4.8 Article

Dual-Atom-Site Sn-Cu/C3N4 Photocatalyst Selectively Produces Formaldehyde from CO2 Reduction

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Environmental

Single atom Fe-dispersed graphitic carbon nitride (g-C3N4) as a highly efficient peroxymonosulfate photocatalytic activator for sulfamethoxazole degradation

Gang Zhao et al.

Summary: A highly efficient single atom Fe-dispersed catalyst with Fe-N-4 coordination structure was synthesized for peroxymonosulfate (PMS) activation and sulfamethoxazole (SMX) degradation. The catalyst showed excellent performance in PMS activation and SMX removal, with a high turnover efficiency and good stability. Identification of reaction active species and proposed degradation mechanism for SMX provide valuable insights for sulfate radical-based advanced oxidation processes.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Asymmetric Coupled Dual-Atom Sites for Selective Photoreduction of Carbon Dioxide to Acetic Acid

Guangri Jia et al.

Summary: An asymmetric coupled heteronuclear photocatalyst is designed for highly selective production of acetic acid from CO2 reduction. Experimental data and theoretical calculations reveal the high activity and excellent performance of this catalyst system.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Multidisciplinary

Cu-Based Organic-Inorganic Composite Materials for Electrochemical CO2 Reduction

Man Hou et al.

Summary: This review systematically summarizes the research advances of various Cu-based organic-inorganic composite materials in CO2RR, discusses the synthesis strategies, structure-performance relationship, and catalytic mechanisms, and proposes the opportunities and challenges in this field.

CHEMISTRY-AN ASIAN JOURNAL (2022)

Review Materials Science, Multidisciplinary

Emerging dual-atomic-site catalysts for electrocatalytic CO2 reduction

Na Qiu et al.

Summary: This review highlights recent advances in dual-atomic-site catalysts (DASCs) for enhancing CO2 reduction reaction (CO2RR). The classification, synthesis, and identification of DASCs are provided, as well as the catalytic applications and structure-activity relationship in CO2RR. Opportunities and challenges for future DASCs design are proposed.

SCIENCE CHINA-MATERIALS (2022)

Article Chemistry, Physical

Efficient photocatalytic CO2 conversion over 2D/2D Ni-doped CsPbBr3/Bi3O4Br Z-scheme heterojunction: Critical role of Ni doping, boosted charge separation and mechanism study

Xiaotian Wang et al.

Summary: In this study, a novel ultrathin Ni-doped CsPbBr3/Bi3O4Br Z-scheme heterostructure was constructed, which showed enhanced CO2 adsorption and activation ability. The synergistic effect between doping and heterostructure significantly improved the efficiency of photocatalytic CO2 reduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Review Chemistry, Physical

Cu-Based Tandem Catalysts for Electrochemical CO2 Reduction

Yongxia Shi et al.

Summary: Large amounts of CO2 gas have been emitted into the atmosphere through human activities, causing environmental problems. Developing and utilizing renewable clean energy is crucial to reduce CO2 emission. Electrochemical CO2 reduction reaction (CO2RR) is considered an effective approach to obtain valuable chemicals and fuels. Copper has been proven to be the only catalyst that can efficiently reduce CO2 to hydrocarbons and oxygenates. However, pure Cu has limitations for industrial-scale production. Cu-based tandem catalysts are a promising strategy for improving CO2RR performance.

ACTA PHYSICO-CHIMICA SINICA (2022)

Article Chemistry, Physical

Exclusive CO2-to-formate conversion over single-atom alloyed Cu-based catalysts

Junjun Li et al.

Summary: Electrochemical CO2 reduction reaction (CO2RR) is an appealing approach to convert emitted CO2 to value-added chemicals and fuels. Formic acid (HCOOH) has been considered as a promising liquid hydrogen storage material. However, the reported catalysts have failed to meet the requirements for industrialized feasibility of CO2RR. In contrast, Cu-based catalysts show excellent activity and low cost. A recent study has developed a single-atom alloy strategy for exclusive CO2-to-formate conversion over Cu-based catalysts, providing a prospect for industrial production of HCOOH from CO2.

