☆ 4.6 Review

Recent advances in the elimination of persistent organic pollutants by photocatalysis

FRONTIERS IN ENVIRONMENTAL SCIENCE (2022)

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Article Environmental Sciences

Polyhedral magnetite nanoparticles modified with porous bio-templated copper oxide as catalyst for visible-light-driven photodegradation of methylene blue

O. A. Alani et al.

Summary: A visible-light-driven bio-templated magnetic copper oxide photocatalyst was prepared for the degradation of methylene blue. The synthesized composite showed high degradation efficiency in the visible light-assisted heterogeneous Fenton process and could be reused multiple times.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2023)

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Article Environmental Sciences

Homogeneous photocatalytic degradationof azo dye Reactive Black 5 using Fe(III) ions under visible light

Shailaja P. Sadhu et al.

Summary: Efficient and cost-effective method using homogeneous photocatalytic oxidation (PCO) with ferric ions (Fe(III)) under visible light (VL) and sunlight (SL) was studied for destroying Reactive Black 5 (RB5) dye. Fe(III)-induced homogeneous PCO appears to be a reliable and low-cost method of advanced oxidation without the need for costly reagents such as H2O2.

ENVIRONMENTAL TECHNOLOGY (2022)

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Article Environmental Sciences

Degradation of tetracycline hydrochloride in aqueous via combined dielectric barrier discharge plasma and Fe-Mn doped AC

Jian Cheng et al.

Summary: The combination of dielectric barrier discharge (DBD) plasma with Fe-Mn doped AC (Fe-Mn/AC) catalyst was used to enhance the degradation of tetracycline hydrochloride (TCH) wastewater, showing high efficiency and stability. The reaction mechanism is complex, with the potential for application in water treatment.

CHEMOSPHERE (2022)

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Review Biochemical Research Methods

Nanomaterials for electrochemical detection of pollutants in water: A review

Humberto Andre Potes-Lesoinne et al.

Summary: The survival of living beings, including humanity, relies on a continuous supply of clean water, but industrial and population growth have led to increasing wastewater discharge, necessitating measures to monitor and treat pollutants in water bodies. This paper reviews the latest developments in micro- and nano-electrochemical devices for detecting pollutants in wastewater, with a focus on versatile materials such as Cu, Co, and Bi.

ELECTROPHORESIS (2022)

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Article Environmental Sciences

Enhanced degradation of complex organic compounds in wastewater using different novel continuous flow non-Thermal pulsed corona plasma discharge reactors

Narasamma Nippatlapalli et al.

Summary: This study focuses on the degradation of pharmaceutically active compounds in water bodies using pulsed corona plasma technology. Three different plasma reactors were designed and experimented, showing that continuous flow reactors achieved higher degradation efficiency, shorter treatment time, and lower energy consumption.

ENVIRONMENTAL RESEARCH (2022)

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Review Environmental Sciences

Recent advances in photocatalytic remediation of emerging organic pollutants using semiconducting metal oxides: an overview

Komargoud Prakruthi et al.

Summary: Currently, untreated or partly treated wastewater from households and commercial sources containing unknown and complex compounds is being discharged into aquatic environments, leading to severe environmental problems that impact human health. Photocatalysis, as an advanced oxidation process, has emerged as an efficient method for removing emerging organic pollutants. Semiconducting nanometal oxides have become pioneering photocatalysts due to their large active surface sites, flexible oxidation states, and easy preparation.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

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Article Engineering, Environmental

Photocatalytic degradation of Penicillin G in aqueous solutions: Kinetic, degradation pathway, and microbioassays assessment

Mohammed Berkani et al.

Summary: The study investigated the photocatalytic degradation of pharmaceutical micropollutants of Penicillin G at a laboratory scale, with promising results in terms of efficiency enhancement by persulfate sodium. Various analytical methods were employed to identify the degradation mechanism, and the safety of the degradation products was confirmed through microbial toxicity assessment with selected bacterial strains.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Engineering, Environmental

A novel electro-Fenton process coupled with sulfite: Enhanced Fe3+ reduction and TOC removal

Ge Song et al.

