期刊
ADVANCED MATERIALS
卷 27, 期 45, 页码 7380-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201503951
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资金
- Welch Foundation [E-1457]
- NSF [DMR-1503573]
- National Science Foundation [DMR-1454688]
- U.S. DOE, Office of Basic Energy Sciences (BES) [DE-AC02-06CH11357]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1454688, 1503573] Funding Source: National Science Foundation
Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba-3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.
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