4.8 Article

Facile Zn2+ Desolvation Enabled by Local Coordination Engineering for Long-Cycling Aqueous Zinc-Ion Batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Electrochemistry

The Trade-Offs in the Design of Reversible Zinc Anodes for Secondary Alkaline Batteries

Honglin Luo et al.

Summary: Zinc-based batteries face limitations in cycling performance due to issues like zinc dendrite formation, electrode deformation, corrosion, and hydrogen evolution. Researchers have developed strategies such as surface coating, additives, and structure design to address these problems, but trade-offs must be considered due to intertwined core factors restricting the reversibility of zinc electrodes.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

Article Chemistry, Multidisciplinary

The origin of capacity fluctuation and rescue of dead Mn-based Zn-ion batteries: a Mn-based competitive capacity evolution protocol

Hang Yang et al.

Summary: By studying manganese oxide, the origin of capacity fluctuation in Mn-based ZIBs was elucidated. New metrics and evaluation criteria were proposed, and the lifespan of batteries was shown to be extendable through acid treatment.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Review Chemistry, Multidisciplinary

Strategies of regulating Zn2+ solvation structures for dendrite-free and side reaction-suppressed zinc-ion batteries

Jin Cao et al.

Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Physical

Anti-Corrosion for Reversible Zinc Anode via a Hydrophobic Interface in Aqueous Zinc Batteries

Kailin Guan et al.

Summary: By assembling a self-consistent hydrophobic interface, water erosion can be blocked and the deposition process of zinc ions can be regulated, thereby improving the stability of the zinc metal anode.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Unveiling performance evolution mechanisms of MnO2 polymorphs for durable aqueous zinc-ion batteries

Yanxin Liao et al.

Summary: The study investigates the performance of MnO2 polymorphs in ZIBs to understand their detailed reaction chemistry and degradation mechanisms. Ex situ characterizations show evolution of active materials and coexisted reactions from co-insertion, dissolution/deposition and chemical conversion mechanisms. Variational contributions from intermediate products and different reaction mechanisms cause fluctuated performance during cycling, with R-MnO2 showing low manganese dissolution and stable capacity under high depth of discharge.

ENERGY STORAGE MATERIALS (2022)

Article Nanoscience & Nanotechnology

Boosting the Cycling Stability of Aqueous Zinc-Ion Batteries through Nanofibrous Coating of a Bead-like MnOx Cathode

Liyan Ding et al.

Summary: This study reports a facile synthetic strategy of bead-like manganese oxide coated with carbon nanofibers for high-performance cathode materials in rechargeable aqueous zinc-ion batteries. The synthesized material improves electron/ion diffusion kinetics and provides robust structural stability, resulting in long cycling durability and excellent rate capability. The study also provides insights into the electrochemical reaction mechanism of the batteries.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Multidisciplinary

Potassium Ammonium Vanadate with Rich Oxygen Vacancies for Fast and Highly Stable Zn-Ion Storage

Quan Zong et al.

Summary: This study improves the structure and electrochemical properties of ammonium vanadate by introducing potassium ions, resulting in excellent cycling stability and high discharge capacity. The introduction of potassium ions alleviates deammoniation and prevents structural collapse, providing a better ion diffusion pathway.

ACS NANO (2022)

Article Engineering, Environmental

Binder-free flexible zinc-ion batteries: one-step potentiostatic electrodeposition strategy derived Ce doped-MnO2 cathode

Yuanyuan Song et al.

Summary: With the development of flexible electronic devices, there is a growing demand for power sources with higher safety, lighter weight, and bending ability. Aqueous zinc-ion batteries have gained attention due to their low cost, abundant zinc resources, and high safety. Despite their potential, the practical application of aqueous zinc-ion batteries is hindered by the unsatisfactory performance of cathode materials and complex manufacturing processes. This research explores a Ce doped-MnO2 binder-free cathode electrode for flexible zinc-ion batteries, demonstrating high reversible specific capacity, significant energy density, and excellent stability. The energy storage mechanism of the flexible zinc-ion batteries with Mn-based oxides cathode is also investigated, providing insights into the reversible insertion/extraction of ions during charge/discharge processes. Overall, this research opens up new opportunities for the use of flexible zinc-ion batteries in portable and wearable electronics.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Construction of Bio-inspired Film with Engineered Hydrophobicity to Boost Interfacial Reaction Kinetics of Aqueous Zinc-Ion Batteries

Qianzhi Gou et al.

