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Article
Nanoscience & Nanotechnology
Sha Tan et al.
Summary: Accurate understanding of the chemistry of solid-electrolyte interphase (SEI) is crucial for developing new electrolytes for high-energy batteries with lithium metal (Li-0) anodes. Our study reveals a more complex formation mechanism of SEI, involving reactions between Li-0 and electrolyte, as well as contributions from cathode, moisture, and native surface species on Li-0, with dynamic changes during cycling.
NATURE NANOTECHNOLOGY
(2023)
Article
Chemistry, Physical
Inyeong Yang et al.
Summary: By increasing structural dimensions and introducing hierarchy, the formation of Li dendrites on Li-metal anode can be stabilized, resulting in extended cycling life and improved reversibility.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Jinlong Jiang et al.
Summary: By depositing gold on the surface of copper foil and constructing a LiF/LixMgy interfacial layer, the deposition position of Li can be controlled to preferentially deposit between the ionically conductive LiF/LixMgy artificial solid electrolyte interphase (SEI) and the high-lithiophilicity metal layer, achieving high-performance Li-metal batteries.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jiarui He et al.
Summary: This study investigates the feasibility of Li-OS batteries under realistic conditions and achieves extremely stable cycling performance by introducing C@Fe3N as a scaffold for uniform lithium deposition and catalysis of the DIXPS conversion reaction.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Shangshu Qian et al.
Summary: Lithium metal anodes have a higher specific capacity than commercial graphite anodes, making them attractive for rechargeable batteries. However, the growth of lithium dendrites poses safety concerns, hindering their practical application. This review summarizes the strategies for protecting lithium metal anodes by preventing dendrite growth, regulating lithium deposition behaviors, and healing existing dendrites. Integrating different strategies can enhance their advantages, narrowing the gap between experimental research and commercial application of lithium metal batteries.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hai Xu et al.
Summary: This study focuses on optimizing the charge storage capability and electrochemical kinetics of reduced graphene oxide (rGO) nanosheets. It reveals the additional contribution of reversible adsorption/desorption of H+ on the carbon atom of rGO sheets. The findings provide insights into proton adsorption chemistry and offer guidance for the design of novel electrode materials.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Hongjiao Huang et al.
Summary: By coating and etching metal clusters, the activity of metal single-atoms can be optimized through electron redistribution and modulation of M-N bond lengths, resulting in enhanced ORR activity. This strategy shows great potential in energy storage devices.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Engineering, Environmental
Junnan Song et al.
Summary: A novel synthesis strategy was developed to prepare hierarchically porous cobalt nitride hybrid nano sheets, which exhibited remarkable catalytic activity. The CoN@NC electrode showed excellent catalytic performance in oxygen evolution reaction, hydrogen evolution reaction, and oxygen reduction reaction, making it a promising material for electrocatalysis and energy storage applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Lintao Yu et al.
Summary: The use of PCNF/MoS2 composite anode can effectively reduce lithium dendrite growth, decrease overvoltage, achieve uniform lithium plating/stripping, and guide lithium deposition. Li2S as an additive helps in forming a uniform and robust solid electrolyte interface, successfully realizing stable lithium anode.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Multidisciplinary Sciences
Yujing Liu et al.
Summary: In this study, self-assembled monolayers (SAMs) were utilized to control electrolyte degradation and solid-electrolyte interphase (SEI) formation in lithium metal batteries (LMBs), resulting in improved cycling performance and lifespan.
Article
Chemistry, Multidisciplinary
Jianyu Chen et al.
Summary: A bidirectional porous Cu current collector was developed in this study, showing stable Li plating and stripping behaviors for practical Li metal batteries. The current collector demonstrated high capacity, outstanding cycling performance, and elevated energy density, suggesting promising applications for future Li metal batteries.
Article
Chemistry, Multidisciplinary
Qing Zhao et al.
Summary: A new cation-selective separator with anion immobilization behavior has been developed to improve the performance of lithium metal anodes. By utilizing a poly(vinylidene fluoride) matrix, the separator exhibits excellent cation-selective properties, leading to prolonged nucleation time of lithium dendrites and enhanced stability of lithium plating/stripping cycling. The integration of this separator into lithium metal batteries also improves various electrochemical performances.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Shao-Jian Zhang et al.
