conditions: A Solvent-Free Sulfur- and Seleno-functionalization of Olefins via I2/DMSO Oxidant System

Andre A. Vieira et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

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Article Chemistry, Multidisciplinary

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

Zheliang Yuan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Chemistry, Organic

Nal-Mediated Acetamidosulphenylation of Alkenes with Nitriles as the Nucleophiles: A Direct Access to Acetamidosulfides

Yang Zheng et al.

ORGANIC LETTERS (2015)

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Article Chemistry, Organic

Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates

Zhaoli Liang et al.

ORGANIC LETTERS (2015)

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Article Chemistry, Organic

Copper Nanopowder Catalyzed Cross-Coupling of Diaryl Disulfides with Aryl Iodides in PEG-400

Xiang-mei Wu et al.

SYNLETT (2015)

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Review Chemistry, Multidisciplinary

Selenium- and Tellurium-Containing Fluorescent Molecular Probes for the Detection of Biologically Important Analytes

Sudesh T. Manjare et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

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Article Chemistry, Multidisciplinary

Visible light organophotoredox catalysis: a general approach to β-keto sulfoxidation of alkenes

Twinkle Keshari et al.

GREEN CHEMISTRY (2014)

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Article Neurosciences

Depression-related behavior and mechanical allodynia are blocked by 3-(4-fluorophenylselenyl)-2,5-diphenylselenophene in a mouse model of neuropathic pain induced by partial sciatic nerve ligation

Bibiana Mozzaquatro Gai et al.

NEUROPHARMACOLOGY (2014)

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Article Psychology, Biological

Diphenyl diselenide supplemented diet reduces depressive-like behavior in hypothyroid female rats

Glaecir Roseni Mundstock Dias et al.

PHYSIOLOGY & BEHAVIOR (2014)

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Article Multidisciplinary Sciences

Selenoether oxytocin analogues have analgesic properties in a mouse model of chronic abdominal pain

Aline Dantas de Araujo et al.

NATURE COMMUNICATIONS (2014)

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Article Chemistry, Medicinal

Synthesis and evaluation of diaryl sulfides and diaryl selenide compounds for antitubulin and cytotoxic activity

Edson dos A. dos Santos et al.

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS (2013)

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Article Chemistry, Applied

A Metal-Free Sulfenylation and Bromosulfenylation of Indoles: Controllable Synthesis of 3-Arylthioindoles and 2-Bromo-3-arylthioindoles

Dayun Huang et al.

ADVANCED SYNTHESIS & CATALYSIS (2012)

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Article Chemistry, Inorganic & Nuclear

Therapeutic potential of selenium and tellurium compounds: Opportunities yet unrealised

Edward R. T. Tiekink

DALTON TRANSACTIONS (2012)

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Article Chemistry, Multidisciplinary

GPx-Like Activity of Selenides and Selenoxides: Experimental Evidence for the Involvement of Hydroxy Perhydroxy Selenane as the Active Species

Vanessa Nascimento et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Review Chemistry, Multidisciplinary

Sulfones: new reagents in organocatalysis

Andrea-Nekane R. Alba et al.

CHEMICAL SOCIETY REVIEWS (2010)

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Article Chemistry, Medicinal

Vinyl sulfones: Synthetic preparations and medicinal chemistry applications

D. Christopber Meadows et al.

MEDICINAL RESEARCH REVIEWS (2006)

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Review Chemistry, Multidisciplinary

Organoselenium and organotellurium compounds: Toxicology and pharmacology

CW Nogueira et al.

CHEMICAL REVIEWS (2004)

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Review Chemistry, Multidisciplinary

Chemistry of biologically important synthetic organoselenium compounds

G Mugesh et al.

CHEMICAL REVIEWS (2001)

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