Synergetic recognition and separation of kelthane and pyridaben base on magnetic molecularly imprinted polymer nanospheres

We present novel magnetic composite nanospheres for the preparation of a nanoiron oxide/carbon dots/beta-cyclodextrin/molecularly imprinted polymer for the selective solid-phase extraction kelthane and pyridaben from vegetables. The molecularly imprinted polymer was synthesized on the surface of nano-iron oxide/carbon dots via a chemical polymerization procedure, where kelthane-beta-cyclodextrin and pyridaben-beta-cyclodextrin inclusion complexes were used as template molecules, and their adsorption behavior was investigated in detail. Characterization analysis and binding experiments revealed that magnetic composite nanospheres had outstanding magnetic properties, a large adsorption capacity, and high competitive selectivity for kelthane and pyridaben. The magnetic composite nanospheres were employed as an adsorbent in solid- phase extraction for the determination of kelthane and pyridaben in vegetable samples. The recoveries of kelthane and pyridaben were 92.8-105.2 and 94.4-104.6%, respectively.