Summary: This study proposes a cost-efficient and scalable method for constructing dense and uniform buffer layers on lithium/sodium anodes. The adoption of silk fibers derived carbon and carbon nanotubes composite enables uniform nucleation and dendrite-free growth, leading to improved cycling stability and efficiency of the batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jingyi Wu et al.
Summary: This article presents the principles and decisive role of charge transport mechanisms in battery performance, with a discussion on the correlation between charge transport regulation and battery microstructure design. It summarizes the design strategies of gradient cathodes, lithium-metal anodes, and solid-state electrolytes. Future directions and perspectives of gradient design are provided to enable practically accessible high-energy and high-power-density batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Chenrayan Senthil et al.
Summary: The authors report a novel artificial lithium/electrolyte solid electrolyte interphase (SEI) mediated by graphene quantum dots, which achieves an ultrasmooth and homogeneous interface environment for dendrite-free lithium metal anodes. This research paves the way for achieving dendrite-free, smooth, and robust metal anodes.
Article
Chemistry, Physical
Shangshu Qian et al.
Summary: By constructing a multi-functional protection layer on the surface of lithium metal, the formation and growth of lithium dendrites can be controlled, and the diffusion and distribution of lithium ions can be enhanced, achieving a stable and high-performance lithium metal anode.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Dongdong Li et al.
Summary: Inverted anode structure can effectively solve lithium dendrite issues, extend the cycle life of lithium metal anode, and exhibit good stability. This strategy can also be applied to other porous current collectors, providing opportunities for next-generation lithium-based batteries.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Chunnan Zhu et al.
Summary: This research reports a new method to improve the Coulombic efficiency and inhibit dendritic growth in rechargeable Li metal batteries by introducing fluorinated aromatic diluents into high-concentration electrolytes. The use of this electrolyte provides higher energy density and cycling life without compromising the performance of the battery.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Yucheng Liu et al.
Summary: This study demonstrates the fabrication of a dual-gradient architecture 3D conductive Li host, which effectively improves the stability and cycling stability of Li metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Ruoqian Lin et al.
Summary: This study investigates the interface structure and chemistry of lithium-polyacrylate electrolyte using advanced cryo-EM imaging and spectroscopic techniques, finding that no protective interphase forms as previously believed. The introduction of additive engineering effectively protects the lithium metal surface against corrosion and improves the cycle life of batteries.
NATURE NANOTECHNOLOGY
(2022)
Review
Chemistry, Physical
Changhong Wang et al.
Summary: This paper discusses the overlooked issue of soft breakdown in all-solid-state lithium batteries (ASSLBs) and proposes an effective method for diagnosis. By analyzing the significant effect of critical parameters, a testing benchmark is established to guide scientific understanding and engineering design.
Article
Chemistry, Multidisciplinary
David T. Boyle et al.
Summary: This study reveals the plating mechanisms and morphologies under low and high currents by measuring the transport of lithium ions at the solid electrolyte interface. Under fast-charging rates, the breakdown of the solid electrolyte interface can lead to detrimental morphologies and poor cyclability in lithium metal batteries.
Article
Chemistry, Physical
Hongfei Xu et al.
Summary: The study presents a phase change electrolyte that can regulate the solvation structure by changing the physical state of the electrolyte. The electrolyte shows high ionic conductivity and electrochemical stability, effectively suppressing lithium dendrite growth and dissolution of active anodic materials, leading to improved electrochemical performance of lithium metal batteries.
ACS ENERGY LETTERS
(2022)
Article
Chemistry, Physical
Jie Shi et al.
Summary: This study introduces a stable and conductive Li2O buffering coating for Ni-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) in all-solid-state lithium batteries (ASSLBs) based on sulfide electrolytes (SEs). The Li2O buffer improves the stability of NCM811 and enhances the transfer of Li+ ions, resulting in higher initial discharge capacity, rate capability, and long-term cycling performance.
ENERGY STORAGE MATERIALS
(2022)
Review
Electrochemistry
Wenzhuo Cao et al.
Summary: This paper examines the behaviors, mechanisms, and influencing factors of Li plating/stripping and proposes general strategies to control Li deposition. It is essential to have comprehensive design strategies for the electrode, electrolyte, and their interface. Three dimensional (3D) anodes and artificial interface engineering can reduce the risk of Li deposition, while electrolyte engineering favors Li transport and suppresses dendrites, serving as the final barrier to uncontrolled Li deposition.
