Novel polyhydroxy cationic collector N-(2,3-propanediol)-N- dodecylamine: Synthesis and flotation performance to hematite and quartz

To enhance the performance of traditional cationic collector, a novel polyhydroxy amine collector N-(2,3-Propanediol)-N-dodecylamine (PDDA) was designed by introducing one propylene glycol group into dodecylamine (DDA). It was prepared by a nucleophilic substitution reaction, which showed better sol-ubility and hydrophobicity than DDA and was firstly employed as the collector for the separation of hematite and quartz. Flotation tests showed that PDDA had an excellent flotation performance and sig-nificantly better selectivity than DDA. In addition, the flotation performance and adsorption mechanism of PDDA on hematite and quartz surfaces were studied using Fourier transform infrared spectroscopy (FT-IR), zeta potential and X-ray photoelectron spectroscopy (XPS) tests. These results demonstrated that the interaction between PDDA and the minerals' surfaces was mainly electrostatic adsorption and hydrogen bond, while PDDA tended to adsorb on the surfaces of quartz more than that of hematite. Performance optimization of amine collectors by introducing hydroxyl was also verified, which was of great meaning to the design, development, and application of the polyhydroxy cationic collector. In conclusion, PDDA could be used as a potential collector in the flotation separation of quartz and hematite.(c) 2022 Published by Elsevier B.V. on behalf of China University of Mining & Technology. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

To enhance the performance of cationic collectors, a novel polyhydroxy amine collector called N-(2,3-Propanediol)-N-dodecylamine (PDDA) was designed by introducing a propylene glycol group into dodecylamine (DDA). PDDA showed better solubility and hydrophobicity than DDA and demonstrated excellent flotation performance and selectivity for the separation of hematite and quartz. The interaction between PDDA and the mineral surfaces was mainly electrostatic adsorption and hydrogen bonding, with a higher affinity of PDDA for quartz surfaces. The optimization of amine collectors by introducing hydroxyl has significant implications for the design, development, and application of polyhydroxy cationic collectors.