相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Article
Chemistry, Multidisciplinary
Shengmei Chen et al.
Summary: The researchers have developed an ultralow-temperature-tolerant zinc air battery by adjusting the structure of conventional KOH electrolyte and developing a low-temperature-tolerant FeCo-PC bifunctional electrocatalyst. The battery can operate at -110 degrees C and shows exceptional performance, including a maximum power density of 61.3 mW cm -2, capacity of 627.9 mAh g-1, and cycling stability of about 140 h at -70 degrees C. This work advances the understanding of antifreezing properties in electrolytes and the design of low-temperature electrocatalysts, contributing to the development of zinc air batteries with enhanced environmental adaptability.
Article
Chemistry, Multidisciplinary
Yao Wang et al.
Summary: In this study, bifunctional electrocatalysts, Fe-Se/NC, were successfully constructed by synthesizing atomically dispersed Fe-Se atom pairs supported on N-doped carbon. The obtained Fe-Se/NC exhibited remarkable bifunctional oxygen catalytic performance with a low potential difference of 0.698 V, surpassing that of previously reported Fe-based single-atom catalysts. Theoretical calculations revealed that the p-d orbital hybridization around the Fe-Se atom pairs resulted in significantly asymmetrical polarized charge distributions. Moreover, Fe-Se/NC-based solid-state rechargeable Zn-air batteries demonstrated superior cycling and stability compared to the traditional Pt/C+Ir/C catalysts, even at extremely low temperatures.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Xiayue Fan et al.
Summary: Flexible aqueous zinc-air batteries (FAZABs) with quasi-solid-state gel polymer electrolytes (QSGPEs) containing sulfonate functionalized nanocomposites exhibit high ionic conductivity, alkali tolerance, and zinc anode stability. The FAZAB shows a long cycling life of 450 hours, making it suitable for powering wearable electronics.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ming Huang et al.
Summary: In this study, a new method is developed to synthesize single-atom catalysts with well-defined Ni-N-4-O catalytic sites, which exhibit high Faradaic efficiency and stability in electrocatalytic CO2 reduction to CO. Experimental and theoretical studies reveal the importance of Ni-O coordination in the performance of the catalytic center.
Article
Chemistry, Multidisciplinary
Siwen Huang et al.
Summary: This study demonstrates a new approach for designing high-performance antifreezing flexible batteries by utilizing the Hofmeister effect and low-concentration salts to regulate the chemical properties of hydrogel electrolytes. The optimized hydrogel electrolyte exhibits excellent flexibility and high ionic conductivity, enabling the zinc-ion battery to achieve good cycling performances even at low temperatures.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Tingting Cui et al.
Summary: The novel dual single-atom catalyst FeMn-DSAC exhibits remarkable bifunctional activities for ORR and OER, enabling efficient operation of the ZAB at ultra-low temperature of -40 degrees C with peak power density of 30 mW cm(-2) and up to 86% specific capacity retention compared to room temperature.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Inorganic & Nuclear
Hui Xu et al.
Summary: Single-atom catalysts offer high reactivity and selectivity, but are susceptible to sintering and agglomerating. Introducing appropriate supports can optimize the local coordination environment and electronic properties, preventing sintering.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Nanoscience & Nanotechnology
Tao Deng et al.
Summary: This study reports a solid electrolyte YSZ@BASE which effectively reduces the interfacial impedance in solid-state sodium batteries and exhibits high critical current density with Na metal anode. By using a trace amount of NaFSI-KFSI molten salt, a high-capacity and cyclically stable full cell has been achieved.
NATURE NANOTECHNOLOGY
(2022)
Article
Chemistry, Physical
Dingqing Jiang et al.
Summary: An organohydrogel electrolyte (OHE) was developed to enhance the performance of flexible zinc-air batteries (ZABs), specifically improving freezing tolerance and energy efficiency.
Article
Nanoscience & Nanotechnology
Ze-Fei Liu et al.
