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Recent Advances on Challenges and Strategies of Manganese Dioxide Cathodes for Aqueous Zinc-Ion Batteries

ENERGY & ENVIRONMENTAL MATERIALS (2023)

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Article Materials Science, Multidisciplinary

Unraveling the Role of Nitrogen-Doped Carbon Nanowires Incorporated with MnO2 Nanosheets as High Performance Cathode for Zinc-Ion Batteries

Xiaohui Li et al.

Summary: The study investigates the mechanism of the composite interaction between manganese-based cathode materials and nitrogen-doped carbon, revealing the role of nitrogen-doped carbon in elongating the Mn-O bond and reducing the valence of Mn4+ ions. This leads to improved electrochemical performance of manganese-based cathode materials.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

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Article Materials Science, Multidisciplinary

Promoting Proton Migration Kinetics by Ni2+ Regulating Enables Improved Aqueous Zn-MnO2 Batteries

Jie Ji et al.

Summary: In this study, the introduction of Ni2+ into γ-MnO2 is proposed to promote proton migration kinetics, resulting in improved energy storage performance for aqueous Zn-MnO2 batteries.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

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Review Electrochemistry

The Trade-Offs in the Design of Reversible Zinc Anodes for Secondary Alkaline Batteries

Honglin Luo et al.

Summary: Zinc-based batteries face limitations in cycling performance due to issues like zinc dendrite formation, electrode deformation, corrosion, and hydrogen evolution. Researchers have developed strategies such as surface coating, additives, and structure design to address these problems, but trade-offs must be considered due to intertwined core factors restricting the reversibility of zinc electrodes.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

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Article Nanoscience & Nanotechnology

Enabling Reversible MnO2/Mn2+ Transformation by Al3+ Addition for Aqueous Zn-MnO2 Hybrid Batteries

Zengming Qin et al.

Summary: A new Zn-MnO2 hybrid battery using Al3+ in the sulfate-based electrolyte is proposed, which exhibits excellent electrochemical performance and cycle life while avoiding environmental hazards and corrosion of the Zn anodes.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Review Chemistry, Multidisciplinary

Fast Ionic Storage in Aqueous Rechargeable Batteries: From Fundamentals to Applications

Meng Huang et al.

Summary: The highly dynamic nature of grid-scale energy systems requires fast kinetics in energy storage and conversion systems. Rechargeable aqueous batteries, with their high ionic diffusivity, safety, and low cost, are a promising solution for energy storage in renewable-energy grids. Recent research has focused on developing electrode materials that enable fast ionic storage in aqueous electrolytes. This review summarizes breakthroughs in fast ionic storage in aqueous battery materials, including 1D/2D/3D and over-3D tunnel materials.

ADVANCED MATERIALS (2022)

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Article Engineering, Environmental

In-situ electrochemical induced artificial solid electrolyte interphase for MnO@C nanocomposite enabling long-lived aqueous zinc-ion batteries

Shuyue Li et al.

Summary: In this study, an in-situ electrochemical induced artificial solid electrolyte interphase (SEI) was discovered to prevent the excessive dissolution of manganese oxides in rechargeable aqueous zinc-ion batteries (AZIBs), leading to an extremely excellent cycle performance with minimal capacity decay. This strategy provides a new proposal to develop high stable manganese oxide cathodes for AZIBs.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Electrochemistry

Optimized cyclic durability of α-MnO2 nanosheets for zinc ion storage through synergistic effect of lithium ions pre-embedding and electrolyte additives

Min Wang et al.

Summary: This study proposes an effective strategy to improve the cyclic stability and specific capacity of rechargeable aqueous Zn/MnO2 batteries through the synergistic effect of lithium ions pre-embedding and electrolyte additives. The results show that the lithium pre-embedded samples exhibit higher reversible capacity, outstanding cyclic stability, and promising rate performance. Furthermore, the addition of Li2SO4 additive enhances the cyclic stability and capacity of the battery.

ELECTROCHIMICA ACTA (2022)

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Article Chemistry, Inorganic & Nuclear

Thermal stability of MnO2 polymorphs

Takuya Hatakeyama et al.

Summary: This study investigates the thermal stability of alpha, beta, gamma, delta, and lambda-type MnO2 polymorphs using DSC and HTXRD. Results show that the thermal stability order of the polymorphs is beta > alpha > gamma > delta approximate to lambda. The structure and phase transformations of each phase under high temperature conditions are discussed in relation to the bonding environment of oxide ions.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Article Materials Science, Multidisciplinary

N/Br co-doped C coating Zn2VO4 as excellent electrochemical performance cathode material for aqueous zinc ion batteries

Liping Qin et al.

Summary: Rechargeable aqueous zinc-ion batteries have the potential to be a cost-effective and safe solution for large-scale energy storage. However, the development of this technology has been hindered by the strong electrostatic forces between zinc ions and the host material, as well as the low conductivity and slow ion diffusion kinetics of cathode materials. In this study, a N/Br co-doped C source was successfully used to prepare a Zn2VO4 coating, which improved the electrical conductivity and electrochemical activity of the material. The coated material showed high capacity and cyclic stability, as well as fast ionic diffusion and excellent charge transfer kinetics.

MATERIALS LETTERS (2022)

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Article Chemistry, Applied

MnO2 cathode materials with the improved stability via nitrogen doping for aqueous zinc-ion batteries

Yanan Zhang et al.

Summary: The nitrogen-doped MnO2@N cathode prepared through defect engineering greatly improves the cycle stability of manganese-based aqueous zinc-ion batteries by enhancing conductivity and electrochemical stability, leading to a high capacity retention rate. In addition, nitrogen doping promotes the diffusion of H+ and Zn(2+), resulting in enhanced battery performance.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Stable Manganese-Oxide Composites as Cathodes for Zn-Ion Batteries: Interface Activation from In Situ Layer Electrochemical Deposition under 2 V

Inmaculada Alvarez-Serrano et al.

Summary: A set of multiphase manganese-oxide composite materials and a birnessite-type KxMnO2 oxide were prepared and evaluated as cathodes for Zn-ion batteries. The results showed that these materials enhanced the electrochemical response. It was found that a zinc salt formed a phase coating on the composite electrodes during the charging stage, contributing to the extended lifetime of the batteries. Additionally, the composite materials and KxMnO2 electrode exhibited excellent performance under different current densities and electrolyte conditions.

ADVANCED MATERIALS INTERFACES (2022)

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Article Chemistry, Multidisciplinary

Advanced Zinc Anode with Nitrogen-Doping Interface Induced by Plasma Surface Treatment

Hao Jia et al.

Summary: This study developed a nitrogen-doped Zn foil as a dendrite-free Zn metal anode with low overpotential and excellent cycling stability, providing new fundamental insights into homogenizing Zn electrodeposition processes and offering a novel direction for engineering ultra-stable Zn metal anodes.

