4.7 Article

Performance of geopolymer concrete activated by sodium silicate and silica fume activator

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ELSEVIER
DOI: 10.1016/j.cscm.2022.e01513

关键词

Early strength; Geopolymer concrete; Pore; Silica fume activator; Sodium silicate activator

资金

  1. Zhejiang Province Public Welfare Technology Application Research Project, China
  2. National innovation program for college students, China
  3. China Schol- arship Council (CSC)
  4. [GF18E080016]
  5. [202113283006]
  6. [201808330642]

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This study examined the properties of geopolymer concrete activated by sodium silicate and silica fume activator. It found that silica fume can improve the workability and strength of the concrete, and has less influence on the slump. Compared with sodium silicate activator, geopolymer concrete activated by silica fume has less cracks and porosities on the surface, and shows good early strength.
This study examined the properties (strength, workability and crack) of geopolymer concrete activated by sodium silicate and silica fume activator. Sodium silicate and sodium hydroxide (NaOH) are commonly activators used to make geological polymer composite. However, they will cause the decline of the performance of geopolymer concrete when it is prone to polymerization in the surrounding of alkaline. Silica fume can improve the workability and strength of geopolymer concrete. The Pearson correlation coefficient and experiment is used to study the performance of geopolymer concrete with sodium silicate and silica fume activator. The influence of two kinds of activators on the slump of geopolymers with different mix ratios was analyzed by Pearson correlation coefficient. The relative coefficient of mineral powder decreased from 0.785 to 0.409. The absolute relative coefficient of calcined magnesite decreased from 0.829 to 0.156. The correlation between slag, calcined magnesite and slump changed from significant to insignificant. The analysis shows that the slump of geopolymers with silica fume activator are less affected by mineral powder and calcined magnesite than that of sodium silicate activator. Geopolymer concrete have more stable performance with silica fume activator. The geopolymer concrete excited by silica fume activator compared with the sodium silicate activator, the cracks and internal porosities on the surface of the specimens are less. The compressive strength and crack of geopolymer concrete excited by silica fume activator reached 43.36 MPa and 0.095 mm, respectively, at 20 degrees C +/- 2 degrees C and more than 95% humidity. It shows good early strength and less cracks. The experimental mix proportions are optimized to conduct the complex the equilibrium of physical and chemical reactions and to reinforce the mechanical property of geopolymer concrete with silicate fume activator.

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