Summary: This study employs a bio-inspired approach to enhance the interfacial reaction kinetics and electrode stability of aqueous zinc-ion batteries. By constructing a bio-inspired hydrophobic conductive poly(3,4-ethylenedioxythiophene) film on the cathode, the electrical conductivity of the electrode is improved, the hydrophobicity of the cathode-electrolyte interface is engineered, and the desolvation behavior of hydrated zinc ions is enhanced, leading to improved overall interfacial reaction kinetics and cathode stability.
Article Chemistry, Physical

Molecular tailoring of MnO2 by bismuth doping to achieve aqueous zinc-ion battery with capacitor-level durability

Yu Ma et al.

Summary: This study proposes a bismuth (Bi) doping technology to improve the structural stability and reaction kinetics of MnO2 as cathode materials in aqueous zinc-ion batteries (ZIBs). The results show that Bi doping enhances the stability of the tunnel structure, electrical conductivity, and weakens the chemical bond strength between Zn2+ and O. The Bi-doped alpha-MnO2 (BMO-6) cathode exhibits excellent cycle life, rate performance, energy density, and mechanical stability, surpassing other reported Mn-based cathodes in aqueous ZIBs.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

Uncovering sulfur doping effect in MnO2 nanosheets as an efficient cathode for aqueous zinc ion battery

Yajun Zhao et al.

Summary: This study proposes sulfur doped MnO2 nanosheets as a high-performance cathode material for zinc-ion batteries, exhibiting large discharge capacity, high rate performance, and long cycle life. The incorporation of sulfur improves the intrinsic electronic conductivity of MnO2 and accelerates reaction kinetics by weakening the electrostatic interactions with Zn(2+) cations. The sulfur doping also induces an amorphous surface with abundant oxygen defects, contributing to additional Zn storage sites with pseudocapacitive behavior.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

Atomic engineering promoted electrooxidation kinetics of manganese-based cathode for stable aqueous zinc-ion batteries

Hao Luo et al.

Summary: This study improves the rate capacity and cycling stability of zinc-based batteries by enhancing the Mn-based cathode materials. The formation of carbon-protected birnessite-MnO2 and its hydrophobic nature effectively prevent Mn dissolution and other side reactions. This strategy shows potential applications in wearable and implantable electronic devices and provides insights for improving other cathode materials.

NANO RESEARCH (2022)

Article Chemistry, Physical

Suppressed Layered-to-Spinel Phase Transition in δ-MnO2 via van der Waals Interaction for Highly Stable Zn/MnO2 Batteries

Ce Qiu et al.

Summary: Coupling delta-MnO2 nanosheets with reduced graphene oxide (rGO) through vdW self-assembly can effectively suppress the phase transition issue and achieve excellent cycling performance in the hybrid cathode.

SMALL METHODS (2022)

Review Chemistry, Multidisciplinary

Insight on Cathodes Chemistry for Aqueous Zinc-Ion Batteries: From Reaction Mechanisms, Structural Engineering, and Modification Strategies

Anni Liu et al.

Summary: By focusing on cathode storage chemistry in aqueous zinc ion batteries (AZIBs), this paper comprehensively summarizes recent advances and explores issues and challenges for high-performance cathodes, presenting inspiring structural engineering and modification strategies. Rational evaluations on representative cathodes are provided, suggesting the potential development direction of AZIBs.
Article Chemistry, Physical

In Situ Induced Coordination between a Desiccant Interphase and Oxygen-Deficient Navajoite towards Highly Efficient Zinc Ion Storage

Jiangtao Huang et al.

Summary: The poor zinc storage performance of vanadium-based cathode materials is effectively addressed using an in situ electrochemical conversion strategy. The reconstructed cathode material, labeled as GP-HVOd, exhibits stable capacity, excellent cycling stability, and high rate performance, thanks to the gypsum layer and oxygen defects.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Achieving reversible Mn2+/Mn4+ double redox couple through anionic substitution in a P2-type layered oxide cathode

Haolv Hu et al.