ADVANCED SCIENCE (2022)

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Article Chemistry, Physical

Unveiling performance evolution mechanisms of MnO2 polymorphs for durable aqueous zinc-ion batteries

Yanxin Liao et al.

Summary: The study investigates the performance of MnO2 polymorphs in ZIBs to understand their detailed reaction chemistry and degradation mechanisms. Ex situ characterizations show evolution of active materials and coexisted reactions from co-insertion, dissolution/deposition and chemical conversion mechanisms. Variational contributions from intermediate products and different reaction mechanisms cause fluctuated performance during cycling, with R-MnO2 showing low manganese dissolution and stable capacity under high depth of discharge.

ENERGY STORAGE MATERIALS (2022)

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Article Nanoscience & Nanotechnology

Enriching Oxygen Vacancy Defects via Ag-O-Mn Bonds for Enhanced Diffusion Kinetics of δ-MnO2 in Zinc-Ion Batteries

Xiaohua Pu et al.

Summary: This study investigates the key issues in the cathode materials of ZIBs and successfully addresses the diffusion dynamics and dissolution problems by doping Ag into MnO2, thereby improving the performance of the battery. The results reveal that the superior performance of MnO2-2 is attributed to the enhanced diffusion kinetics of the cathode resulting from the enriched oxygen vacancy defects and the formation of Ag-O-Mn bonds. In addition, the kinetic mechanism of the Zn/MnO2-2 cell can be described as a reversible process of the dissolution/precipitation of the ZHS phase and consequent insertion/extraction of Zn2+ and H3O+. This research provides further insights into the design of manganese-based aqueous ZIB cathode materials and facilitates the development and application of large-scale energy storage systems in the future.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Nanoscience & Nanotechnology

Synergistic Optimization Strategy Involving Sandwich-like MnO2@rGO and Laponite-Modified PAM for High-Performance Zinc-Ion Batteries and Zinc Dendrite Suppression

Ze-Fei Liu et al.

Summary: Optimization of cathode structure and exploration of a novel electrolyte system are important for achieving high-performance zinc-ion batteries and suppressing zinc dendrites. In this study, a quasi-solid-state zinc-ion battery was designed and constructed with a MnO2@rGO cathode, a Lap-modified polyacrylamide hydrogel electrolyte, and an electrodeposited zinc anode. The optimized battery exhibited high reversible capacity, low polarization, excellent electrochemical performance, and flexibility.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Engineering, Environmental

In-situ synthesis of graphdiyne on Mn3O4 nanoparticles for efficient Zn ions diffusion and storage

Quanhu Sun et al.

Summary: This study reports an in-situ chemical synthesis method to prepare Mn3O4-GDY composite material as an electrode material for zinc-ion batteries. The as-prepared composite material shows unique structural and chemical properties, which can improve the cyclic stability and capacity decay issues in batteries. Electrochemical characterization results demonstrate that Mn3O4-GDY material exhibits high reversible capacity and good cycling performance.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Structural Regulation of ZnMn2O4 cathode material by K, Fe-Double doping to improve its rate and cycling stabilityfor rechargeable aqueous zinc-based batteries

Tong Shao et al.

Summary: In this study, the issues of sluggish reaction kinetics and manganese dissolution in aqueous zinc-based batteries are effectively addressed through the double-doping of K and Fe. The doping improves the conductivity of the material and enhances the diffusion of Zn2+, leading to higher specific capacity and better capacity retention. The strategy proposed in this work provides another example for the practical application of manganese-based materials in aqueous zinc-based batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Layered manganese dioxide nanoflowers with Cu2+and Bi3+ intercalation as high-performance cathode for aqueous zinc-ion battery

Fengni Long et al.

Summary: In this study, two cathode materials with nanoflower structures, Cu0.06MnO2·1.7H2O (CuMO) and Bi0.09MnO2·1.5H2O (BiMO), have been successfully designed for high-performance AZIBs. The layered structures of these materials are sustained by pre-intercalated metal ions and water molecules, improving their stability. CuMO exhibits excellent electronic conductivity and remarkable specific capacities, while BiMO demonstrates long-term cycling stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Electrochemistry

Construction of Novel Hierarchical Honeycomb-Like Mn3O4 MnO2 Core-Shell Architecture with High Voltage for Advanced Aqueous Zinc-Ion Batteries

Liangjun Gong et al.

Summary: A hierarchical honeycomb-like Mn3O4@MnO2 core-shell composite is proposed as a robust cathode material for rechargeable aqueous zinc-ion batteries (ZIBs). It exhibits fast ion transport and storage, as well as suppression of volume expansion of the active material, leading to enhanced reaction kinetics and electrochemical performance.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

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Article Chemistry, Multidisciplinary

Construction of Bio-inspired Film with Engineered Hydrophobicity to Boost Interfacial Reaction Kinetics of Aqueous Zinc-Ion Batteries

Qianzhi Gou et al.

Summary: This study employs a bio-inspired approach to enhance the interfacial reaction kinetics and electrode stability of aqueous zinc-ion batteries. By constructing a bio-inspired hydrophobic conductive poly(3,4-ethylenedioxythiophene) film on the cathode, the electrical conductivity of the electrode is improved, the hydrophobicity of the cathode-electrolyte interface is engineered, and the desolvation behavior of hydrated zinc ions is enhanced, leading to improved overall interfacial reaction kinetics and cathode stability.

SMALL (2022)

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Article Chemistry, Applied

Defect-engineered Mn3O4/CNTs composites enhancing reaction kinetics for zinc-ions storage performance

Xiuli Guo et al.

Summary: The reasonable design of nanocomposite materials and introduction of defect engineering are important for improving the electronic conductivity and reaction kinetics of manganese-based compounds. In this study, manganese-deficient Mn3O4 nanoparticles grown on carbon nanotubes (CNTs) were developed as an advanced cathode material for aqueous rechargeable zinc-ion batteries. The cathode exhibited enriched Mn defects and small particle size, enhancing electronic conductivity and promoting fast reaction kinetics. The DMOC electrode showed high capacity and excellent cycle life, making it promising for practical energy storage applications.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Molecular tailoring of MnO2 by bismuth doping to achieve aqueous zinc-ion battery with capacitor-level durability

Yu Ma et al.

Summary: This study proposes a bismuth (Bi) doping technology to improve the structural stability and reaction kinetics of MnO2 as cathode materials in aqueous zinc-ion batteries (ZIBs). The results show that Bi doping enhances the stability of the tunnel structure, electrical conductivity, and weakens the chemical bond strength between Zn2+ and O. The Bi-doped alpha-MnO2 (BMO-6) cathode exhibits excellent cycle life, rate performance, energy density, and mechanical stability, surpassing other reported Mn-based cathodes in aqueous ZIBs.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Physical

Layered MnO2 nanodots as high-rate and stable cathode materials for aqueous zinc-ion storage

Heng Tang et al.

