Optimization of the Flotation of Low-Grade Phosphate Ore Using DOE: a Comparative Evaluation of Fatty Acid Formulation to Sodium Oleate

Phosphate ores upgraded by flotation are widely used as vital raw materials for the sustainable production of phosphate fertilizers to maintain the food supply. High-grade phosphate reserves become more and more depleted. Low-grade phosphate mining and processing are in the spotlight of the fertilizer industries to cope with the exponential growth in the world's population and meet the increased demand for fertilizers. As part of a series of research works conducted within a major project aiming at upgrading a low-grade phosphate ore never-exploited before, the present work endeavors to optimize the flotation of this ore using the response surface method (RSM) as a follow-up of a screening study. Unveiling new insights on such a strategy paved the way for improving flotation performances. This work demonstrated that an optimum 30.18% P2O5 with 88.07% recovery was achieved using 63.10 g/t of sodium alginate (NaAL) and 2484.72 g/t of sodium oleate (NaOL) at pH 11.40. This maximum was contrasted with a new formulation of fatty acids (FAM). The 30.76% P2O5 grade with a recovery of 89.72% was attained using 50.94 g/t of NaAL and 1455.40 g/t of FAM at pH 11.68. FAM collector markedly outperformed NaOL at low concentrations proving the efficiency of synergists.

Automated summary

Phosphate ores are important raw materials for phosphate fertilizers, but high-grade reserves are depleting. This study optimizes the flotation process of a low-grade phosphate ore, finding an effective formulation to achieve high P2O5 grade and recovery rate.