Summary: In this study, we successfully introduced reversible Mn2+/Mn4+ double redox couple into P2-type Na0.6Mg0.3Mn0.7O2 cathode with suppressed Jahn-Teller (J-T) effect through F anion doping strategy. The introduction of F anions enlarged the interlayer spacing, reduced the band gap, improved charge transfer kinetics, suppressed Mn2+ dissolution, promoted reversible conversion, enhanced oxygen redox reaction, and ultimately enhanced the electrochemical performance.

NANO ENERGY (2022)

Editorial Material Chemistry, Physical

Toward practical aqueous zinc-ion batteries for electrochemical energy storage

Chang Li et al.

Summary: This article introduces researchers from the University of Waterloo and Cornell University, as well as their research areas. Their research primarily focuses on electrolyte systems for zinc-ion batteries, electrochemical reversibility of zinc anodes, and other related fields.
Article Chemistry, Multidisciplinary

Regulation of Outer Solvation Shell Toward Superior Low-Temperature Aqueous Zinc-Ion Batteries

Qianyi Ma et al.

Summary: The addition of 2-propanol is shown to regulate the outer solvation shell structure of Zn2+ in aqueous Zn-ion batteries, resulting in uniform Zn deposition and dendrite-free growth.

ADVANCED MATERIALS (2022)

Article Engineering, Environmental

Synergistic interlayer and defect engineering of hydrated vanadium oxide toward stable Zn-ion batteries

Jiechang Gao et al.

Summary: In this study, Ca-intercalated hydrated vanadium oxide (CaVO) nanobelts were synthesized, which showed enhanced electrochemical performance as cathode materials for practical Zn-ion batteries. The intercalated Ca ions and induced V vacancies synergistically enhanced the Zn-ion storage capability and effectively stabilized the crystal structure, leading to high reversible capacity, superior rate performance, and impressive cycling stability.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Materials Science, Multidisciplinary

Oxygen vacancies and N-doping in organic-inorganic pre-intercalated vanadium oxide for high-performance aqueous zinc-ion batteries

Feng Zhang et al.

Summary: Metal ion pre-intercalation into vanadium oxide is an effective strategy for optimizing the performance of rechargeable zinc-ion battery (ZIB) cathodes. However, improving the battery's long lifespan and high-capacity retention remains a challenge. This study introduces N-doped vanadium oxide as a cathode material for aqueous ZIBs, showing enhanced electronic conductivity and accelerated diffusion kinetics of zinc ions, leading to excellent electrochemical performance and long cycle life.

INFOMAT (2022)

Article Engineering, Environmental

Manipulating intercalation-extraction mechanisms in structurally modulated 6-MnO2 nanowires for high-performance aqueous zinc-ion batteries

Rongguo Zhang et al.

Summary: This study demonstrates a structural modulation strategy by Cu2+ intercalation to manipulate the electrochemical reaction mechanism in layered 6-MnO2, resulting in rapid and reversible zinc ion storage. The findings address the challenges of low capacity and poor cycling stability in manganese-based materials and provide a new approach for the development of cathode materials for zinc-ion batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Multidisciplinary

Recent Development of Mn-based Oxides as Zinc-Ion Battery Cathode

Wen Shi et al.

Summary: This article systematically summarizes the recent progress of Mn-based oxides as ZIB cathodes, including the classification based on different oxidation states, the respective polymorphs used as ZIB cathodes, commonly employed modification strategies to enhance performance, and the effects of these strategies on performance enhancement.

CHEMSUSCHEM (2021)

Article Chemistry, Physical

Co2+/3+/4+-Regulated Electron State of Mn-O for Superb Aqueous Zinc-Manganese Oxide Batteries

Jie Ji et al.

Summary: This study introduces a multi-valence cobalt-doped Mn3O4 cathode material (Co-Mn3O4) with high capacity and reversibility. The various states of doped cobalt play different roles in the manganese oxide, effectively improving the performance of the battery.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Inhibition of Manganese Dissolution in Mn2O3 Cathode with Controllable Ni2+ Incorporation for High-Performance Zinc Ion Battery

Dongdong Zhang et al.

