4.8 Article

A Pseudo-Regular Alternating Conjugated Copolymer Using an Asymmetric Monomer: A High-Mobility Organic Transistor in Nonchlorinated Solvents

期刊

ADVANCED MATERIALS
卷 27, 期 24, 页码 3626-3631

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201500335

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资金

  1. Center for Advanced Soft Electronics under the Global Frontier Research Program of the Ministry of Science, ICT and Future Planning, Korea [2011-0031628, 2012M3A6A5055225]
  2. National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2012047047]
  3. National Research Foundation of Korea [2012M3A6A5055225, 2011-0031628] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Pseudo-regular alternating PDPP-TVS copolymers using an asymmetric monomer (thiophene-vinylene-selenophene (TVS)) are synthesized. Unlike regular alternating copolymers, these polymers are highly soluble in nonchlorinated solvents such as tetrahydrofuran, toluene, xylene, and tetralin. The organic field-effect transistor devices fabricated using these polymers dissolved in nonchlorinated solvents exhibit a high hole mobility up to 8.2 cm(2) V-1 s(-1).

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