Summary: In this study, novel layered MnO2 nanodots were synthesized and utilized as the cathode material for aqueous zinc-ion batteries/hybrid capacitors (ZIBs/ZICs) for the first time. The delta-MnO2 NDs displayed high specific capacity, impressive rate capacity, large specific energy, and superior durability. The H+/Zn2+ co-insertion energy storage mechanism of the cathode was also verified. The quantization design strategy provides a new approach for the design and development of advanced cathodes for aqueous ZIBs and ZICs.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Physical

Uncovering sulfur doping effect in MnO2 nanosheets as an efficient cathode for aqueous zinc ion battery

Yajun Zhao et al.

Summary: This study proposes sulfur doped MnO2 nanosheets as a high-performance cathode material for zinc-ion batteries, exhibiting large discharge capacity, high rate performance, and long cycle life. The incorporation of sulfur improves the intrinsic electronic conductivity of MnO2 and accelerates reaction kinetics by weakening the electrostatic interactions with Zn(2+) cations. The sulfur doping also induces an amorphous surface with abundant oxygen defects, contributing to additional Zn storage sites with pseudocapacitive behavior.

ENERGY STORAGE MATERIALS (2022)

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Article Engineering, Environmental

Aerogel-structured MnO2 cathode assembled by defect-rich ultrathin nanosheets for zinc-ion batteries

Yang Li et al.

Summary: In this study, we report the scalable synthesis of an aerogel-structured MnO2 (A-MnO2) assembled by defect-rich ultrathin nanosheets for ZIBs. The A-MnO2 exhibits enhanced electrical conductivity and decreased Zn2+ diffusion energy barrier through V doping and its induced oxygen vacancies, and the ultrathin nanosheets-assembled aerogel structure favors the exposure of more electrochemically active sites and shortens the ion diffusion distance.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Ultrathin ?-MnO2 nanosheets branched onto N-doped carbon nanotubes as binder-free cathode electrodes for aqueous zinc-ion batteries with a high areal capacity

Mincai Zhao et al.

Summary: This study rational synthesized a binder-free cathode material, ultrathin birnessite-type delta MnO2 nanosheets branched onto N-doped carbon nanotubes grown on a carbon cloth substrate (CC/NCNTs/delta MnO2), for aqueous zinc-ion batteries (ZIBs). The CC/NCNTs/delta-MnO2 cathode showed high electrical conductivity, large specific surface area, abundant active sites, fast ion diffusion, good structural stability, and it was free of any polymer binders. Its performance as a binder-free cathode electrode for aqueous ZIBs exhibited high areal capacity, energy density, rate capability, and cycling stability.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Physical

Dual ions intercalation drives high-performance aqueous Zn-ion storage on birnessite-type manganese oxides cathode

Fengyang Jing et al.

Summary: This study improves the Zn2+ transport and structural stability of aqueous zinc-ion batteries by introducing magnesium and potassium ions, achieving outstanding electrochemical performance with ultrahigh reversible capacity and excellent cycling stability.

ENERGY STORAGE MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Interfacial Designing of MnO2 Half-Wrapped by Aromatic Polymers for High-Performance Aqueous Zinc-Ion Batteries

Yi Zhao et al.

Summary: This study presents a novel organic/inorganic hybrid cathode of carbon-based poly(4,4'-oxybisbenzenamine)/MnO2 for aqueous zinc-ion batteries. The interfacial design between PODA chains and MnO2 enhances ion and electron mobility, prevents Mn atom dissolution, and improves redox kinetics and structural integrity of MnO2. The C@PODA/MnO2 cathode exhibits high capacity, superior rate performance, and excellent cycling stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Engineering, Environmental

Mn3O4-stabilized multiphase manganese oxides with micron cage structure for high-performance AZIBs

Tingting Li et al.

Summary: This study presents a multiphase Mn-based oxide cathode with porous heterostructures for aqueous zinc ion batteries (AZIBs). The cathode exhibits high reversible specific capacity and superior rate capability, attributed to its facile charge transfer channel and ions insertion, as well as the phase stability facilitated by the synergistic effects of N-doping, heterojunction, and porous micron cage. Additionally, the application of a novel water-soluble binder (LA133) in AZIBs shows promise for practical use.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Interface regulated MnO2/Mn2+ redox chemistry in aqueous Zn ion batteries

Haoyu Li et al.

Summary: Due to the goal of carbon neutrality, rechargeable aqueous Zn-MnO2 batteries have been gaining attention. However, there is still controversy surrounding the reaction process and influence factors of beta-MnO2 cathodes. This work proposes a complete MnO2/Mn2+ redox chemistry to explain the abnormal electrochemical behaviors of beta-MnO2 cathodes and reveals the effects of interfacial environment in regulating the electrochemical reactions, providing new insights into the working mechanism of aqueous Zn-MnO2 batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Multidisciplinary

Material Design and Energy Storage Mechanism of Mn-Based Cathodes for Aqueous Zinc-Ion Batteries

Shiyin Xie et al.

Summary: This article provides an overview of Mn-based cathode materials for aqueous zinc-ion batteries (ZIBs) and introduces strategies to address the issues associated with these materials. The authors attempt to establish internal relations between different factors and provide new perspectives on future efforts.

CHEMICAL RECORD (2022)

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Dual metal ions and water molecular pre-intercalated d-MnO2 spherical microflowers for aqueous zinc ion batteries

Shihao Zhou et al.

Summary: In this study, layered delta-MnO2 with improved structural stability and enhanced ion migration rate was prepared by pre-intercalating Al3+. The material exhibited high reversible specific capacity and excellent stability in aqueous zinc ion batteries.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Electrochemical Property of Solid-State MnO2-Zn Battery with the Combination of Improved Cathode and Solid Electrolyte

Patrick Dedetemo Kimilita et al.

Summary: A novel aqueous zinc-ion battery using a solid-state electrolyte based on polyacrylamide hybridized with layered double hydroxide was developed, exhibiting excellent performance with high capacity and good cycle retention.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Universal multifunctional hydrogen bond network construction strategy for enhanced aqueous Zn2+/proton hybrid batteries

Ming Li et al.

Summary: This study proposes a strategy for constructing a multifunctional intramolecular hydrogen bond network, addressing the challenges of structural damage, dissolution, conductivity, and ion diffusion kinetics in aqueous rechargeable zinc-ion batteries. The strategy demonstrates significant improvements in electrochemical performance, providing new opportunities for enhancing the energy density of other types of aqueous batteries in the future.

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Electrolyte additive engineering for aqueous Zn ion batteries

Yifei Geng et al.

Summary: Aqueous Zn ion batteries (AZIBs) are a promising electrochemical energy storage device. Additive engineering is an innovative and flexible technology that effectively solves the challenges faced by AZIBs cathode and anode. This review summarizes the effects of additive engineering on cathode and anode, as well as the influence on charge storage mechanism and kinetic characteristics of AZIBs.