Summary: Optimization of cathode structure and exploration of a novel electrolyte system are important for achieving high-performance zinc-ion batteries and suppressing zinc dendrites. In this study, a quasi-solid-state zinc-ion battery was designed and constructed with a MnO2@rGO cathode, a Lap-modified polyacrylamide hydrogel electrolyte, and an electrodeposited zinc anode. The optimized battery exhibited high reversible capacity, low polarization, excellent electrochemical performance, and flexibility.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Li An et al.
Summary: A surface evolution strategy was applied to change the surface structure of MnCo2O4 oxide, allowing for the switching of reaction pathways from 2e(-) ORR to 4e(-) ORR. Different surface configurations of MnCo2O4 were found to exhibit excellent performance in the oxygen reduction reaction.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jin-Lin Yang et al.
Summary: A polyanionic hydrogel film is introduced as a protective layer on the Zn anode. It balances the transport of zinc ions and effectively suppresses hydrogen evolution and dendrite formation, enabling stable and reversible Zn stripping/plating.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Wei Li et al.
Summary: This study successfully addresses the challenges in engineering non-precious transition metal-based electrocatalysts for achieving optimal intrinsic activity, high density of active sites, and rapid mass transfer ability. The Fe0.5Co@HOMNCP composite catalyst exhibits extraordinary ORR activity and outperforms most Co-based catalysts reported to date. Moreover, it shows superior open-circuit voltage and power density when used as the air electrode in a zinc-air battery compared to a commercial Pt/C + IrO2 catalyst.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Mi Xu et al.
Summary: The construction of safe and environmentally-benign solid-state electrolytes (SSEs) for flexible zinc-air batteries is highly desirable. In this study, hierarchically nanostructured CCNF-PDIL SSEs with reinforced concrete architecture were successfully developed, showing good flexibility, mechanical robustness, and high ion conductivity. The resulting flexible solid-state zinc-air batteries exhibited superior performance compared to state-of-the-art batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Multidisciplinary Sciences
Sailin Liu et al.
Summary: This review examines the failure mechanism of rechargeable zinc metal batteries under temperature influence, presents current electrolyte strategies for improving battery performance in harsh temperatures, and offers perspectives on their industrial application.
Article
Chemistry, Physical
Runze Li et al.
Summary: This article discusses the key factors affecting the catalytic performance of metal-based atomically dispersed catalysts and their relationship with the active sites. It first introduces the effectiveness of active site design through coordination effects, then discusses the role of chemical bonds in the active sites and the influence of the spacing of active atoms in intermetallic compounds on catalytic behavior. Additionally, the importance of synergistic effects in catalyst design is emphasized, and the key parameters affecting catalytic performance at the atomic scale are summarized.
Article
Multidisciplinary Sciences
Qichen Wang et al.
Summary: In this study, a high-rate and robust performance is achieved in quasi-solid-state Zn-air batteries using a single-atom catalyst and an organohydrogel electrolyte. A cycling current density of 100 mA cm(-2) at 25 degrees C and a broad temperature adaptability of -60 to 60 degrees C are demonstrated.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Qingqing Liu et al.
Summary: A dual-network structured hydrogel electrolyte composed of PAM, SA, and KI has been developed for solid-state zinc-air/iodide hybrid batteries, showing improved mechanical strength, increased ionic conductivity, excellent renewability, and a long cycling life of 110 hours with high energy efficiency of 80%. The introduction of iodine species not only enhances cathodic kinetics but also regulates the solvation structure of zinc ions for better interface stability, providing significant concepts for developing high-performance energy devices and technologies.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Chenliang Ye et al.
Summary: In this study, an electrical pulse method was used to synthesize atomically dispersed Pt on nitrogen-doped carbon support. The Pt-1-FeOx/CN catalyst exhibited high activity for oxygen reduction reaction (ORR) due to optimal OH* adsorption strength achieved by tuning the size of iron oxide clusters. The unique structure and high catalytic performance of Pt-1-FeOx/CN enabled excellent performance in Zinc-Air batteries at ultralow temperature.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Multidisciplinary
Xiayue Fan et al.
