期刊
CIS IRON AND STEEL REVIEW
卷 24, 期 -, 页码 9-16出版社
ORE & METALS PUBLISHERS
DOI: 10.17580/cisisr.2022.02.02
关键词
petroleum coke; coking coals; petroleum coke additive; delayed coking; metallurgical coke; petroleum residues
资金
- [0792-2020-0010 ?]
This article introduces petroleum coke as a potential replacement for coking coals in the production of metallurgical coke, and presents experimental research results on the manufacture of petroleum coke additive using different sulfuric petroleum residues. The study found that the input parameters of the coking process have an impact on the composition and properties of the carbon materials obtained. Evaluation and ranking of the obtained samples were conducted based on the content and chemical composition of the petroleum coke additive. Furthermore, infrared spectra were used to interpret the characteristics of the samples.
Petroleum coke is a potential partial replacement of coking coals (being in short supply) in manufacture of metal-lurgical coke; in Russia and other CIS countries it was entitled as petroleum coking additive (PCA), petroleum coke with output of volatile substances within the range 15-25 %. The second part of the work describes the results of conducted experimental researches in the field of manufacture of petroleum coke additive on the example of use of two kinds of sulfuric petroleum residues of KINEF JSC as raw materials: residue of atmospheric distil-lation and mixture of residues of vacuum distillation and visbreaking. The research was conducted for two tem-perature procedures within the ranges 455-465 and 475-485 degrees C. Eight samples of carbon material were obtained as a result of conversion, and influence of input parameters of the coking process on composition and physical-chem-ical properties of obtained carbon materials was established. Based on content of volatile substances in petrole-um coke additive and its group chemical composition, which was determined via extraction method (content of a-, 0-and y-fractions) and via infrared Fourier spectroscopy, assessment and ranging of the eight obtained PCA samples were carried out by their sintering susceptibility. Interpretation of infrared spectra of obtained PCA samples was conducted via comparison with infrared spectra of coking coal, which have identical absorption stripes. Rela-tion between PCA sintering ability and procedure parameters of the coking process was revealed. It was determined that technological process occurring at the less coking temperature 455-465 degrees C provides high quality PCA forming, otherwise the procedure with higher temperature (475-485 degrees C).
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