期刊
ADVANCED ENGINEERING MATERIALS
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adem.202201766
关键词
catalyst manufacturing; honeycombs; impulse excitation; microcracks; Young's modulus
Manufacturing honeycomb-structured catalysts requires understanding the microstructure of the solid substrate and its dependence on thermal-processing conditions. The thermal responses of microcracks in an uncoated microcracked aluminum titanate honeycomb catalyst were investigated by analyzing resonance frequency. Microcracks were observed to have two healing responses: instantaneous and delayed healing, which significantly influence catalyst manufacturing design.
Manufacturing honeycomb-structured catalysts require a careful understanding of the microstructure of the solid substrate and its dependence on thermal-processing conditions. Herein, it is the thermal responses of microcracks in an uncoated microcracked aluminum titanate honeycomb catalyst is investigated by analyzing the material's resonance frequency using the high-temperature impulse excitation technique. The resonance frequencies are presented as Young's modulus values to avoid sample size effects. Dynamic Young's modulus measurements show closed-loop hysteresis due to microcracks healing and reopening, causing a reversible response. The hysteresis is further used to understand microcracks' dependence on critical thermal-processing conditions used in a catalyst manufacturing plant, including peak operating temperature (800-1000 degrees C), dwell period (1-3 h), and heating rates (1-5 degrees C min(-1)). Microcracks are observed to have two healing responses: instantaneous and delayed healing. Both responses significantly influence the design of catalyst manufacturing. Complete reopening of microcracks from their healing temperature (1150 degrees C) is a very time-consuming process (50-60 h). However, it is shown in the analysis that microcrack relaxation is a critical phenomenon that must be considered in quality-controlled environments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据