ENERGY STORAGE MATERIALS (2022)

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Highly Zn2+-conductive and robust modified montmorillonite protective layer of electrodes toward high-performance rechargeable zinc-ion batteries

Yong Wang et al.

Summary: A novel coating layer has been designed for the zinc anode and MnO2 cathode of rechargeable zinc-ion batteries (ZIBs) to address the issues of corrosion, parasitic side-reactions, and dendrite formation. This coating layer, called ZnOMMT, effectively reduces corrosion and dissolution, while also providing a selective pathway for fast ion transfer and inhibiting side-reactions and dendrite generation. Experimental results demonstrate that ZIBs with the ZnOMMT coating layer exhibit enhanced performance, including outstanding cyclic stability and reversible capacity.

ENERGY STORAGE MATERIALS (2022)

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a, b,1,**, c, 1, d, a, c, b, c, b, e, e,*, c,*, b, e, **

Zhenghui Pan et al.

Summary: In this study, a 3D ZnOHF nanowire array interface was in-situ built on Zn foil through a hydrothermal method, and used as a Zn2+ ion modulation layer to guide the reversible and long-cycling Zn plating/stripping processes. The ZnOHF NWs@Zn anode demonstrated a low Zn nucleation overpotential, high Zn storage capacity, and excellent coulombic efficiency, and showed outstanding cycle stability.

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A polyaniline surface-modified Prussian blue analogue cathode for flexible aqueous Zn-ion batteries

Qifan Liu et al.

Summary: A modification strategy of polyaniline (PANI) coating on zinc ferricyanide (ZnHCF) is proposed to inhibit the dissolution of ZnHCF and achieve two stable discharge voltage platforms and high capacity in Zn-ion batteries. The battery also exhibits high stretchability and maintains stable electrochemical properties during stretching.

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Towards the practical application of Zn metal anodes for mild aqueous rechargeable Zn batteries

Ning Dong et al.

Summary: This article discusses some overlooked but critically important issues in rechargeable aqueous Zn batteries, including the relationship between coulombic efficiency and lifespan of Zn anodes, the control of pH environment near Zn anodes, the design of appropriate aqueous separators, and the estimation of practical energy density for aqueous Zn batteries. The article concludes that an energy density of 60-80 W h kg(-1) should be realistic in practice with suitable cell design.

CHEMICAL SCIENCE (2022)

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Article Chemistry, Inorganic & Nuclear

Calcium-intercalated birnessite MnO2 anchored on carbon nanotubes as high-performance cathodes for aqueous zinc-ion batteries

Weiwei Wang et al.

Summary: In this study, a new cathode material for aqueous Zn-ion batteries (ZIBs) was developed, exhibiting high specific capacity and long cycle life. The material consists of calcium-intercalated MnO2 and carbon nanotubes, with external calcium intercalation enabling fast ionic migration and internal carbon nanotubes providing enhanced electrical conductivity.

DALTON TRANSACTIONS (2022)

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Article Engineering, Environmental

Manipulating intercalation-extraction mechanisms in structurally modulated 6-MnO2 nanowires for high-performance aqueous zinc-ion batteries

Rongguo Zhang et al.

Summary: This study demonstrates a structural modulation strategy by Cu2+ intercalation to manipulate the electrochemical reaction mechanism in layered 6-MnO2, resulting in rapid and reversible zinc ion storage. The findings address the challenges of low capacity and poor cycling stability in manganese-based materials and provide a new approach for the development of cathode materials for zinc-ion batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Electrochemistry

Block Copolymer-Derived Porous Carbon Fibers Enable High MnO2 Loading and Fast Charging in Aqueous Zinc-Ion Battery

Dong Guo et al.

Summary: Rechargeable aqueous Zn MnO2 batteries are attractive due to their high energy density, safety, environmental friendliness, and low cost. However, the low electrical conductivity of binders and the thickness of MnO2 still limit the fast-charging performance.

BATTERIES & SUPERCAPS (2022)

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Review Electrochemistry

Prussian Blue Analogues as Electrodes for Aqueous Monovalent Ion Batteries

Shen Qiu et al.

Summary: This review introduces the recent progress of Prussian blue analogues for aqueous monovalent ion batteries, including metal ions of Li+, Na+, K+, and non-metal ions of H+ and NH4+.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

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Article Chemistry, Applied

β-MnO2 with proton conversion mechanism in rechargeable zinc ion battery

Wenbao Liu et al.

Summary: The study investigated the reaction mechanism of nanorod beta-MnO2 in aqueous zinc ion battery, providing a new perspective for the development of Zn//MnO2 battery chemistry.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

Discharging Behavior of Hollandite α-MnO2 in a Hydrated Zinc-Ion Battery

Thanh Le et al.

Summary: The study systematically investigated the initial discharge process of α-MnO2 cathode in a hydrated environment using DFT and experiments, revealing the essential role of water in the discharge process; DFT calculations suggest that both protons and zinc ions contribute to the discharge potentials of α-MnO2 observed experimentally.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Recent Development of Mn-based Oxides as Zinc-Ion Battery Cathode

Wen Shi et al.

Summary: This article systematically summarizes the recent progress of Mn-based oxides as ZIB cathodes, including the classification based on different oxidation states, the respective polymorphs used as ZIB cathodes, commonly employed modification strategies to enhance performance, and the effects of these strategies on performance enhancement.

CHEMSUSCHEM (2021)

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Al-Intercalated MnO2 cathode with reversible phase transition for aqueous Zn-Ion batteries

Cong Chen et al.

Summary: The novel Al-intercalation engineering of MnO2 cathode for aqueous ZIBs significantly improves specific capacity and cycling retention, demonstrating great potential for applications in energy technologies and portable/wearable electronics.

CHEMICAL ENGINEERING JOURNAL (2021)

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Facile synthesis λ-MnO2 spinel for highly effective catalytic oxidation of benzene

Lei Li et al.

Summary: Porous lambda-MnO2 with spinel structure was successfully synthesized and applied for benzene oxidation, showing superior catalytic activity. The catalyst's performance is attributed to its large surface area, strong redox ability, and abundant surface-active oxygen species.

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Synthesis of three-dimensional β-MnO2/PPy composite for high-performance cathode in zinc-ion batteries

Xiaobo Liao et al.

Summary: In this study, a beta-MnO2/polypyrrole (PPy) composite was successfully synthesized and showed higher specific discharge capacity and rate performance in aqueous zinc-ion batteries, attributed to the high conductivity of PPy nanowires and the 3D mesoporous microsphere structure assembled by beta MnO2 nanorods and PPy nanowires.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Physical

MnO nanoparticles with cationic defects encapsulated in nitrogen-doped porous carbon for high-performance aqueous zinc-ion batteries

Bo Yang et al.