Summary: This paper comprehensively reviews the fundamentals and relationships of semi-solid/solid electrolytes in flexible and portable energy devices. The latest advancements in improving the performance of these devices and strategies for overcoming technical challenges are summarized. Several possible directions for future research and development are proposed to achieve desirable flexible and portable electrochemical energy devices.
Article
Chemistry, Multidisciplinary
Xiao Liang et al.
Summary: Single-atom-site catalysts are a highly prosperous branch of catalysis research that have made tremendous progress in recent years. The major goal of research is to establish feasible synthetic strategies for preparing high-performance catalysts, understand the active-site structures and catalytic mechanisms, and develop practical catalysts with industrial value.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Jianyi Li et al.
Summary: Tuning the structure of the catalyst's active center to the atomic level is crucial for efficient utilization of the active component, especially for precious metals. In this study, atomic Ir was introduced into LaNiO3 perovskite oxide using the liquid phase ion exchange method, resulting in excellent catalytic performance in the oxygen evolution reaction (OER). The addition of Ir significantly enriched the surface electron density, improving electron transfer and stable adsorption of intermediates. The strong interactions in Ni-O-Ir led to superior overpotential and efficiency in the OER process. Additionally, the presence of Ir inhibited a lattice oxygen oxidation mechanism (LOM), ensuring the catalyst's stability in alkaline conditions.
Article
Chemistry, Physical
Wentao Zhang et al.
Summary: This study proposes a kinetics-boosted strategy for Zn2+ transport and desolvation by engineering a zwitterionic hydrogel electrolyte. The modified electrolyte shows improved electrochemical performance and cyclability for Zn anodes.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Qujiang Sun et al.
Summary: This study reveals the mechanism of solvent molecular interaction on battery performance, designs a new electrolyte to stabilize alloying anodes, and demonstrates the impact of different solvation structures on electrochemical properties, achieving superior battery performances.
ACS ENERGY LETTERS
(2022)
Article
Materials Science, Multidisciplinary
Hongyu Jing et al.
Summary: This review comprehensively outlines the latest progress of theory-guided design of advanced energy transformation materials, with a focus on the study of single atoms in various power devices and electrocatalytic conversion reactions related to energy. The electronic structure, interaction mechanism, and reaction activation path are discussed, and experimental synthesis strategies, structural recognition, and electrocatalytic performance are determined. Some viewpoints into the current issues and future design concept are also provided.
ADVANCED POWDER MATERIALS
(2022)
Article
Electrochemistry
Qingqing Liu et al.
Summary: Polymer-based electrolytes play a critical role in zinc-air batteries, improving their performance. This article reviews the recent progress in polymer-based electrolytes for zinc-air batteries and proposes future challenges and viable strategies.
Review
Chemistry, Physical
Jiao Wu et al.
Summary: The rapid development of wearable devices has increased the demand for stable, solid-state, flexible, and even stretchable energy storage systems. Zinc-air batteries (ZABs), especially high-safety ones, have attracted attention due to their high specific energy density. However, the performance of ZABs severely deteriorates at low temperatures due to reduced ionic conductivity and sluggish kinetics. Gel polymer electrolytes (GPEs) designed with superior mechanical performance and accelerated ion transport have shown potential to enhance the electrochemical performance of ZABs at low temperatures. This review provides insights into the rational design of GPEs for ZABs and their potential applications in other energy storage systems.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Chemistry, Physical
Yanan Wang et al.
Summary: Doping of semiconductors is essential for modern electronics and optoelectronics, and surface charge transfer doping is emerging as an effective and reliable technique for 2D materials, especially 2D semiconductors. The recent advances and developments in SCTD for 2D semiconductors, as well as its application in electronic and optoelectronic devices, have been summarized.
Article
Chemistry, Multidisciplinary
Wenpeng Ni et al.
Summary: By coupling with single-atom Fe-N-4 sites, the activity of intrinsic carbon defects can be significantly improved, leading to remarkable enhancements in electrocatalytic performance for CO2 reduction. The resulting catalyst shows high CO Faradaic efficiency, CO selectivity, and current density, demonstrating great potential for the development of rechargeable Zn-CO2 batteries.
