期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 99, 期 9, 页码 3159-3166出版社
WILEY
DOI: 10.1111/jace.14332
关键词
oyster shell-volcanic ash; alkali activation; heat treatment; calcium silicate hydrate; gel composition
资金
- World Academy of Sciences (TWAS) [N 13-018 RG/CHE/AF/AC G-UNESCO FR: 3240277723]
- Bureau Afrique Centrale et des Grands Lacs de l'Agence Universitaire de la Francophonie (BACGL-AUF) [NS0020*** 10406]
The gel composition and mechanical properties of alkali-activated oyster shell-volcanic ash were investigated at different NaOH concentrations (8, 12, and 15M) and curing temperatures (60 degrees C and 80 degrees C) in wet and dry conditions. XRD, FTIR, SEM-EDS, and TGA-DSC were used for microstructural characterization of the binder. The gel composition of the system was found to be influenced by NaOH concentration and was not affected when curing temperature was varied from 60 degrees C to 80 degrees C. The main phase was N, C-A-S-H for all alkali-activated oyster shell-volcanic ash, with C-S-H as secondary phase for some samples and contains high percentage of iron. The splitting at nu(3) = 1400-1494 cm(-1) on FTIR spectra corresponded to the elimination of the degeneracy due to the distortion of CO32- group. The high degree of splitting indicated that this carbonate group is linked to Ca2+. The compressive strength was influenced by curing temperature and the formation of a secondary phase. The compressive strength in dry condition increased roughly between 28 and 180 d for some samples, while in wet condition, the partial dissolution of Si-O-Si bonds of some silicate phases resulted in a reduction of strength.
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