Summary: In this study, MnO nanoparticles with cationic defects encapsulated into nitrogen-doped porous carbon were synthesized as a promising cathode material for aqueous zinc-ion batteries. The composite exhibited high specific capacity, long-term cyclic stability, and reversible phase change during cycling, attributed to the improved electrical conductivity of MnO nanoparticles by nitrogen-doped porous carbon. Multiple analysis techniques revealed the ion storage mechanism and irreversible phase transformation of this composite, highlighting its potential for application in aqueous ZIBs.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Multidisciplinary

In Situ Oriented Mn Deficient ZnMn2O4@C Nanoarchitecture for Durable Rechargeable Aqueous Zinc-Ion Batteries

Saiful Islam et al.

Summary: A novel Mn-deficient ZnMn2O4@C nanoarchitecture cathode material for rechargeable aqueous zinc-ion batteries has been developed, showing promising performance with high capacity retention and good electronic conductivity, indicating great potential for practical applications.

ADVANCED SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Inhibition of Manganese Dissolution in Mn2O3 Cathode with Controllable Ni2+ Incorporation for High-Performance Zinc Ion Battery

Dongdong Zhang et al.

Summary: A Ni-doped Mn2O3 cathode has been developed in this study to suppress the dissolution of manganese and improve the electrochemical performance, showing high specific capacity and excellent capacity retention over cycles. The doped Ni effectively stabilizes the Mn2O3 structure, demonstrating a promising strategy for future development of ZIBs.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Sandwich-Like Heterostructures of MoS2/Graphene with Enlarged Interlayer Spacing and Enhanced Hydrophilicity as High-Performance Cathodes for Aqueous Zinc-Ion Batteries

Shengwei Li et al.

Summary: The research successfully increased the MoS2 interlayer spacing and enhanced hydrophilicity by innovatively intercalating graphene into MoS2 layers, forming MoS2/graphene nanocomposites with flower-like structures. These composites showed exceptional high-rate capability and long-term cycling stability, paving a new direction for high-performance cathodes in aqueous zinc-ion batteries.

ADVANCED MATERIALS (2021)

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Article Materials Science, Multidisciplinary

α-MnO2/super-P with conductive carbon network for rechargeable aqueous Zinc ion batteries

Chao Yang et al.

Summary: The alpha-MnO2/super-P composite, synthesized via in-situ hydrothermal method, exhibits excellent discharge capacity and coulombic efficiency in aqueous Zinc ion battery, mainly due to the short diffusion path of Zn2+ and the largescale conductive network of conductive carbon (super P) particles.

MATERIALS LETTERS (2021)

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Article Chemistry, Applied

Molten salt synthesis of α-MnO2/Mn2O3 nanocomposite as a high-performance cathode material for aqueous zinc-ion batteries

Aixiang Huang et al.

Summary: Nanostructured manganese oxides synthesized by molten salt method exhibit excellent electrochemical performance in aqueous zinc-ion batteries, with significantly improved rate capability and cyclability by modifying the Zn anode.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Physical

Precise Proton Redistribution for Two‐Electron Redox in Aqueous Zinc/Manganese Dioxide Batteries (Adv. Energy Mater. 41/2021)

Zhaoxi Shen et al.

Advanced Energy Materials (2021)

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Article Chemistry, Physical

Self-initiated coating of polypyrrole on MnO2/Mn2O3 nanocomposite for high-performance aqueous zinc-ion batteries

Aixiang Huang et al.

Summary: By applying a novel strategy to generate a thin layer of polypyrrole onto the surface of MnO2/Mn2O3 nanocomposite, this study significantly enhances the electronic conductivity and stability of Mn-based cathode materials, leading to improved capacity and cycling performance in rechargeable aqueous zinc-ion batteries.

APPLIED SURFACE SCIENCE (2021)

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Article Electrochemistry

Boosted charge transfer in oxygen vacancy-rich K+ birnessite MnO2 for water oxidation and zinc-ion batteries

MengXian Lin et al.

Summary: In this study, oxygen vacancy-rich K-birnessite MnO2 (KxMnO2) was successfully obtained through plasma processing, demonstrating improved structural stability and ion transport properties. This material can serve as a cathode material for zinc-ion batteries and an electrocatalyst for oxygen evolution reaction, offering a new opportunity for designing low-cost and high-performance electrode materials.

ELECTROCHIMICA ACTA (2021)

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Review Chemistry, Analytical

Storage mechanisms and improved strategies for manganese-based aqueous zinc-ion batteries

Lin Xu et al.

Summary: Aqueous Zn-ion rechargeable batteries are considered promising for large-scale energy storage due to their abundant resources, high security, environmental friendliness, and acceptable energy density. Manganese-based compounds are widely used in AZIBs for their low cost and high theoretical capacity, and these batteries have different energy storage mechanisms when using manganese-based cathode materials. Improving the electrochemical performance of manganese-based positive electrode materials through various strategies can enhance the performance of AZIBs.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Physical

Diffusion-driven fabrication of yolk-shell structured K-birnessite@mesoporous carbon nanospheres with rich oxygen vacancies for high-energy and high-power zinc-ion batteries

Xian-Zhi Zhai et al.

Summary: In this study, yolk-shell structured K-birnessite@mesoporous carbon nanospheres with rich oxygen vacancies were successfully synthesized for the first time, showing excellent electrochemical performances with high reversible capacities and exceptional cyclability. The diffusion-driven strategy and etching effect of KOH played important roles in regulating the transport of reaction ions and generating intercalated K+ ions and abundant oxygen vacancies, which led to superior electrochemical kinetics.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Nanoengineering of Advanced Carbon Materials for Sodium-Ion Batteries

Shuoqing Zhao et al.

Summary: Using nanoengineering strategies to enhance the electrochemical performance and structural stability of carbon-based anode materials in sodium-ion batteries shows promising potential. Further exploration of improvement methods is necessary to increase the competitiveness of sodium-ion batteries.

SMALL (2021)

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Review Chemistry, Physical

Aqueous Rechargeable Multivalent Metal-Ion Batteries: Advances and Challenges

Zhenghui Pan et al.

Summary: Aqueous rechargeable multivalent metal-ion batteries (ARMMBs) show great potential for various energy storage applications, but face challenges such as narrow operating voltage windows and low energy density. Efforts are currently focused on addressing these challenges through the development of new electrode materials and electrolytes, with the main goal being the transition from laboratory prototypes to commercialization/industrialization in the near future.

ADVANCED ENERGY MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Crystalline and amorphous MnO2 cathodes with open framework enable high-performance aqueous zinc-ion batteries

Chunfu Huang et al.

Summary: The study reports the preparation of crystalline/amorphous MnO2 using order/disorder engineering, which exhibits improved electrochemical performance due to more active sites and a more stable structure, making it a promising cathode material for aqueous zinc-ion batteries. The storage mechanism of the disordered MnO2 electrode is systematically investigated, demonstrating the potential of order/disorder engineering in introducing novel properties in electrode materials for high-performance aqueous ZIBs.

FRONTIERS OF MATERIALS SCIENCE (2021)

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Article Chemistry, Physical

Lattice-resolution visualization of anisotropic sodiation degrees and revelation of sodium storage mechanisms in todorokite-type MnO2 with in-situ TEM

Ran Cai et al.