ADVANCED MATERIALS
(2021)
Article
Multidisciplinary Sciences
Wei Sun et al.
Summary: The study presents a zinc-O-2/zinc peroxide chemistry that operates through a 2e(-)/O-2 process in nonalkaline aqueous electrolytes, allowing highly reversible redox reactions in zinc-air batteries. This innovative ZnO2 chemistry, enabled by water-poor and zinc ion (Zn2+)-rich inner Helmholtz layer, shows superior reversibility and stability compared to alkaline zinc-air batteries.
Article
Chemistry, Multidisciplinary
Chang-Xin Zhao et al.
Summary: This study reveals the potential advantages of zinc-air batteries for low-temperature energy storage and demonstrates improved performance by regulating the electrolyte structure. The stable performance achieved under extreme low temperatures provides inspiration for the development of advanced battery systems for extreme working conditions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Multidisciplinary Sciences
Gege Yang et al.
Summary: The research uncovered the mechanism of the oxygen reduction reaction on dual-metal atomically dispersed Fe,Mn/N-C catalyst, demonstrating its excellent performance and durability in fuel cells and metal-air batteries.
NATURE COMMUNICATIONS
(2021)
Article
Energy & Fuels
Sambhaji S. Shinde et al.
Summary: Researchers report a cell-level design for all-solid-state zinc-air pouch cells with exceptionally high energy density and cycle lifespan.
Article
Chemistry, Multidisciplinary
Jia Yang et al.
Summary: The study demonstrates that strain engineering of curved single atomic iron-nitrogen sites can significantly enhance electrocatalytic activity. The introduction of high-curvature surface with compressive strain on Fe-N-4 sites leads to downshifted d-band center, reducing the bonding strength between oxygenated intermediates and metal sites, resulting in a lower energy barrier for oxygen reduction. Catalytic tests show a 31-fold increase in kinetic current density for curved Fe-N-4 sites compared to planar ones in alkaline media.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Physical
Siyuan Zhao et al.
Summary: Zinc-based batteries with hydrogel electrolytes are promising for flexible energy storage due to their high capacity, low cost, and safety features. However, research on these batteries under extreme conditions is still in the early stages, with many technical issues remaining to be addressed. Design strategies for hydrogel electrolytes suitable for use in all extreme conditions are proposed, along with a discussion on the challenges and future directions of hydrogel electrolytes for zinc-based batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Caihong Yang et al.
Summary: Layered nanoclay plays a crucial role in improving energy storage and conversion systems efficiency in a low-carbon economy. With its unique characteristics, it shows great potential in various applications such as rechargeable batteries, supercapacitors, and beyond.
Article
Chemistry, Multidisciplinary
Wang Xin et al.
ADVANCED MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Zengxia Pei et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Review
Chemistry, Multidisciplinary
Qi Zhang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Nanoscience & Nanotechnology
Yu Xiong et al.
NATURE NANOTECHNOLOGY
(2020)
Article
Chemistry, Multidisciplinary
Jie Yin et al.
ADVANCED MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Huishan Shang et al.
Review
Chemistry, Multidisciplinary
Jiarui Yang et al.
ADVANCED MATERIALS
(2020)
Article
Chemistry, Physical
Xiayue Fan et al.
Article
Chemistry, Multidisciplinary
Li An et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2019)
Article
Multidisciplinary Sciences
Zhiyan Chen et al.
Article
Chemistry, Physical
Qichen Wang et al.
ACS ENERGY LETTERS
(2018)
Review
Chemistry, Multidisciplinary
Jin Yi et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2018)
Article
Chemistry, Multidisciplinary
Rui Jiang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Multidisciplinary
Li An et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Physical
Jiazhan Li et al.
Article
Chemistry, Physical
Huilong Fei et al.
Article
Materials Science, Biomaterials
Yun Tan et al.
JOURNAL OF MATERIALS CHEMISTRY B
(2015)
