期刊
MATERIALS TODAY CHEMISTRY
卷 26, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2022.101039
关键词
Available online xxx; Light -induced heating; Heat generation; Optical heaters; Transition metal ions; Cr3+
资金
- National Science Center Poland (NCN) [2019/35/N/ST5/00553]
- Foundation for Polish Science
This work proposes a new type of photothermal agent based on inorganic materials heavily doped with Cr3+ ions, which shows significant improvement in optical heating performance and may become an important alternative to currently used photothermal agents.
In response to the demands placed on functional materials for light-to-heat conversion applications, a new type of photothermal agent is proposed in this work. The proposed approach is based on inorganic materials heavily doped with Cr3+ ions. As shown, the increase in the probability of non-radiative processes and the increasing absorption cross-section of Cr3+ ions in GdAl3(BO3)(4):Cr3+ observed with an increasing dopant ion concentration enabled significant optical heating of the sample. The proposed strategy exploiting Cr3+ ions, due to the much higher absorption cross-section of transition metal ions with respect to the lanthanide ions, may become an important alternative for currently used photo -thermal agents. (C) 2022 The Author(s). Published by Elsevier Ltd.
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