GREEN ENERGY & ENVIRONMENT (2022)

Article Engineering, Environmental

Advances for CO2 Photocatalytic Reduction in Porous Ti-Based Photocatalysts

Mingyang Li et al.

Summary: The photoreduction of CO2 into high value-added fuels is a prospective approach for dealing with energy depletion and global warming. Ti-based photocatalysts with porous structures have aroused wide concern due to their potential advantages such as high specific surface area, cost-effectiveness, earth-abundance, and non-toxicity. This review presents the current achievements on porous TiO2, Ti-based zeolites, and Ti-based metal-organic frameworks for CO2 photoreduction, and discusses multiple modification methods for optimizing the performance of these Ti-based materials. Finally, challenges and perspectives of porous Ti-based photocatalysts for CO2 photoreduction are proposed.

ACS ES&T ENGINEERING (2022)

Article Engineering, Environmental

Photocatalytic and Photoelectrochemical Carbon Dioxide Reductions toward Value-Added Multicarbon Products

Haijiao Lu et al.

Summary: Developing new energy sources is crucial for meeting energy demands and reducing CO2 emissions. Converting CO2 into value-added products is a promising strategy, but is limited by low activity and selectivity. The article reviews the basics of PC and PEC CO(2)RRs and discusses the main strategies for achieving high CO2RR activity and selectivity for multicarbon products.

ACS ES&T ENGINEERING (2022)

Review Engineering, Environmental

Simultaneous Dual-Functional Photocatalysis by g-C3N4-Based Nanostructures

Anise Akhundi et al.

Summary: Heterogeneous photocatalytic reactions have been used to address environmental and energy issues by utilizing appropriate photocatalysts. The recent innovative approach is to achieve multiple functions simultaneously. This requires novel design and engineering of semiconductor photocatalysts. Graphitic carbon nitride has gained attention as a dual-functional photocatalyst. Morphological engineering and band gap manipulation are useful strategies to improve its photocatalytic activity.

ACS ES&T ENGINEERING (2022)

Article Chemistry, Multidisciplinary

Interface rich CuO/Al2CuO4 surface for selective ethylene production from electrochemical CO2 conversion

Siraj Sultan et al.

Summary: In this study, a newly designed electrocatalyst with phase and interphase engineering achieves high selectivity for the electrochemical reduction of carbon dioxide to ethylene. The catalyst shows good catalytic stability and material durability.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Energy & Fuels

Highly Enhanced Full Solar Spectrum-Driven Photocatalytic CO2Reduction Performance in Cu2-xS/g-C3N4Composite: Efficient Charge Transfer and Mechanism Insight

Lisha Jiang et al.

Summary: This study presents an efficient Cu2-xS/g-C(3)N(4) composite photocatalyst for CO2 photoreduction, with superior full solar-spectrum-driven performance attributed to the efficient charge transfer between Cu2-xS and g-C(3)N(4). The composite showed significantly higher activities compared to pure Cu2-xS and g-C3N4, paving the way for the development of carbon nitride-based photocatalysts for efficient CO2 photoreduction with full-spectrum-responsive property.

SOLAR RRL (2021)

Article Chemistry, Multidisciplinary

Dual-Single-Atom Tailoring with Bifunctional Integration for High-Performance CO2 Photoreduction

Lei Cheng et al.

Summary: This study demonstrates the development of dual-single-atom catalysts supported on porous carbon nitride for effective photocatalytic CO2 reduction. The combination of cobalt and ruthenium facilitates dynamic charge transfer and selective CO2 surface-bound interaction, leading to high photocatalytic CO2 conversion efficiency without the need for sacrificial agents. The synergy between the unique properties of the two metals boosts the overall photocatalytic performance.

ADVANCED MATERIALS (2021)

Review Chemistry, Physical

Engineering 2D Photocatalysts toward Carbon Dioxide Reduction

Yansong Zhou et al.

Summary: Photocatalytic technology is an attractive strategy for driving chemical reactions using renewable solar energy to address energy and environmental concerns. Recent research has focused on 2D nanomaterials in photocatalytic CO2 reduction due to their unique structural properties. Ongoing development of modification strategies for 2D nanomaterials can enhance light absorption, promote charge carrier separation, and improve CO2 activation, thus boosting photocatalytic efficiency.