Summary: This study investigates the structural evolution of tau-MnO2 nanorods during sodiation using in-situ transmission electron microscopy, revealing multistep phase conversion reactions and lattice-level visualization of different sodiation degrees. Anisotropic contraction and expansion of lattice a and c upon inserting Na+ ions are observed, providing valuable insights into electrochemical sodium storage mechanisms in tunnel-structured tau-MnO2 material.

ENERGY STORAGE MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Two Birds with One Stone: Boosting Zinc-Ion Insertion/Extraction Kinetics and Suppressing Vanadium Dissolution of V2O5 via La3+ Incorporation Enable Advanced Zinc-Ion Batteries

Dongdong Zhang et al.

Summary: The incorporation of La3+ ions into V2O5 cathodes can enhance Zn2+ diffusion kinetics and stabilize vanadium species, leading to improved cyclability and energy density of aqueous zinc-ion batteries. The La-V2O5 cathodes show exceptional rate capacity, long-term stability, and outstanding energy density, outperforming various metal-ion-doped V2O5 cathodes. Additionally, the La-V2O5 pouch cell exhibits excellent electrochemical performance, flexibility, and integration ability, providing guidance for other advanced electrochemical devices.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Studying the Conversion Mechanism to Broaden Cathode Options in Aqueous Zinc-Ion Batteries

Junnan Hao et al.

Summary: Research findings indicate that Zn2+ storage in CuI cathode involves a direct conversion reaction mechanism, rather than an intercalation mechanism, and this mechanism can also be applied to other high-capacity cathodes effectively.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Enhanced electrochemical production and facile modification of graphite oxide for cost-effective sodium ion battery anodes

Yubai Zhang et al.

Summary: The study demonstrates a green and simple method to prepare cost-effective and stable graphitic SIB anodes. Thermally processed electrochemical graphite oxide shows high reversible capacity and low fading, offering a promising approach for industrial production of low-cost anodes for sodium-ion batteries.

CARBON (2021)

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Article Electrochemistry

Manganese oxides hierarchical microspheres as cathode material for high-performance aqueous zinc-ion batteries

Bo Yang et al.

Summary: In this study, hierarchical microspheres of manganese oxides (MnOx) with excellent electrochemical performance were synthesized, among which MnO hierarchical microspheres showed good cycling stability and high reversible capacity. The zinc ion storage mechanism of MnO cathode in aqueous ZIBs was revealed, and the layered-type MnO2 structure formed during initial cycles contributed to its remarkable electrochemical performance.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Boosting zinc ion energy storage capability of inert MnO cathode by defect engineering

Peifeng Yu et al.

Summary: This study successfully activated the electrochemical inertness of MnO by introducing nitrogen dopant and oxygen vacancy, significantly enhancing its zinc ion storage capacity. Experimental results showed that this defect engineering strategy enabled MnO to exhibit high specific capacity, superb rate capability, prolonged cycling stability, and attractive energy density.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Physical

High-performance reversible aqueous zinc-ion battery based on iron-doped alpha-manganese dioxide coated by polypyrrole

Jun-Wei Xu et al.

Summary: In this study, Fe/alpha-MnO2@PPy composite materials were successfully prepared for efficient zinc-ion storage cathode in AZIBs. The optimized structure not only enhances the reversible specific capacity but also exhibits high diffusion coefficient, showing great potential for practical applications in advanced electrode materials for AZIBs.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Analytical

MnO2@V2O5 microspheres as cathode materials for high performance aqueous rechargeable Zn-ion battery

Hongjing Shang et al.

Summary: In this study, vanadium pentoxide-coated manganese dioxide was proposed as a cathode material for rechargeable aqueous zinc-ion batteries. The coated microspheres showed improved ion insertion/extraction kinetics, suppressed dissolution of the cathode material, high specific capacity, excellent rate capability, and good long-term cycling stability. This research highlights the potential of using Zn-ion conductor oxide coating to enhance the electrochemical performance of manganese dioxide in aqueous ZIBs.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Interlayer Modification of Pseudocapacitive Vanadium Oxide and Zn(H2O)n2+ Migration Regulation for Ultrahigh Rate and Durable Aqueous Zinc-Ion Batteries

Hangda Chen et al.

Summary: By inserting Mn2+, the structure stability of hydrated vanadium oxide is improved, the electronic structure is adjusted, and the conductivity is enhanced. Moreover, Mn2+ alters the migration pathway of Zn2+, reduces the migration barrier, and enhances the rate performance.

ADVANCED SCIENCE (2021)

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Article Chemistry, Physical

Bi2O3 Induced Ultralong Cycle Lifespan and High Capacity of MnO2 Nanotube Cathodes in Aqueous Zinc-Ion Batteries

Lei Gou et al.

Summary: By constructing a MnO2/Bi2O3 hybrid cathode, the electrochemical performance of aqueous rechargeable zinc-ion batteries can be effectively enhanced, resulting in longer cycling durability and higher capacity. The formation of Bi3+ and Bi2Mn4O10 can enhance the structural stability of the material, improve the transport kinetics of zinc ions, and inhibit the formation of irreversible phases.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Al-doped α-MnO2 coated by lignin for high-performance rechargeable aqueous zinc-ion batteries

Jingliang Xu et al.

Summary: The structural stability of alpha-MnO2 is enhanced by simultaneous Al3+ doping and lignin coating, leading to improved conductivity and increased surface area. This results in superior performance in terms of reversible capacity and cycle stability compared to the reference alpha-MnO2 cathode.

RSC ADVANCES (2021)

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Review Chemistry, Physical

Redox flow batteries: a new frontier on energy storage

P. Arevalo-Cid et al.

Summary: This review provides a comprehensive introduction to redox flow batteries and critically evaluates the state-of-the-art progress, covering individual components, economic analysis, and characterization techniques, showcasing their potential and advantages as a leading stationary energy storage technology.

SUSTAINABLE ENERGY & FUELS (2021)

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Article Nanoscience & Nanotechnology

Layer-by-layer synthesis of Zn-doped MnO2 nanocrystals as cathode materials for aqueous zinc-ion battery

A. A. Lobinsky et al.

Summary: This work successfully synthesized Zn-doped MnO2 nanocrystals as the cathode material for an aqueous zinc-ion battery, showing excellent electrochemical performance with high specific capacity and good cycling stability.

NANOSYSTEMS-PHYSICS CHEMISTRY MATHEMATICS (2021)

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Article Chemistry, Physical

Defect engineering via the F-doping of β-MnO2 cathode to design hierarchical spheres of interlaced nanosheets for superior high-rate aqueous zinc ion batteries

Seoyeong Kim et al.