Article
Electrochemistry
Jinkiong Ling et al.
Summary: Electrical energy generation and storage have always been complementary to each other but are often disconnected in practical electrical appliances. Recently, efforts to combine both energy generation and storage into self powered energizers have demonstrated promising power sources for wearable and implantable electronics.
Article
Electrochemistry
Xin-Yang Yue et al.
Summary: In this study, MoN nanolayer-decorated multilayer graphene was used as a layer material to suppress the shuttle effect of lithium polysulfides and enhance the redox kinetics in Li-S batteries. After the initial discharge process, the MoN layers break up into independent microreaction units consisting of MoN bodies and MoS2 edges, forming an in situ heterogeneous composite catalyst. The MoN bodies can trap LiPSs and enhance their redox kinetics, while the MoS2 edges weaken the mobility of LiPSs through the anchoring effect. Li-S cells using this interlayer exhibit excellent cycling stability under a high sulfur loading.
Article
Electrochemistry
Ai-Long Chen et al.
Summary: A novel Li+ flux distributor achieved by placing PVDF/PMMA composite nanofiber interlayer on a current collector induces uniform lithium deposition to mitigate dendrite growth, improving the stability of lithium metal batteries. Experimental results show that the design enables molecular-level uniform Li nucleation, leading to high cycling stability and increased rate capacity.
Article
Chemistry, Multidisciplinary
David T. Boyle et al.
Summary: The poor fast-charge capabilities of rechargeable Li metal anodes are limited by the current-dependent regimes of Li plating mechanisms and morphology. Understanding how high currents lead to detrimental morphology and poor cyclability can help prevent SEI-breakdown and slow ion transport, informing further electrolyte engineering and customization of fast-charging protocols for Li metal batteries.
Article
Chemistry, Multidisciplinary
Yongjin Fang et al.
Summary: The use of nitrogen-doped amorphous Zn-carbon multichannel fibers as hosts for lithium accommodation, with lithiophilic nitrogen-doped carbon and functional Zn nanoparticles for preferred deposition sites, reduces local current density, guides uniform lithium deposition, and improves battery efficiency and stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Engineering, Environmental
Byung Gon Kim et al.
Summary: A 1D hollow carbon fiber with lithiophilic Au nanoparticles can effectively reduce Li dendrite growth and stabilize the solid-electrolyte interphase layer, achieving a high Coulombic efficiency for Li-metal batteries. The Au@HCF anode shows significantly improved cycle life in LiFePO4 full cells, indicating the potential for realizing emerging Li-metal batteries with a Li-confinable structure design concept.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Jiaming Zhang et al.
Summary: This study focused on applying metallic Mo as a host for Li/Mo composite anode, revealing through density functional theory results that Mo substrate promotes uniform deposition of Li, reducing dendrite growth effectively, and enhancing cycling lifespan and stability of the battery.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Xintong Lian et al.
Summary: A reliable synthetic approach was reported for the in-situ growth of Co-based ZIF-67 on electrospun nanofibers, followed by carbonization and sulfurization to form Co1-xS hollow polyhedrons anchored on multichannel carbon nanofibers (Co1-xS/MCF) for LIBs and SIBs. The resulting binder-free Co1-xS/MCF anode demonstrated advanced electrochemical properties for both LIBs and SIBs, attributed to the unique multichannel nanostructure and Co1-xS hollow polyhedrons providing active sites and reducing structural strain.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Xiang Li et al.
Summary: This research developed a functional modification layer from a derivant of natural silk to protect the lithium anode, offering abundant functional group sites for efficient uniform Li-ion flux and in situ formation of a Li3N-rich solid electrolyte interphase film. The high-performance lithium metal anode achieved dendrite-free morphology and significantly enhanced cycle stability, showing long-term cycling stability of 3000 cycles when paired with LiFePO4 cathodes and over 400 cycles with sulfur cathodes. This study provides a facile and practical approach for interface modification of the high-performance lithium anode and explores the application of biomass-based materials in advanced batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Junmou Du et al.
Summary: A method for fabricating uniform metallic Li layers with a lithiophilic Sn interphase layer was explored, which enhances the surface wettability of the Li electrode, reduces nucleation barriers, and improves the electrochemical performance of Li metal. This approach led to improved capacity retention and high energy density in full cells, opening up a promising pathway for high-energy-density batteries.