Summary: The Fe3+-EF/sulfite process enhances the degradation and mineralization of organic pollutants by preventing Fe3+ precipitation and accelerating the iron cycle, resulting in improved H2O2 utilization efficiency and reduced electric energy consumption. Reactive species like SO3 center dot-, SO4 center dot-, center dot OH, O-2(center dot-) and O-1(2) were identified as responsible for the degradation of pollutants in the process. The process also broadens the pH application range and shows great potential for cost-effective removal of refractory organic pollutants.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Environmental Sciences

Degradation of benzothiazole pollutant by sulfate radical-based advanced oxidation process

Jie Ma et al.

Summary: Benzothiazole (BTH) has been successfully degraded using sulfate radical-based advanced oxidation process (AOP) technique in this study. Several influencing factors were identified, and the primary radical(s) responsible for BTH degradation were determined.

ENVIRONMENTAL TECHNOLOGY (2022)

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Article Environmental Sciences

Cobalt-ferrite/Ag-fMWCNT hybrid nanocomposite catalyst for efficient degradation of synthetic organic dyes via peroxymonosulfate activation

M. O. Abdel-Salam et al.

Summary: The activation of peroxymonosulfate (PMS) by magnetic CoFe2O4/Ag-nanoparticles anchored on functionalized multiwalled carbon nanotubes (fMWCNTs) has shown high effectiveness in degrading dyes in wastewater. The optimized CoFe2O4/Ag-fMWCNT catalyst achieved complete removal of 20ppm dye concentration within 14 minutes. The study also investigated the surface morphologies and physicochemical properties of the catalyst, as well as the influence of reaction parameters on dye degradation efficiency.

ENVIRONMENTAL RESEARCH (2022)

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Article Engineering, Environmental

Solar light photocatalytic transformation of heptachlorobiphenyl (PCB 180) using g-C3N4 based magnetic porous photocatalyst

Hui Wang et al.

Summary: A novel porous core-shell magnetic beta-cyclodextrin/graphitic carbon nitride photocatalyst was synthesized and used in a solar light driven catalytic system for the degradation of polychlorinated biphenyls (PCBs). The catalytic performance of the photocatalyst was enhanced by its porous structure and ultrathin GCN nanosheets design. The high specific surface area provided numerous active sites for pollutant adsorption and degradation.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Enhanced UV-assisted Fenton performance of nanostructured biomimetic α-Fe2O3 on degradation of tetracycline

Hadiza Abdullahi Ari et al.

Summary: Nanostructured alpha-Fe2O3 (hematite) was successfully synthesized using plant extract without additional toxic agents, showing enhanced catalytic performance. The synthesized material exhibited good crystallinity and large surface area, making it efficient for degrading tetracycline. The catalyst showed high activity in UV-Fenton degradation and could be reused multiple times without significant loss in activity.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2022)

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Article Environmental Sciences

Effect of non-metal doping on the photocatalytic activity of titanium dioxide on the photodegradation of aqueous bisphenol A

Chao-Yin Kuo et al.

Summary: The study involved doping non-metals B, N, P, and I into TiO2 to form photocatalyst particles, which were characterized using XRD, UV-visible absorption spectroscopy, and XPS to elucidate the mechanism of doping. Doping with B, N, P, and I greatly enhanced the effectiveness of the photocatalyst in degrading BPA under sunlight.

ENVIRONMENTAL TECHNOLOGY (2021)

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Article Environmental Sciences

Efficient removal of cytotoxic drugs from wastewater by single-stage combined photocatalysis-algae treatment process

Farnaz Kouchakpour et al.

Summary: The study evaluates the efficiency of a single-stage combined photocatalysis-algae treatment process in removing the anticancer drug FLU from aqueous solution. Compared to individual treatment methods, the combined system achieved a higher FLU removal efficiency in a shorter reaction time. Kinetics studies demonstrated a synergistic effect between algal treatment process and photocatalysis.

ENVIRONMENTAL TECHNOLOGY (2021)

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Review Environmental Sciences

State-of-the-art and current challenges for TiO2/UV-LED photocatalytic degradation of emerging organic micropollutants

Danilo Bertagna Silva et al.