Summary: A Ni-doped Mn2O3 cathode has been developed in this study to suppress the dissolution of manganese and improve the electrochemical performance, showing high specific capacity and excellent capacity retention over cycles. The doped Ni effectively stabilizes the Mn2O3 structure, demonstrating a promising strategy for future development of ZIBs.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Synergistic Manipulation of Zn2+ Ion Flux and Desolvation Effect Enabled by Anodic Growth of a 3D ZnF2 Matrix for Long-Lifespan and Dendrite-Free Zn Metal Anodes

Yang Yang et al.

Summary: The study successfully developed a Zn@ZnF2 electrode with a multi-functional protective layer by designing a 3D interconnected ZnF2 matrix on the surface of Zn foil. This electrode exhibits stable zinc deposition kinetics and good plating/stripping reversibility, showing potential for practical application in various battery systems.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Manipulating the Local Electronic Structure in Li-Rich Layered Cathode Towards Superior Electrochemical Performance

Hongfei Zheng et al.

Summary: The research successfully improved the performance of Li-rich layered cathodes by dual-doping Na+ and F- ions, and regulating Li+/Ni2+ intermixing and Li-O-Li configuration, leading to increased battery capacity and cycle life.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Engineering, Environmental

Interfacial polarization triggered by glutamate accelerates dehydration of hydrated zinc ions for zinc-ion batteries

Yan Qi Jin et al.

Summary: Interfacial polarization triggered by glutamate can accelerate the dehydration process of hydrated zinc ions, leading to an increase in battery capacity; during charging and discharging, Glu-MoS2 undergoes a reversible phase conversion from the 2H phase to the 1T phase, contributing to performance optimization.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Unveiling the Intricate Intercalation Mechanism in Manganese Sesquioxide as Positive Electrode in Aqueous Zn-Metal Battery

Yuan Ma et al.

Summary: This study systematically and comprehensively investigated the charge storage mechanism of cubic α-Mn2O3, demonstrating the reversible de-/intercalation of Zn2+ through an electrochemically induced irreversible phase transition and dissolution process. Additionally, by fabricating hierarchically structured mesoporous α-Mn2O3 microrod array material, unprecedented rate capability and appealing stability were achieved.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Cation- deficient Zn0.3(NH4)0.3V4O10•0.91H2O for rechargeable aqueous zinc battery with superior low- temperature performance

Tao He et al.

Summary: A novel cation-deficient nonstoichiometric Zn-0.3(NH4)(0.3)V4O10·0.91H2O (ZNV) cathode material for aqueous zinc batteries (AZBs) was reported in this research, exhibiting high discharge capacity and superior cycle stability. Both experiments and theoretical simulations demonstrated that the presence of cation vacancies facilitates Zn2+ diffusion during cycles.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Defect engineering via the F-doping of β-MnO2 cathode to design hierarchical spheres of interlaced nanosheets for superior high-rate aqueous zinc ion batteries

Seoyeong Kim et al.

Summary: A hierarchical beta-MnO2 cathode material with interlaced nanosheets spheres was introduced through efficient defect engineering using fluorine (F)-doping and oxygen vacancies, improving ion insertion, transport kinetics, and electrical conductivity in ZIB. This resulted in a high energy density, superior high-rate performance, and good capacity retention, highlighting the potential of defect-engineered cathode materials for enhanced electrochemical performance in rechargeable aqueous batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Comprehensive understanding of the roles of water molecules in aqueous Zn-ion batteries: from electrolytes to electrode materials

Ming Li et al.

Summary: This study comprehensively summarizes the role of water molecules in rechargeable aqueous zinc-ion batteries, focusing on the influencing mechanisms from various perspectives. It also proposes new insights and actionable methods for the potential future directions in the design of high-performance AZIBs.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Ultra-long-life and highly reversible Zn metal anodes enabled by a desolvation and deanionization interface layer†

Xiaotan Zhang et al.