ADVANCED ENERGY MATERIALS
(2021)
Review
Energy & Fuels
Fabian Duffner et al.
Summary: This review highlights the current production status of representative PLIBs and the advantages of lithium-ion batteries as advanced electrochemical energy storage technology. It also discusses the research and manufacturing processes of post-lithium technologies.
Article
Chemistry, Multidisciplinary
Dong Guo et al.
Summary: 2D heterostructured materials with ultrathin nanosheet morphology, defined pore configuration, and stable hybrid compositions have attracted attention for efficient energy storage. Covalently assembling COFs on MXene nanosheets to create a robust heterostructure leads to significantly improved lithium storage and charge transport for fast-charging anodes.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Chuang Sun et al.
Summary: The use of a sol electrolyte based on OP-10 can alleviate lithium anode pulverization in lithium metal batteries, improving their cycling life. This sol electrolyte has better ionic conductivity than gel and solid-state electrolytes, homogenizing lithium ion diffusion throughout the electrolyte efficiently. Li/Li symmetric cells using this sol electrolyte demonstrate long-term cycling stability, showing the potential for efficient selection of electrolytes for lithium metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Lin Fu et al.
Summary: The concept of salt-in-metal is proposed in this study, where a Li/LiNO3 composite foil is constructed to embed LiNO3 into the bulk structure of metallic Li. This helps in achieving a stable solid electrolyte interphase (SEI) and regulating the nucleation and growth processes of Li, reducing dendritic Li growth. This approach results in stable cycling and high capacity retention for rechargeable batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Jaewoo Lee et al.
Summary: In order to address the issue of dendrite-free lithium in metallic Li anode, a new innovative Li-metal storage host with lithiophilic surface and nanoarchitectured structure is proposed. After tuning the surface chemistry, the host shows excellent electrochemical performance with high Li-metal reversible capacity and stable long-term cyclability.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Huinan Lin et al.
Summary: A new method for constructing Au/Cu nanoscaffold as an effective Li metal hosting material to solve the dendrite growth and unstable interface issues during Li plating/stripping process is proposed in this work. The symmetric cells based on this nanoscaffold exhibit stable performance, demonstrating great potential for high-performance lithium metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Ying Li et al.
Summary: The stable formation of electrode-electrolyte interface (EEI) is crucial for achieving high performance in rechargeable batteries. The choice of electrode material plays a critical role in catalyzing the reduction of electrolyte, which influences the formation of solid electrolyte interface (SEI) and ultimately affects battery performance. Direct and indirect factors on electrodes can influence the catalytic effects on electrolyte reduction, and selective regulations can be achieved through electrode design optimization.
ACS ENERGY LETTERS
(2021)
Review
Electrochemistry
Aoming Huang et al.
Summary: Silicon shows promise as an anode material for lithium-ion batteries, but challenges like volume variation and low conductivity still need to be addressed. Designing micro-nano structures and composites of heterogeneous materials are effective strategies. Electrospinning technology can help construct unique structures to solve issues with Si-based anodes.
Review
Electrochemistry
Shichao Zhang et al.
Summary: Lithium-based batteries have made a significant impact on modern society, but safety issues like thermal runaway have hindered their practical application, especially with metal anodes. Recent research has focused on flame-retardant and nonflammable electrolytes, exploring their mechanisms, efficiency, and influence on battery performance. Future prospects involve designing safer lithium-based batteries with nonflammable electrolytes.
Article
Multidisciplinary Sciences
Yongjin Fang et al.
Summary: In this study, a three-dimensional hybrid host was developed to inhibit dendritic lithium formation in lithium batteries, resulting in a more stable lithium plating/stripping behavior. When coupled with a commercial cathode, the assembled full cell showed high rate capability and stable cycling life.
Review
Nanoscience & Nanotechnology
C. Jin et al.
Summary: Lithium metal batteries have attracted attention due to their high theoretical capacity and low reduction potential, but face challenges in practical applications, with functional skeletons being an attractive approach to overcome these challenges.
MATERIALS TODAY NANO
(2021)
Article
Chemistry, Multidisciplinary
Ji Qian et al.
Summary: The use of a lithiophilic 3D Cu host to suppress Li dendrites growth and achieve dense Li deposition improves the electrochemical performance of Li metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
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Tian-Shi Wang et al.
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(2020)
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(2020)
Review
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Thorben Krauskopf et al.
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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