Summary: The development of UV-LED technology presents new possibilities for TiO(2) photocatalysis, but further research is needed on its application in real water matrices and environmentally relevant concentrations. To reduce costs, improving UV-LED efficiency, optimizing light uniformity, and adopting efficiency enhancement options like periodic illumination, wavelength coupling, and H(2)O(2) addition are essential.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Article Engineering, Chemical

Evaluation of the sono-assisted photolysis method for the mineralization of toxic pollutants

Ritesh Patidar et al.

Summary: The review focuses on combined sono-photolysis techniques for the degradation of persistent organic pollutants, showing that the synergistic effect of ultrasound and ultraviolet light can effectively enhance the degradation efficiency of toxic pollutants. The physical feature of ultrasound facilitates intense mixing of the pollutant, allowing UV light to penetrate deeply and accelerate oxidation reactions, leading to improved degradation of pollutants.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Review Environmental Sciences

Synthesis and catalytic utilization of bimetallic systems for wastewater remediation: A review

Khyle Glainmer N. Quiton et al.

Summary: This study investigates the application of bimetallic catalysts in water and wastewater treatment, finding that Fe-based bimetallic catalysts are one of the most efficient heterogeneous catalysts for the treatment of organic and inorganic contamination. The roles and performances of bimetallic catalysts in the removal of environmental contaminants vary.

CHEMOSPHERE (2021)

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Review Environmental Sciences

Biotechnology and nanotechnology for remediation of chlorinated volatile organic compounds: current perspectives

Parisa Ebrahimbabaie et al.

Summary: CVOCs are harmful organic pollutants, and this review summarizes recent innovative treatment solutions for CVOC-affected media, aiming to provide a basic framework for selecting successful CVOC remediation strategies.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Article Engineering, Environmental

Application of advanced materials in sonophotocatalytic processes for the remediation of environmental pollutants

Jayaraman Theerthagiri et al.

Summary: Significant industrial advancements have led to the release of toxic pollutants into the environment, necessitating efficient wastewater treatment processes to reduce contamination. Photocatalytic degradation is considered effective, but has limitations. Combining sonolysis with photocatalysis shows benefits for environmental remediation by utilizing more active radicals to degrade organic pollutants.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Review Chemistry, Inorganic & Nuclear

Conventional to green synthesis of magnetic iron oxide nanoparticles; its application as catalyst, photocatalyst and toxicity: A short review

Saikatendu Deb Roy et al.

Summary: This review discusses the biosynthetic approach of using plant-based origin to synthesize iron oxide nanoparticles, which is environmentally friendly and cost-effective. The size of the nanoparticles is dependent on the synthetic route, pH, and temperature, with their catalytic application closely related to size. Magnetic iron oxides have shown potent catalytic activity in organic reactions, and their efficiency can be enhanced through decoration with other substances.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

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Review Chemistry, Multidisciplinary

Strategies for SERS Detection of Organochlorine Pesticides

Rebeca Moldovan et al.

Summary: Organochlorine pesticides (OCPs) are highly lipophilic chemicals that are being phased out globally due to their persistent nature and detrimental effects on human health and the environment. Traditional separation techniques like gas chromatography are accurate but expensive and time-consuming, prompting researchers to seek faster and more cost-effective alternatives for detection and quantification of OCPs.

NANOMATERIALS (2021)

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Article Environmental Sciences

Utilization of solar energy for wastewater treatment: Challenges and progressive research trends

A. K. Pandey et al.

Summary: This article discusses the trends in the use of photocatalysis process, desalination technologies, and solar disinfection techniques for treating industrial and domestic wastewater. It highlights the global water crisis, major pollutants, and environmental impacts. The article also emphasizes the benefits of using solar power for wastewater treatment.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2021)

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Review Chemistry, Multidisciplinary

Review of aminopolycarboxylic acids-based metal complexes application to water and wastewater treatment by (photo-)Fenton process at neutral pH

Prisco Prete et al.

