期刊
JOURNAL OF SEPARATION SCIENCE
卷 39, 期 23, 页码 4603-4609出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201600619
关键词
Gas chromatography with mass spectrometry; On-site extraction; Tablet effervescence; Triazole fungicides; Water
资金
- Nature Science Foundation of Zhejiang Province [LY16B050008]
- Science and Technology Department of Zhejiang Province [2015C32006]
- Key Laboratory of Detection for Pesticide Residues of Ministry of Agriculture Project [2014PRG01]
- Hangzhou Qianjiang Distinguished Experts Project
- New Talents Program for Science and Technology Department of Zhejiang Province [2016R403079]
A pretreatment method named tablet-effervescence-assisted dissolved carbon flotation was introduced for the determination of four triazole fungicides in environmental water. In this method, the use of effervescent tablet composed of nontoxic sodium carbonate and sodium dihydrogen phosphate could generate CO2 in situ to assist the dispersion of extraction solvent and to accelerate mass transfer of target analytes. In addition, the simple phase separation simply based on the rising of low-density organic solvent from the aqueous phase was applied rather than the application of apparatus, which demonstrated the potential for on-site extraction in the field. The experimental variables, including the composition of effervescent tablets, amount of effervescent tablets, types and volume of extraction solvent, were investigated. Under the optimized conditions, the method showed good linearity for myclobutanil, tebuconazole, epoxiconazole, and difenoconazole in the range of 1-100 mu g/L. The limits of detection and the limits of quantification were within the range of 0.15-0.26 and 0.49-0.86 mu g/L, respectively. The obtained correlation coefficients varied from 0.997 to 0.999, and suitable enrichment factors were 422-589. The recoveries were 82.5-112.9% with relative standard deviations of 4.7-13.5%.
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