Smart L-borneol-loaded hierarchical hollow polymer nanospheres with antipollution and antibacterial capabilities

Article Chemistry, Applied

Alpha-terpineol grafted acetylated lentinan as an anti-bacterial adhesion agent

Qiang Ding et al.

Summary: This study showed that AceLNT-g-alpha-terM can effectively inhibit the adhesion and biofilm formation of gram-negative bacteria, providing a new strategy for preventing infection of biomedical implants.

CARBOHYDRATE POLYMERS (2022)

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Article Chemistry, Multidisciplinary

Kinetics-Controlled Super-Assembly of Asymmetric Porous and Hollow Carbon Nanoparticles as Light-Sensitive Smart Nanovehicles

Lei Xie et al.

Summary: A kinetics-controlled interfacial superassembly strategy was developed to prepare asymmetric porous and hollow carbon nanoparticles. These nanoparticles can act as fuel-free nanomotors, achieving propulsion under NIR light and exhibiting excellent photothermal performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Polymer Science

Smart Synthesis of Hollow Microporous Organic Capsules with a Polyaniline Modified Shell

Qingyin Li et al.

Summary: Novel hypercrosslinked polymer-based hollow microporous organic capsules with a polyaniline-modified shell (PANI@S-HMOCs) were prepared by in-situ polymerization of aniline in the porous structure of sulfonated hollow microporous organic capsules (S-HMOCs). The content of PANI showed an evident effect on the porosity and surface area of PANI@S-HMOCs. Among them, PANI@S-HMOC2 exhibited good adsorption performance for Cr(VI).

MACROMOLECULAR RAPID COMMUNICATIONS (2022)

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Article Materials Science, Biomaterials

Construction of antibacterial adhesion surfaces based on bioinspired borneol-containing glycopolymers

Qiuli Cheng et al.

Summary: In this study, new copolymers (poly(LAEMA-co-GMA-co-BA)) were synthesized by combining 2-lactobionamidoethyl methacrylamide with a uniquely structured borneol compound. The prepared coatings showed good antibacterial adhesion properties and biocompatibility. This study provides a strategy for designing antibacterial surfaces using glycopolymers and natural antibacterial compounds.

BIOMATERIALS SCIENCE (2022)

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Article Chemistry, Applied

Bifunctional ZnCo2S4@CoZn13 hybrid electrocatalysts for high efficient overall water splitting

Depeng Zhao et al.

Summary: Developing highly active and low-cost electrocatalysts is crucial for improving the efficiency of water splitting. This study reports several amino-induced cobalt-based composite catalysts, which exhibit excellent performance in oxygen evolution and hydrogen evolution reactions, making them promising for water electrolysis.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Engineering, Environmental

Hypercrosslinked triazine-phloroglucinol hierarchical porous polymers for the effective removal of organic micropollutants

Xiao-Qing Huang et al.

Summary: In this study, trisphloroglucinol substituted triazine was used as a building block to construct hypercrosslinked polymers for the removal of organic micropollutants from water. These polymers exhibited hierarchical porous structure, high degree of functionality, and good hydrophilicity. The embedded trisphloroglucinol skeletons enabled effective adsorption of various cationic and nonionic organic micropollutants. The adsorption capacity and rate of the polymers were superior to previously reported adsorbent materials. Additionally, the polymers could be easily reused multiple times without a significant decrease in adsorption efficiency, making them suitable for wastewater treatment.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Negatively charged hollow crosslinked aromatic polymer fiber membrane for high-efficiency removal of cationic dyes in wastewater

Xiaoqing Lu et al.

Summary: This study successfully synthesized a negatively charged hollow crosslinked aromatic polystyrene (PS) fiber (HPF-C) membrane and investigated its performance in dye removal. The results showed that the membrane had high adsorption capacity and fast permeation rate, and was able to completely remove the dyes. It also exhibited excellent sustainability and stability.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Developing a novel nitrogen-doped hollow porous carbon sphere (N-HPCS) blended nanofiltration membrane with superior water permeance characteristic for high saline and colored wastewaters treatment

Zeinab Salahshoor et al.

Summary: This study developed a novel mixed matrix polyethersulfone (PES) nanofiltration membrane by blending nitrogen-doped hollow carbon sphere with a mesoporous shell (N-HPCS). The membrane showed improved hydrophilicity, pure water flux, mean pore diameter, and fouling resistance. It also exhibited enhanced rejection of salts and dyes, as well as high removal percentage for heavy metals. The study demonstrated the potential of the modified membrane for high saline textile wastewater treatment.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Simultaneous Nitrite Resourcing and Mercury Ion Removal Using MXene-Anchored Goethite Heterogeneous Fenton Composite

Xi Chen et al.

