期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 50, 页码 16329-16336出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b08958
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资金
- Royal Society
- EPSRC [EP/J01981X/1]
- European Union [660731]
- EPSRC [EP/J01981X/1, EP/L016621/2] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L016621/2, EP/J01981X/1] Funding Source: researchfish
- Marie Curie Actions (MSCA) [660731] Funding Source: Marie Curie Actions (MSCA)
We present an operationally simple iterative coupling strategy for the synthesis of oligomeric homo- and hetero[n]rotaxanes with precise control over the position of each macrocycle. The exceptional yield of the AT-CuAAC reaction, combined with optimized conditions that allow the rapid synthesis of the target oligomers, opens the door to the study of precision-engineered oligomeric interlocked molecules.
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