Summary: A hierarchical beta-MnO2 cathode material with interlaced nanosheets spheres was introduced through efficient defect engineering using fluorine (F)-doping and oxygen vacancies, improving ion insertion, transport kinetics, and electrical conductivity in ZIB. This resulted in a high energy density, superior high-rate performance, and good capacity retention, highlighting the potential of defect-engineered cathode materials for enhanced electrochemical performance in rechargeable aqueous batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Comprehensive understanding of the roles of water molecules in aqueous Zn-ion batteries: from electrolytes to electrode materials

Ming Li et al.

Summary: This study comprehensively summarizes the role of water molecules in rechargeable aqueous zinc-ion batteries, focusing on the influencing mechanisms from various perspectives. It also proposes new insights and actionable methods for the potential future directions in the design of high-performance AZIBs.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Electrochemistry

High-Mass-Loading Electrodes for Advanced Secondary Batteries and Supercapacitors

Feng Wu et al.

Summary: The increasing demand for high energy density advanced electrochemical energy storage systems (EESSs) for electric vehicles and portable electronics is driving the electrode revolution, with the development of high-mass-loading electrodes (HMLEs) as a promising approach. However, HMLEs face challenges such as poor charge kinetics, electrode structural stability, and complex production processes. This review provides a comprehensive summary of HMLEs, discussing strategies to improve their electrochemical performance and their applications in various EESSs.

ELECTROCHEMICAL ENERGY REVIEWS (2021)

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Article Materials Science, Multidisciplinary

Rechargeable aqueous zinc-ion batteries: Mechanism, design strategies and future perspectives

Huanyan Liu et al.

Summary: Rechargeable aqueous zinc-ion batteries (ZIBs) are considered a promising energy storage solution for grid-scale applications due to their safety, eco-friendliness, and cost-effectiveness. Despite significant progress in developing efficient cathodes, anodes, and electrolytes, the understanding of ZIBs and their energy storage mechanisms is still in its early stages and requires further investigation for practical implementation. This review provides a comprehensive summary of the development of ZIBs, design strategies, challenges, and opportunities for practical viability.

MATERIALS TODAY (2021)

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Article Materials Science, Multidisciplinary

MnO Stabilized in Carbon-Veiled Multivariate Manganese Oxides as High-Performance Cathode Material for Aqueous Zn-Ion Batteries

Wanwei Jiang et al.

Summary: This study presents a cooperative design of multivariate manganese oxides@carbon hybrids as an attractive Zn-ion cathode for aqueous Zn-ion batteries. The cathode exhibits excellent performance due to facile charge transfer and ions insertion, promoting the development of low-cost and high-performance rechargeable Zn-ion batteries.

ENERGY & ENVIRONMENTAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

A Highly Flexible and Lightweight MnO2/Graphene Membrane for Superior Zinc-Ion Batteries

Jinjin Wang et al.

Summary: This study introduces a self-standing hybrid nanoarchitecture for flexible and foldable zinc-ion batteries, featuring high energy density and good cycling durability. The batteries can operate without capacity loss in both bent and folded circumstances, holding great promise for smart and wearable electronics.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Electronic Structure Regulation of Layered Vanadium Oxide via Interlayer Doping Strategy toward Superior High-Rate and Low-Temperature Zinc-Ion Batteries

Hongbo Geng et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Polymer Science

Preparation of Polyaniline-coated Composite Aerogel of MnO2 and Reduced Graphene Oxide for High-performance Zinc-ion Battery

Jing Mao et al.

CHINESE JOURNAL OF POLYMER SCIENCE (2020)

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Article Electrochemistry

Nickel and cobalt Co-substituted spinel ZnMn2O4@N-rGO for increased capacity and stability as a cathode material for rechargeable aqueous zinc-ion battery

Yayuan Tao et al.

ELECTROCHIMICA ACTA (2020)

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Article Chemistry, Physical

Plasma-induced redox reactions synthesis of nanosized α-, γ- and δ-MnO2 catalysts for dye degradation

Franck W. Boyom-Tatchemo et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Materials Science, Multidisciplinary

Constructing α-MnO2@PPy core-shell nanorods towards enhancing electrochemical behaviors in aqueous zinc ion battery

Cong Guo et al.

MATERIALS LETTERS (2020)

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Article Chemistry, Multidisciplinary

H+-Insertion Boosted α-MnO2 for an Aqueous Zn-Ion Battery

Xu Gao et al.

SMALL (2020)

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Article Nanoscience & Nanotechnology

Layered Birnessite Cathode with a Displacement/Intercalation Mechanism for High-Performance Aqueous Zinc-Ion Batteries

Xian-Zhi Zhai et al.

NANO-MICRO LETTERS (2020)

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Article Electrochemistry

One-Dimensional MnO2 Nanowires Space-Confined in Hollow Mesoporous Carbon Nanotubes for Enhanced Zn2+ Storage Performance

Weifang Liu et al.

CHEMELECTROCHEM (2020)

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Article Chemistry, Applied

gamma-MnO2 nanorods/graphene composite as efficient cathode for advanced rechargeable aqueous zinc-ion battery

Chao Wang et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Review Electrochemistry

Nanostructure Design Strategies for Aqueous Zinc-Ion Batteries

Wei Ling et al.

CHEMELECTROCHEM (2020)

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Article Energy & Fuels

Decoupling electrolytes towards stable and high-energy rechargeable aqueous zinc-manganese dioxide batteries

Cheng Zhong et al.

NATURE ENERGY (2020)

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Article Nanoscience & Nanotechnology

Proton Insertion Promoted a Polyfurfural/MnO2 Nanocomposite Cathode for a Rechargeable Aqueous Zn-MnO2 Battery

Qin Zhao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Nanoscience & Nanotechnology

Boosted Charge Transfer in Twinborn α-(Mn2O3-MnO2) Heterostructures: Toward High-Rate and Ultralong-Life Zinc-Ion Batteries

Jun Long et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Nanoscience & Nanotechnology

Superfine MnO2 Nanowires with Rich Defects Toward Boosted Zinc Ion Storage Performance

Jinjin Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Functionalized Zn@ZnO Hexagonal Pyramid Array for Dendrite-Free and Ultrastable Zinc Metal Anodes

Ji Young Kim et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Facile plasma treated β-MnO2@C hybrids for durable cycling cathodes in aqueous Zn-ion batteries

Wanwei Jiang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Engineering, Environmental

Amorphous manganese dioxide with the enhanced pseudocapacitive performance for aqueous rechargeable zinc-ion battery

Yi Cai et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Electrochemistry

Graphene-Wrapped MnO/C Composites by MOFs-Derived as Cathode Material for Aqueous Zinc ion Batteries

Fang Tang et al.

ELECTROCHIMICA ACTA (2020)

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Article Chemistry, Physical

Toward a Reversible Mn4+/Mn2+Redox Reaction and Dendrite-Free Zn Anode in Near-Neutral Aqueous Zn/MnO2Batteries via Salt Anion Chemistry

Xiaohui Zeng et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Electrochemistry

A P2@Tunnel Heterostructure Cathode for High-Performance Sodium-Ion Batteries

Qun Huang et al.