Summary: A bifunctional beta-FeOOH@MXene material was fabricated and showed excellent performance in nitrite oxidation and Hg2+ removal. The synergism between MXene and beta-FeOOH played a key role in the material's outstanding abilities.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

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Article Chemistry, Physical

Synergistically Improved Antifouling Efficiency of a Bioinspired Self-renewing Interface via a Borneol/Boron Acrylate Polymer

Fan Song et al.

Summary: Underwater facilities face challenges of biofouling, but PBABs demonstrate high antibacterial rates and superior antifouling properties, making them suitable for actual marine applications.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Amorphous-to-Crystalline Transformation: General Synthesis of Hollow Structured Covalent Organic Frameworks with High Crystallinity

Zeshan Xiong et al.

Summary: This study reports a versatile and efficient strategy of amorphous-to-crystalline transformation for the fabrication of highly crystalline HCOFs. The approach allows for the control of hollowing process and crystallization process by regulating the dynamic imine exchange reaction. Various HCOFs with ultrahigh surface areas and uniform morphologies were successfully synthesized, and COF-based yolk-shell nanostructures with functional interior cores were also fabricated. The obtained metal@HCOFs catalysts showed enhanced catalytic activity and size-selectivity, highlighting the significance of nucleation-growth kinetics of COFs in tuning their morphologies, structures, and applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Engineering of hollow polymeric nanosphere-supported imidazolium-based ionic liquids with enhanced antimicrobial activities

Yu Zhang et al.

Summary: The newly developed HPN-ILs exhibit uniform hollow spherical morphology, adequate surface area, and excellent physicochemical stability. They show high activity against both Gram-positive and Gram-negative bacteria with typical time/dosage-dependent antibacterial activities.

NANO RESEARCH (2022)

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Article Engineering, Chemical

Electrospun polyacrylonitrile-based lace nanostructures and their Cu (II) adsorption

Xizi Xu et al.

Summary: A functionalized porous nanofibrous membrane loaded with MgO nanoparticles was prepared by coaxial electrospinning and post-processing method, and showed high efficiency in removing copper ions from aqueous solutions. The membrane had a larger specific surface area, a more uniform diameter distribution, and surface pores, as well as good mechanical properties and hydrophilicity. The adsorption of copper ions reached equilibrium within 3 hours, with an optimal adsorption pH of 5 and a maximum adsorption capacity of 354 mg/g. The membrane also demonstrated good recycling performance.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Engineering, Chemical

Acetamido-functionalized hyper-crosslinked polymers for efficient removal of phenol in aqueous solution

You Wang et al.

Summary: In recent years, functionalized hyper-crosslinked polymers have gained attention for their high surface area, adjustable porosity, and diverse functionality. In this study, acetamido-functionalized HCPs were synthesized and shown to have high surface area, abundant nitrogen and oxygen content, and unique hierarchical porosity. The adsorption experiments revealed that these polymers have good adsorption capacity for phenol.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Nanoscience & Nanotechnology

A Perspective for Developing Polymer-Based Electromagnetic Interference Shielding Composites

Yali Zhang et al.

Summary: The rapid development of aerospace weapons and equipment, wireless base stations, and 5G communication technologies has increased the demands for polymer-based electromagnetic interference (EMI) shielding composites. However, most of these composites fail to combine high performance and multi-functionality. In response, three possible directions for overcoming these limitations have been proposed, including the construction of efficient conductive networks and the optimization of multi-interfaces for lightweight and multifunction compatibility. This research aims to provide a theoretical basis and technical guidance for the preparation and development of polymer-based EMI shielding composites.

NANO-MICRO LETTERS (2022)

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Review Chemistry, Multidisciplinary

Intelligent poly(L-histidine)-based nanovehicles for controlled drug delivery

Yu Zhang et al.

Summary: Stimuli-responsive drug delivery systems based on polymeric nanovehicles can release drugs according to the acidic tumor microenvironment, improving treatment specificity and efficacy.

JOURNAL OF CONTROLLED RELEASE (2022)

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Article Nanoscience & Nanotechnology

Electrospun healthcare nanofibers from medicinal liquor of Phellinus igniarius

Wenlai Jiang et al.