ADVANCED ENERGY MATERIALS (2021)

Article Engineering, Environmental

Single Pt atom-anchored C3N4: A bridging Pt-N bond boosted electron transfer for highly efficient photocatalytic H2 generation

Yidong Hu et al.

Summary: The introduction of atomically dispersed Pt in graphitic carbon nitride as Pt SAs/C3N4 photocatalyst, with Pt-N bonds serving as a bridge for electron transfer, significantly improves the photocatalytic efficiency for hydrogen evolution.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Materials Science, Multidisciplinary

Rich oxygen vacancies mediated bismuth oxysulfide crystals towards photocatalytic CO2-to-CH4 conversion

Lisha Jiang et al.

Summary: Oxygen vacancy-rich bismuth oxysulfide (Bi2O2S) with a layered structure was prepared as an efficient photocatalyst for CO2 reduction under visible light. The presence of abundant oxygen vacancies in Bi2O2S enhances CO2 adsorption, activation abilities, and carrier separation efficiency. This study provides insights into developing Bi-O-S photocatalysts through defect engineering for photocatalytic CO2 reduction.

SCIENCE CHINA-MATERIALS (2021)

Review Chemistry, Multidisciplinary

2D Graphitic Carbon Nitride for Energy Conversion and Storage

Yinghui Wang et al.

Summary: This review provides a detailed introduction to the physicochemical properties of 2D g-C3N4 nanosheets, their synthetic strategies, and various applications in energy conversion and storage, highlighting their superior performance and design potential.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

Emerging Dual-Atomic-Site Catalysts for Efficient Energy Catalysis

Weiyu Zhang et al.

Summary: Atomically dispersed metal catalysts with well-defined structures have been a research hotspot in heterogeneous catalysis. Dual-atomic-site catalysts, as an extension of single-atom catalysts, possess higher metal loading and more flexible active sites, offering the potential for better catalytic performance.

ADVANCED MATERIALS (2021)

Article Multidisciplinary Sciences

Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation

Shubo Tian et al.

Summary: The study successfully prepared a mesoporous graphitic carbon nitride-supported dual-atom Pt-2 catalyst, which displayed excellent catalytic performance in the hydrogenation of nitrobenzene to aniline reaction, with a conversion rate higher than that of other comparative catalysts. This catalyst also shows potential applications in other important reactions.

NATURE COMMUNICATIONS (2021)

Article Multidisciplinary Sciences

Sustained CO2-photoreduction activity and high selectivity over Mn, C-codoped ZnO core-triple shell hollow spheres

Mahmoud Sayed et al.

Summary: The photoreduction of CO2 into energy-rich products is a sustainable solution for global energy and environmental crisis with the use of Mn ions as ionized cocatalyst to promote the process. The design of core-triple shell Mn, C-codoped ZnO hollow spheres as efficient photocatalysts demonstrates promising CO2 conversion performance, highlighting the importance of ionized cocatalyst in sustainable energy production.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4

Jian Li et al.

Summary: The study demonstrates a bioinspired photocatalyst with flexible dual-metal-site pairs that enhance CH4 selectivity and production rate. By stabilizing various C1 intermediates, it achieves a highly selective CO2-to-CH4 process.

NATURE CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Promoting the conversion of CO2 to CH4via synergistic dual active sites

Zhanzhao Fu et al.

Summary: This study introduces a simple coordination regulation method of the active site to improve the efficiency of CO2 conversion, demonstrates the excellent catalytic performance of NiN3B in CH4 conversion, and highlights the synergistic dual active sites formed between non-metal B and metal Ni atoms in catalysis.

NANOSCALE (2021)

Review Engineering, Environmental

Environmental Materials beyond and below the Nanoscale: Single-Atom Catalysts

Seunghyun Weon et al.

Summary: Nanotechnology has driven scientific advances in catalytic materials and processes, particularly in applications such as environmental remediation. The unique properties of nanostructured materials have been widely used by controlling the size and structure of materials. Recent research focuses on the potential application of single-atom catalysts in environmental remediation.

ACS ES&T ENGINEERING (2021)

Article Chemistry, Multidisciplinary

Suppressing the liquid product crossover in electrochemical CO2 reduction

Ning Wang et al.

