期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 46, 页码 15142-15145出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b10542
关键词
-
资金
- National Science Foundation [CHE-1253385]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1253385] Funding Source: National Science Foundation
A negative feedback loop that relies on the coordination-coupled deprotonation (CCD) of a hydra zone switch has been developed. Above a particular threshold of zinc(II), CCD releases enough protons to the environment to trigger a cascade of reactions that yield an imine. This imine sequesters the excess of zinc(II) from the hydrazone switch, hence lowering the effective amount of protons, and switching the cascade reactions OFF, thus establishing the negative feedback loop.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据