Summary: In this study, the traditional medicinal liquor was transformed into medicinal core-shell nanofibers using coaxial electrospinning technology. The nanofibers exhibited a clear core-shell structure, with the active ingredients in an amorphous state and good compatibility with the polymeric matrix. In vitro experiments demonstrated that the nanofibers could quickly dissolve and release the loaded active ingredients, ensuring rapid permeation. This study pioneers a new approach to transform traditional medicine into nano healthcare products.

ADVANCED COMPOSITES AND HYBRID MATERIALS (2022)

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Review Materials Science, Biomaterials

Porous organic polymers for drug delivery: hierarchical pore structures, variable morphologies, and biological properties

Yunxin Tang et al.

Summary: Porous organic polymers have attracted considerable attention due to their hierarchical pore structures, variable morphologies, and tunable biological properties. This review discusses the synthetic and post forming/control methods for controlling the hierarchical structures and morphologies of porous organic polymers, highlighting the different methods that affect their specific surface areas, hierarchical structures, and unique morphologies. Additionally, the applications of porous organic polymers in drug encapsulation and the development of stimuli-responsive materials are explored, focusing on their use for targeted drug release and as therapeutic agents.

BIOMATERIALS SCIENCE (2022)

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Article Materials Science, Biomaterials

Electrospun hierarchical structural films for effective wound healing

Haixia Xu et al.

Summary: This study reports the design and preparation of a hierarchical structural film wound dressing made of hydrophobic polycaprolactone (PCL), hydrophilic gelatin, and hydrophilic Janus nanofibers loaded with ciprofloxacin (CIP) and zinc oxide nanoparticles (n-ZnO). The dressing showed outstanding surface wettability, excellent mechanical properties, and rapid drug release. It also exhibited antibacterial activity and accelerated wound healing in mice.

BIOMATERIALS ADVANCES (2022)

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Article Biochemistry & Molecular Biology

Efficient Synthesis of Folate-Conjugated Hollow Polymeric Capsules for Accurate Drug Delivery to Cancer Cells

Wenliang Song et al.

Summary: This study presents an efficient and systematic approach to synthesize bioapplicable porous hollow polymeric capsules, offering potential applications in drug delivery. By converting hydroxyl groups on the surface to carboxyl groups, biomolecules can be covalently decorated on the organic capsules. The research results show that these organic capsules have potential applications in drug encapsulation efficiency and release.

BIOMACROMOLECULES (2021)

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Article Engineering, Environmental

Modified tri-axial electrospun functional core-shell nanofibrous membranes for natural photodegradation of antibiotics

Kun Zhao et al.

Summary: In this study, functional nanoparticles and nanofibrous membranes were used to successfully degrade doxycycline, with the membrane loaded with beta-FeOOH/TiO2 showing the best performance and achieving a degradation efficiency of 90.14% under natural sunlight.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Multidisciplinary Sciences

A structural polymer for highly efficient all-day passive radiative cooling

Tong Wang et al.

Summary: The authors present a hierarchically structured polymethyl methacrylate film with a micropore array combined with random nanopores for highly efficient day- and nighttime passive radiative cooling, achieving high solar reflectance and longwave infrared thermal emittance. There is still a challenge in fabricating highly efficient and low-cost radiative coolers for all-day and all-climates.

NATURE COMMUNICATIONS (2021)

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Article Nanoscience & Nanotechnology

Antifouling and Antibacterial Polymer-Coated Surfaces Based on the Combined Effect of Zwitterions and the Natural Borneol

Qiuli Cheng et al.

Summary: By combining zwitterionic MPC with borneol compound, an excellent antifouling and antibacterial surface with superb hydrophilicity was prepared via Schiff-base bond. The copolymer's coordination between MPC and borneol moieties showed effective prevention of protein adsorption and inhibition of bacterial adhesion, making it a potential application in biomedical materials.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Functional Porous Organic Polymers with Conjugated Triaryl Triazine as the Core for Superfast Adsorption Removal of Organic Dyes

Yong Zhang et al.

Summary: Conjugated triaryl triazines were used to construct porous organic polymer adsorbents with hierarchical porous structures, sheet-like morphology, good surface wettability, and high functionality, offering superfast adsorption of cationic dyes from water. The adsorbent demonstrated a superior pseudo-second-order rate constant for methylene blue dye adsorption and can be regenerated multiple times without performance loss, indicating its potential for water treatment applications.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

Visible light absorption by perylene diimide for synergistic persulfate activation towards efficient photodegradation of bisphenol A

Qiuyi Ji et al.