Summary: The crossover of liquid products in electrochemical CO2 reduction (CO2R) has been a neglected issue, but it hinders the application and efficiency of the process. Promising methods to suppress liquid product crossover include the use of bipolar membranes, solid-state electrolytes, and cation-exchange membranes, with remaining challenges to overcome in achieving the goal of producing concentrated liquid products from CO2.

SMARTMAT (2021)

Article Chemistry, Multidisciplinary

Unexpected Roles of Triethanolamine in the Photochemical Reduction of CO2 to Formate by Ruthenium Complexes

Renato N. Sampaio et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Physical

Carbon-Based Single-Atom Catalysts for Advanced Applications

Manoj B. Gawande et al.

ACS CATALYSIS (2020)

Review Chemistry, Physical

Atomic-Level Reactive Sites for Semiconductor-Based Photocatalytic CO2 Reduction

Yanzhao Zhang et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Nafion-Assisted Noncovalent Assembly of Molecular Sensitizers and Catalysts for Sustained Photoreduction of CO2 to CO

Shinbi Lee et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Review Chemistry, Multidisciplinary

Heterogeneous Single-Atom Catalysts for Electrochemical CO2Reduction Reaction

Minhan Li et al.

ADVANCED MATERIALS (2020)

Article Multidisciplinary Sciences

Harnessing strong metal-support interactions via a reverse route

Peiwen Wu et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction

Jiaqi Feng et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Multidisciplinary

Theoretical insights into single-atom catalysts

Lulu Li et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Time-resolved observation of C-C coupling intermediates on Cu electrodes for selective electrochemical CO2 reduction

Younghye Kim et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

A highly active, robust photocatalyst heterogenized in discrete cages of metal-organic polyhedra for CO2 reduction

Hyeon Shin Lee et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Efficient and Robust Carbon Dioxide Electroreduction Enabled by Atomically Dispersed Snδ+ Sites

Xiaolong Zu et al.

ADVANCED MATERIALS (2019)

Article Multidisciplinary Sciences

Validity of Valence Estimation of Dopants in Glasses using XANES Analysis

Hirokazu Masai et al.

SCIENTIFIC REPORTS (2018)

Review Chemistry, Inorganic & Nuclear

Artificial photosynthesis: Catalytic water oxidation and CO2 reduction by dinuclear non-noble-metal molecular catalysts

Jia-Wei Wang et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Article Multidisciplinary Sciences

On the origin of the elusive first intermediate of CO2 electroreduction

Irina Chernyshova et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

Article Multidisciplinary Sciences

Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst

Tingting Sun et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

Article Chemistry, Multidisciplinary

Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction

Jing Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Multidisciplinary

Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies

Wooyul Kim et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide

Guoping Gao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Physical

On the mechanism of high product selectivity for HCOOH using Pb in CO2 electroreduction

Seoin Back et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

Article Chemistry, Multidisciplinary

Visible-Light-Driven CO2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts

Ryo Kuriki et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Multidisciplinary

Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes

James L. White et al.

CHEMICAL REVIEWS (2015)

Article Electrochemistry

A Fundamental Understanding of Li Insertion/Extraction Behaviors in SnO and SnO2

Jae-Wan Park et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Structural distortion in graphitic-C3N4 realizing an efficient photoreactivity

Hui Wang et al.

NANOSCALE (2015)

Article Chemistry, Multidisciplinary

Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions

Neil C. Tomson et al.

CHEMICAL SCIENCE (2015)

Article Chemistry, Multidisciplinary

Nafion layer-enhanced photosynthetic conversion of CO2 into hydrocarbons on TiO2 nanoparticles

Wooyul Kim et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

Article Chemistry, Multidisciplinary

A Photocatalyst-Enzyme Coupled Artificial Photosynthesis System for Solar Energy in Production of Formic Acid from CO2

Rajesh K. Yadav et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Physical

Reduction of CO2 on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle

Jay Agarwal et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2011)

Article Materials Science, Multidisciplinary

Berry-phase treatment of the homogeneous electric field perturbation in insulators

RW Nunes et al.

PHYSICAL REVIEW B (2001)