Summary: The development and application of active catalysts for Fenton and photo-Fenton processes at neutral pH for tertiary wastewater treatment are crucial for future industrial scale advanced oxidation processes. Current limitations in full-scale Fenton and photo-Fenton application are due to the need for acidic pH, and this review suggests new perspectives for catalytic systems design following the 12 principles of green chemistry.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2021)

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Article Environmental Sciences

Remediation of phenanthrene contaminated soil by ferrous oxalate and its phytotoxicity evaluation

Zhijun Luo et al.

Summary: The photochemical process of ferrous oxalate effectively degrades phenanthrene in contaminated soil under visible light irradiation by generating hydroxyl radicals. Ferrous oxalate possesses excellent visible light absorption ability, which is crucial for enhancing the degradation efficiency of phenanthrene.

CHEMOSPHERE (2021)

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Review Chemistry, Inorganic & Nuclear

Sensors for the environmental pollutant detection: Are we already there?

Yi Zhang et al.

Summary: Sensors, integrating various sciences, have great potential in environmental detection despite the complexity of environmental samples. There is a need for further development of simple, efficient, low-cost, and in-situ sensor strategies for pollutants detection.

COORDINATION CHEMISTRY REVIEWS (2021)

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Review Engineering, Environmental

Current progress in degradation and removal methods of polybrominated diphenyl ethers from water and soil: A review

Bin Yao et al.

Summary: The widespread presence of PBDEs in the environment has raised concerns, and finding a proper remediation method is urgent. A comprehensive evaluation of different techniques for PBDEs remediation is urgently needed.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Physical

First evidence of a photochemical process including an iron-aspartate complex and its use for paracetamol elimination from aqueous solution

Mohamed Elhadi Benssassi et al.

Summary: This study investigates the photochemical properties of Fe(III)-Aspartate complex and its ability to degrade paracetamol in aqueous solution under UVA irradiation. The complex undergoes photolysis to form reactive oxygen species, with degradation efficiency depending on irradiation wavelength and pH. The presence of Fe(III)-Asp complex significantly enhances paracetamol degradation, while the addition of Zn(II) and Mn(II) has no significant effect, and Cu(II) slightly inhibits degradation.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2021)

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Review Environmental Sciences

Detection and remediation of pollutants to maintain ecosustainability employing nanotechnology: A review

Neelam Yadav et al.

Summary: Environmental deterioration caused by human activities poses a threat to sustainable, clean, and green environment. Environmental nanotechnology provides an innovative solution by reducing unnecessary use of raw materials, electricity, excessive use of agrochemicals, and release of industrial effluents.

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CFD analysis of a H2O2/UVC water treatment process in the annular FluHelik reactor

Sayonara Vanessa de Medeiros Lima et al.

Summary: This study focused on the photochemical degradation of tetracycline in the innovative photoreactor FluHelik, using computational fluid dynamics (CFD) simulations to optimize operational conditions and enhance reactor performance at the laboratory scale.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

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Review Environmental Sciences

Pre-oxidation enhanced cyanobacteria removal in drinking water treatment: A review

Jing Qi et al.

Summary: Cyanobacterial bloom has negative impacts on source water quality and drinking water production, while pre-oxidation can improve the removal of cyanobacteria in solid-liquid separation processes. Moderate pre-oxidation may enhance the efficiency of cyanobacteria removal.

JOURNAL OF ENVIRONMENTAL SCIENCES (2021)

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Article Engineering, Environmental

Degradation of roxarsone in UV-based advanced oxidation processes: A comparative study

Lu Chen et al.

Summary: The degradation of roxarsone (ROX) via UV-based advanced oxidation processes (AOPs) was investigated, with UV/PDS being the most effective in removing ROX and UV/H2O2 being the most effective in reducing total organic carbon (TOC). The degradation of ROX follows a pseudo-first-order kinetics model, with a significant enhancement observed at pH 11.0 in UV/PMS process.

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Review Chemistry, Multidisciplinary

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Sasanka Peiris et al.

Summary: Photocatalysis is a clean technology process converting solar energy to useful reactions, but efficiency of TiO2 is limited. Scientists aim to enhance efficiency by implementing various modification strategies to overcome barriers and limitations in TiO2 photocatalysis.