Summary: A novel PDI/PS/Vis system was constructed for efficient removal of BPA in water environment, utilizing visible light and producing non-toxic ring-opening products. The system showed high efficiency in photocatalytic activity and organic elimination, with different radicals contributing to the process.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

Se-doped CoP nanoparticles confined in 3D porous carbon frameworks with enlarged interlayer spacings boost potassium-ion storage

Jiajia Ye et al.

Summary: Se-doped CoP nanoparticles confined in 3D porous carbon frameworks demonstrate outstanding rate capability and long cycle life as K-ion battery anodes. Se-doping modifies the lattice of CoP, providing increased active sites and improved stability for high specific capacities. The 3D porous carbon frameworks offer pathways for fast electron and K-ion transport.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Applied

Simultaneous adsorption of heavy metals and organic dyes by β-Cyclodextrin-Chitosan based cross-linked adsorbent

Muhammad Usman et al.

Summary: A new adsorbent NTA-beta-CD-CS was synthesized for the simultaneous removal of dyes and metals, showing high adsorption capacities and excellent regeneration performance, making it potentially promising for treating wastewater from various industries.

CARBOHYDRATE POLYMERS (2021)

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Article Engineering, Environmental

Multifunctional fabrics finished using electrosprayed hybrid Janus particles containing nanocatalysts

Jiangsong Hou et al.

Summary: The study involved depositing Janus particles on fabric surface to impart superhydrophobic, UV resistance, and antimicrobial properties. The finished fabric showed significantly increased ultraviolet protection factor and water contact angle, while maintaining gas permeability.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Nanoscience & Nanotechnology

Bioinspired Durable Antibacterial and Antifouling Coatings Based on Borneol Fluorinated Polymers: Demonstrating Direct Evidence of Antiadhesion

Fan Song et al.

Summary: A polymer coating made from natural substances with excellent antibacterial and antifouling properties was reported. The coating incorporating fluorine elements and borneol demonstrated exceptional environmental friendliness and long-term stability.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Review Engineering, Environmental

Strategies to improve the adsorption properties of graphene-based adsorbent towards heavy metal ions and their compound pollutants: A review

Qiaoping Kong et al.

Summary: Graphene has large specific surface area and high adsorption efficiency, but its tendency to stack together can limit its adsorption performance. Special strategies such as surface functionalization regulation, morphology and structure control are needed to improve the adsorption properties of graphene-based adsorbents for heavy metal removal.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Physical

Hybrid water vapor sorbent design with pollution shielding properties: extracting clean water from polluted bulk water sources

Renyuan Li et al.

Summary: SWEAPS is a simple water extraction apparatus designed to produce clean water from various polluted sources through water vapor harvesting. It has self-floating capability and the ability to filter out contaminants, allowing it to harvest clean water vapor above the source-water-air interface.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage

Bingna Zheng et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Multifunctional β-Cyclodextrin Polymer for Simultaneous Removal of Natural Organic Matter and Organic Micropollutants and Detrimental Microorganisms from Water

Xuejiao Hu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Applied

Borneol-modified chitosan: Antimicrobial adhesion properties and application in skin flora protection

Yu Xin et al.

CARBOHYDRATE POLYMERS (2020)

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Article Chemistry, Physical

Bio-inspired fabrication of Ester-functionalized imprinted composite membrane for rapid and high-efficient recovery of lithium ion from seawater

Chao Yu et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Sulfonic acid modified hollow polymer nanospheres with tunable wall-thickness for improving biodiesel synthesis efficiency

Wenliang Song et al.

GREEN CHEMISTRY (2020)

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Article Engineering, Environmental

Oxygen-rich hyper-cross-linked polymers with hierarchical porosity for aniline adsorption

Yangqi Gan et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Materials Science, Multidisciplinary

Laser-induced graphene and carbon nanotubes as conductive carbon-based materials in environmental technology

Chidambaram Thamaraiselvan et al.

Materials Today (2019)

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Article Chemistry, Multidisciplinary

Guided Assembly of Well-Defined Hierarchical Nanoporous Polymers by Lewis Acid-Base Interactions

Wenliang Song et al.

ACS NANO (2019)

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Article Chemistry, Applied

Preparation of acrylamide/acrylic acid cellulose hydrogels for the adsorption of heavy metal ions

Binchan Zhao et al.

CARBOHYDRATE POLYMERS (2019)

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Article Engineering, Environmental

Peroxydisulfate activation by positively polarized carbocatalyst for enhanced removal of aqueous organic pollutants

Chunyang Nie et al.

