期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 238, 期 -, 页码 68-73出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2016.03.013
关键词
CZTS powder; Mechanochemical synthesis; Neutron scattering; Cation distribution; Rietveld refinement; Order-disorder transition
资金
- MatSEC graduate school of the Helmholtz Zentrum Berlin (HZB)
- Dahlem Research School
In this work a series of stoichiometric Cu2ZnSnS4 (CZTS) samples annealed at different temperatures in the range of 473-623 K were investigated. The temperature dependence of the Cu/Zn-order-disorder behavior was analyzed by neutron powder diffraction measurements. Cu fully occupies the 2a and Sn the 2b position within the whole temperature range. For Zn and the remaining Cu on sites 2d and 2c, a clear change from ordered to disordered kesterite structure is found. The critical temperature T-c for this Landau-type second order transition was determined as 552 +/- 2 K. It was found that in Cu2ZnSnS4 very long annealing times are necessary to reach equilibrium at low temperatures. (C) 2016 Elsevier Inc. All rights reserved.
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