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Remediation of emerging environmental pollutants: A review based on advances in the uses of eco-friendly biofabricated nanomaterials

Gurulingaiah Bhavya et al.

Summary: Environmental pollutants from human activities are posing adverse effects on the planet, especially heavy metals and organic pollutants are considered significant worldwide. Recent research focus has shifted towards developing cost-effective technologies as traditional methods are ineffective in eliminating pollutants, with biofabricated nanomaterials showing potential for sustainable environmental remediation.

CHEMOSPHERE (2021)

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Review Environmental Sciences

Bioremediation strategies with biochar for polychlorinated biphenyls (PCBs)-contaminated soils: A review

Soheil Valizadeh et al.

Summary: Biochar (BC) is an eco-friendly carbonaceous material that can be utilized for the remediation of PCBs-contaminated soils. Studies have shown that BC is beneficial for soil quality enhancement and agricultural productivity, with synergy effects on PCBs-contaminated soils.

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Integration of an aminopyridine derived cobalt based homogenous cocatalyst with a composite photocatalyst to promote H2 evolution from water

Rana Muhammad Irfan et al.

Summary: The study introduced the utilization of a cobalt based homogeneous cocatalyst with composite photocatalyst CdS/Ni3C, significantly enhancing the hydrogen production rate. The homogeneous cocatalyst did not occupy the active sites of the photosensitizer, paving the way for capturing electrons and enhancing the photocatalytic performance for low-cost H-2 evolution under visible light.

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Semiconductor based photocatalysts for detoxification of emerging pharmaceutical pollutants from aquatic systems: A critical review

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Comparison of emerging contaminant abatement by conventional ozonation, catalytic ozonation, O3/H2O2 and electro-peroxone processes

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Surface oxygen vacancies enriched FeOOH/Bi2MoO6 photocatalysis- fenton synergy degradation of organic pollutants

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Visible-light driven degradation of tetracycline hydrochloride and 2,4-dichlorophenol by film-like N-carbon@N-ZnO catalyst with three-dimensional interconnected nanofibrous structure

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Article Engineering, Chemical

Recovery of magnetite from fluidized-bed homogeneous crystallization of iron-containing solution as photocatalyst for Fenton-like degradation of RB5 azo dye under UVA irradiation

Nicolaus N. N. Mahasti et al.

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Heterogeneous Photocatalysis Scalability for Environmental Remediation: Opportunities and Challenges

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Efficient degradation of organic pollutants by catalytic ozonation and photocatalysis synergy system using double-functional MgO/g-C3N4 catalyst

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APPLIED SURFACE SCIENCE (2020)

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Efficient degradation of chloroquine drug by electro-Fenton oxidation: Effects of operating conditions and degradation mechanism

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Photo-Fenton oxidation of Orange G azo dye: process optimization and mineralization mechanism

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Photochemical Anti-Fouling Approach for Electrochemical Pollutant Degradation on Facet-Tailored TiO2 Single Crystals

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In Situ Photochemical Activation of Sulfate for Enhanced Degradation of Organic Pollutants in Water

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Heterogeneous Catalysis on Metal Oxides

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Diclofenac degradation using mont-La (6%)-Cu0.6Cd0.4S as photocatalyst under NUV-Vis irradiation. Operational parameters, kinetics and mechanism

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Photocatalytic degradation of perfluorooctanoic acid and perfluorooctane sulfonate in water: A critical review

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Comparative study of acid blue 113 wastewater degradation and mineralization by UV/persulfate and UV/Oxone processes

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Advanced approach for degradation of recalcitrant by nanophotocatalysis using nanocomposites and their future perspectives

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Photo-oxidation of Tributyltin, Dibutyltin and Monobutyltin in Water and Marine Sediments

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Photocatalytic degradation of acetaminophen in aqueous solutions by TiO2/ZSM-5 zeolite with low energy irradiation

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Heterogeneous Photocatalysis: Recent Advances and Applications

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Efficient photochemical water splitting and organic pollutant degradation by highly ordered TiO2 nanopore arrays

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Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems

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TiO2-mediated photocatalytic degradation of a triphenylmethane dye (gentian violet), in aqueous suspensions

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