期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 42, 页码 13866-13869出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b09572
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资金
- Heinz Endowments
- R. K. Mellon Foundation
- National Institutes of Health [GM49970]
- National Science Foundation [CHE1126268]
The unique properties of entirely aliphatic TAML activator [Fe-III{(Me2CNCOCMe2NCO)(2)CMe2}OH2](-) (3), namely the increased steric bulk of the ligand and the unmatched resistance to the acid-induced demetalation, enables the generation of high-valent iron derivatives in pure water at any pH. An iron(V)oxo species is readily produced with NaClO at pH values from 2 to 10.6 without any observable intermediate. This is the first reported example of iron(V)oxo formed in pure water. At pH 13, iron(V)oxo is not formed and NaClO oxidizes 3 to an iron(IV)oxo derivative.
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