CHEMELECTROCHEM (2020)

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Review Energy & Fuels

Application of Manganese-Based Materials in Aqueous Rechargeable Zinc-Ion Batteries

Wanhong Zhang et al.

FRONTIERS IN ENERGY RESEARCH (2020)

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Article Materials Science, Multidisciplinary

Recent advances in cathode materials of rechargeable aqueous zinc-ion batteries

L. Wang et al.

MATERIALS TODAY ADVANCES (2020)

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Article Chemistry, Physical

Double-shell zinc manganate hollow microspheres embedded in carbon networks as cathode materials for high-performance aqueous zinc-ion batteries

Shuting Wang et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Ultrathin MnO2 nanoflakes grown on N-doped hollow carbon spheres for high-performance aqueous zinc ion batteries

Linlin Chen et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Physical

Electrochemical transformation reaction of Cu-MnO in aqueous rechargeable zinc-ion batteries for high performance and long cycle life

Fekadu Wubatu Fenta et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Electrochemically induced cationic defect in MnO intercalation cathode for aqueous zinc-ion battery

Chuyu Zhu et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Highly stable Zn metal anodes enabled by atomic layer deposited Al2O3 coating for aqueous zinc-ion batteries

Huibing He et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Anti-freezing flexible aqueous Zn-MnO2 batteries working at-35 °C enabled by a borax-crosslinked polyvinyl alcohol/glycerol gel electrolyte

Minfeng Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Multidisciplinary Sciences

Oxygen Defects in β-MnO2 Enabling High-Performance Rechargeable Aqueous Zinc/Manganese Dioxide Battery

Mingming Han et al.

ISCIENCE (2020)

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Article Chemistry, Inorganic & Nuclear

Mn2O3/Al2O3 cathode material derived from a metal-organic framework with enhanced cycling performance for aqueous zinc-ion batteries

Lei Gou et al.

DALTON TRANSACTIONS (2020)

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Review Materials Science, Multidisciplinary

Challenges and perspectives for manganese-based oxides for advanced aqueous zinc-ion batteries

Yinlei Zhao et al.

INFOMAT (2020)

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Article Chemistry, Multidisciplinary

Reversible Oxygen Redox Chemistry in Aqueous Zinc-Ion Batteries

Fang Wan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Reaction Mechanisms for Long-Life Rechargeable Zn/MnO2 Batteries

Yun Li et al.

CHEMISTRY OF MATERIALS (2019)

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Article Materials Science, Multidisciplinary

α-Mno2 nanorod/onion-like carbon composite cathode material for aqueous zinc-ion battery

Nithyadharseni Palaniyandy et al.

MATERIALS CHEMISTRY AND PHYSICS (2019)

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Article Chemistry, Physical

Defect Engineering of Oxygen-Deficient Manganese Oxide to Achieve High-Performing Aqueous Zinc Ion Battery

Ting Xiong et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Nanoscience & Nanotechnology

Tailoring Three-Dimensional Composite Architecture for Advanced Zinc-Ion Batteries

Yang Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Nanoscale Parallel Circuitry Based on Interpenetrating Conductive Assembly for Flexible and High-Power Zinc Ion Battery

Shaojuan Luo et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Electrochemistry

Ultrathin δ-MnO2 nanosheets as cathode for aqueous rechargeable zinc ion battery

Cong Guo et al.

ELECTROCHIMICA ACTA (2019)

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Article Materials Science, Multidisciplinary

Cathodic electrodeposition of porous MnO2 film as binder-free cathode for high performance rechargeable Zinc-ion battery

Xiaoyong Fan et al.

FUNCTIONAL MATERIALS LETTERS (2019)

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Article Electrochemistry

Mn3O4@NC Composite Nanorods as a Cathode for Rechargeable Aqueous Zn-Ion Batteries

Ming Sun et al.

CHEMELECTROCHEM (2019)

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Article Chemistry, Multidisciplinary

Joint Charge Storage for High-Rate Aqueous Zinc-Manganese Dioxide Batteries

Yan Jin et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Physical

Advanced electrochemical performance of ZnMn2O4/N-doped graphene hybrid as cathode material for zinc ion battery

Linlin Chen et al.

JOURNAL OF POWER SOURCES (2019)

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Article Chemistry, Physical

A Universal Principle to Design Reversible Aqueous Batteries Based on Deposition-Dissolution Mechanism

Guojin Liang et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Multidisciplinary Sciences

δ-MnO2 nanoflower/graphite cathode for rechargeable aqueous zinc ion batteries

Sonti Khamsanga et al.

SCIENTIFIC REPORTS (2019)

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Article Nanoscience & Nanotechnology

Novel Insights into Energy Storage Mechanism of Aqueous Rechargeable Zn/MnO2 Batteries with Participation of Mn2+

Yongfeng Huang et al.

NANO-MICRO LETTERS (2019)

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Article Chemistry, Multidisciplinary

A Superior δ-MnO2 Cathode and a Self-Healing Zn-δ-MnO2 Battery

Donghong Wang et al.

ACS NANO (2019)

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Article Chemistry, Physical

Sulfur-impregnated disordered SnO2/carbon aerogel core-shell microspheres cathode for lithium-sulfur batteries

Meili Qi et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Chemistry, Physical

Superior-Performance Aqueous Zinc Ion Battery Based on Structural Transformation of MnO2 by Rare Earth Doping

Jianwei Wang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

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Article Materials Science, Multidisciplinary

β-MnO2 nanolayer coated on carbon cloth as a high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life

Zhihong Deng et al.

MATERIALS LETTERS (2019)

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Article Chemistry, Physical

Built-in oriented electric field facilitating durable Zn-MnO2 battery

Sitian Lian et al.

NANO ENERGY (2019)

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Letter Chemistry, Multidisciplinary

Boosting the Solar Cell Efficiency by Flexo-photovoltaic Effect?

Haiyang Zou et al.

ACS NANO (2019)

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Article Chemistry, Multidisciplinary

Cathode Interfacial Layer Formation via in Situ Electrochemically Charging in Aqueous Zinc-Ion Battery

Shan Guo et al.

ACS NANO (2019)

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Article Chemistry, Physical

Electrochemical activation of commercial MnO microsized particles for high-performance aqueous zinc-ion batteries

Jinjin Wang et al.

JOURNAL OF POWER SOURCES (2019)

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Article Chemistry, Multidisciplinary

Unravelling H+/Zn2+ Synergistic Intercalation in a Novel Phase of Manganese Oxide for High-Performance Aqueous Rechargeable Battery

Qinghe Zhao et al.

SMALL (2019)

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Green-low-cost rechargeable aqueous zinc-ion batteries using hollow porous spinel ZnMn2O4 as the cathode material

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Electrochemically Induced Structural Transformation in a γ-MnO2 Cathode of a High Capacity Zinc-Ion Battery System

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