Summary: The CNG membrane, serving as a desolvation layer, effectively prevents water molecules from contacting the zinc anode, thereby delaying water-induced corrosion reactions and promoting redirected zinc deposition through deanionization shock. The flexible and toughened nature of the CNG membrane allows it to withstand strong forces and accommodate surface fluctuations of the zinc anode during plating/stripping processes, resulting in enhanced Coulombic efficiency and extended cycle life.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Physical

Structurally reconstituted calcium manganate nanoparticles as a high-performance cathode for aqueous Zn-ion batteries

Siqi Zeng et al.

Summary: Developing Ca-deficient Ca0.96Mn3.04O4 nanoparticles through a structural reconstitution strategy has improved electrical conductivity, enhanced structural stability, and accelerated Zn ion diffusion rate. The Zn//CP-CMO battery based on these nanoparticles shows favorable capacity, excellent cyclic lifespan, and high coulombic efficiency. This work demonstrates the effective use of structural recombination strategy for developing high-performance cathode materials for AZIBs.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Materials Science, Multidisciplinary

MnO Stabilized in Carbon-Veiled Multivariate Manganese Oxides as High-Performance Cathode Material for Aqueous Zn-Ion Batteries

Wanwei Jiang et al.

Summary: This study presents a cooperative design of multivariate manganese oxides@carbon hybrids as an attractive Zn-ion cathode for aqueous Zn-ion batteries. The cathode exhibits excellent performance due to facile charge transfer and ions insertion, promoting the development of low-cost and high-performance rechargeable Zn-ion batteries.

ENERGY & ENVIRONMENTAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Design Strategies for High-Performance Aqueous Zn/Organic Batteries

Zhiwei Tie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

A Fluorination Method for Improving Cation-Disordered Rocksalt Cathode Performance

Juhyeon Ahn et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Physical

Defect Engineering in Manganese-Based Oxides for Aqueous Rechargeable Zinc-Ion Batteries: A Review

Ting Xiong et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Physical

Appropriately hydrophilic/hydrophobic cathode enables high-performance aqueous zinc-ion batteries

Xiaotan Zhang et al.

ENERGY STORAGE MATERIALS (2020)

Review Chemistry, Multidisciplinary

Preintercalation Strategy in Manganese Oxides for Electrochemical Energy Storage: Review and Prospects

Qinghe Zhao et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Manipulating the ion-transfer kinetics and interface stability for high-performance zinc metal anodes

Xuesong Xie et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

An Electrolytic Zn-MnO2 Battery for High-Voltage and Scalable Energy Storage

Dongliang Chao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

Built-in oriented electric field facilitating durable Zn-MnO2 battery

Sitian Lian et al.

NANO ENERGY (2019)

Review Chemistry, Multidisciplinary

Issues and opportunities facing aqueous zinc-ion batteries

Boya Tang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface

Dipan Kundu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

Aqueous Magnesium Zinc Hybrid Battery: An Advanced High-Voltage and High-Energy MgMn2O4 Cathode

Vaiyapuri Soundharrajan et al.

ACS ENERGY LETTERS (2018)

Article Nanoscience & Nanotechnology

Novel Alkaline Zn/Na0.44MnO2 Dual-Ion Battery with a High Capacity and Long Cycle Lifespan

Tianci Yuan et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Fluorine-Doped Carbon Surface Modification of Li-Rich Layered Oxide Composite Cathodes for High Performance Lithium-Ion Batteries

Fenghua Zheng et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Chemistry, Multidisciplinary

Zn/MnO2 Battery Chemistry With H+ and Zn2+ Coinsertion

Wei Sun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities

Ning Zhang et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Cation-Deficient Spinel ZnMn2O4 Cathode in Zn(CF3SO3)2 Electrolyte for Rechargeable Aqueous Zn-Ion Battery

Ning Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Electrochemistry

A layered δ-MnO2 nanoflake cathode with high zinc-storage capacities for eco-friendly battery applications

Muhammad Hilmy Alfaruqi et al.

ELECTROCHEMISTRY COMMUNICATIONS (2015)

Article Chemistry, Physical

Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System

Leyuan Zhang et al.

ADVANCED ENERGY MATERIALS (2015)

Article Chemistry, Physical

A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films

E Elangovan et al.

APPLIED SURFACE SCIENCE (2005)