WATER RESEARCH (2019)

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Article Nanoscience & Nanotechnology

Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions

Ya Li et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

All-in-One Porous Polymer Adsorbents with Excellent Environmental Chemosensory Responsivity, Visual Detectivity, Superfast Adsorption, and Easy Regeneration

Yiming Xie et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Insight into the adsorption mechanisms of methylene blue and chromium(iii) from aqueous solution onto pomelo fruit peel

Van-Phuc Dinh et al.

RSC ADVANCES (2019)

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Article Nanoscience & Nanotechnology

pH-Responsive Nanoscale Covalent Organic Polymers as a Biodegradable Drug Carrier for Combined Photodynamic Chemotherapy of Cancer

Hairong Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

Ultrastable Imine-Based Covalent Organic Frameworks for Sulfuric Acid Recovery: An Effect of Interlayer Hydrogen Bonding

Arjun Halder et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Review Chemistry, Multidisciplinary

Versatile Antibacterial Materials: An Emerging Arsenal for Combatting Bacterial Pathogens

Xiaokang Ding et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Polymer Science

Diblock copolymer containing bioinspired borneol and dopamine moieties: Synthesis and antibacterial coating applications

Xin Wang et al.

POLYMER (2017)

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Article Polymer Science

Swellable functional hypercrosslinked polymer networks for the uptake of chemical warfare agents

Craig Wilson et al.

POLYMER CHEMISTRY (2017)

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Article Biophysics

Antifungal graphene oxide-borneol composite

Guofeng Li et al.

COLLOIDS AND SURFACES B-BIOINTERFACES (2017)

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Article Nanoscience & Nanotechnology

Graphene Oxide/Chitosan Aerogel Microspheres with Honeycomb Cobweb and Radially Oriented Microchannel Structures for Broad Spectrum and Rapid Adsorption of Water Contaminants

Ruomeng Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Nanoscience & Nanotechnology

Antibacterial Adhesion of Poly(methyl methacrylate) Modified by Borneol Acrylate

Xueli Sun et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Biochemistry & Molecular Biology

Hierarchical Polymer Brushes with Dominant Antibacterial Mechanisms Switching from Bactericidal to Bacteria Repellent

Shunjie Yan et al.

BIOMACROMOLECULES (2016)

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Article Chemistry, Multidisciplinary

Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)

San-Yuan Ding et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Letter Multidisciplinary Sciences

Recover wastewater resources locally

Zhiyong Jason Ren et al.

NATURE (2016)

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Article Chemistry, Multidisciplinary

Borneol-grafted cellulose for antifungal adhesion and fungal growth inhibition

Bing Shi et al.

RSC ADVANCES (2015)

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Article Nanoscience & Nanotechnology

Antibacterial Adhesion of Borneol-Based Polymer via Surface Chiral Stereochemistry

Lingqiong Luo et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Article Nanoscience & Nanotechnology

Electrospun Borneol-PVP Nanocomposites

Xiao-Yan Li et al.

JOURNAL OF NANOMATERIALS (2012)

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Article Chemistry, Multidisciplinary

Antibacterial Activity of Graphite, Graphite Oxide, Graphene Oxide, and Reduced Graphene Oxide: Membrane and Oxidative Stress

Shaobin Liu et al.

ACS NANO (2011)

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Article Chemistry, Multidisciplinary

Electronic-Structure-Dependent Bacterial Cytotoxicity of Single-Walled Carbon Nanotubes

Chad D. Vecitis et al.

ACS NANO (2010)

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Article Chemistry, Multidisciplinary

Temperature responsive channel uniformity impacts on highly guest-selective adsorption in a porous coordination polymer

Ryotaro Matsuda et al.

CHEMICAL SCIENCE (2010)

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Article Chemistry, Physical

Hydrogen storage in microporous hypercrosslinked organic polymer networks

Colin D. Wood et al.

CHEMISTRY OF MATERIALS (2007)

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Review Multidisciplinary Sciences

The challenge of micropollutants in aquatic systems

Rene P. Schwarzenbach et al.

SCIENCE (2006)

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Article Biotechnology & Applied Microbiology

Antimicrobial agents from plants: antibacterial activity of plant volatile oils

HJD Dorman et al.

JOURNAL OF APPLIED MICROBIOLOGY (2000)

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Smart L-borneol-loaded hierarchical hollow polymer nanospheres with antipollution and antibacterial capabilities

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