Advances and Prospects in Improving the Utilization Efficiency of Lithium for High Energy Density Lithium Batteries

Lithium-ion batteries have attracted much attention in the field like portable devices and electronic vehicles. Due to growing demands of energy storage systems, lithium metal batteries with higher energy density are promising candidates to replace lithium-ion batteries. However, using excess amounts of lithium can lower the energy density and cause safety risks. To solve these problems, it is crucial to use limited amount of lithium in lithium metal batteries to achieve higher utilization efficiency of lithium, higher energy density, and higher safety. The main reasons for the loss of active lithium are the side reactions between electrolyte and electrode, growth of lithium dendrites, and the volume change of electrode materials during the charge and discharge process. Based on these issues, much effort have been put to improve the utilization efficiency of lithium such as mitigating the side reactions, guiding the uniform lithium deposition, and increasing the adhesion between electrolyte and electrode. In this review, strategies for high utilization efficiency of lithium are presented. Moreover, the remaining challenges and the future perspectives on improving the utilization of lithium are also outlined.

Automated summary

Lithium-ion batteries have garnered significant attention in industries such as portable devices and electric vehicles. As the demand for energy storage systems grows, lithium metal batteries with higher energy density are seen as promising alternatives to lithium-ion batteries. However, excessive amounts of lithium can decrease energy density and pose safety risks. To address these issues, it is crucial to limit the amount of lithium used in lithium metal batteries in order to achieve higher lithium utilization efficiency, energy density, and safety. The main factors contributing to the loss of active lithium include side reactions between the electrolyte and electrode, the formation of lithium dendrites, and the volume changes of electrode materials during charge and discharge. Efforts have been made to improve lithium utilization efficiency, such as mitigating side reactions, guiding uniform lithium deposition, and enhancing electrolyte-electrode adhesion. This review presents strategies for achieving high utilization efficiency of lithium and outlines the remaining challenges and future perspectives for improving lithium utilization.