Recovery in oxidation behavior of damaged SiC-ZrB2/SiC coating of carbon/carbon composites

Polysiloxane (PSO) was adopted as the matrix of the repair agents, and SiC-ZrB2 powder was used as the filler, to repair the prefabricated defects on the SiC-ZrB2/SiC (SZS) coating of carbon/carbon (C/C) composites. The repair agents were brushed on the defect areas and then underwent preoxidation (PR) or heat-treatment (HR) in a vacuum. The effects of different treatment processes on the chemical composition, microstructure of the repair agents, and the oxidation resistance behavior of the repaired coating were investigated. The repaired agents after both processes were pyrolyzed and generated SiOC ceramics, and they were well combined with the original coating. The thermal stability of PSO after preoxidation is poorer than that after heat-treatment, resulting in a weight loss rate of 5.88% after oxidation at 1 500 degrees C for 270 min, while that of the HR coating is only-0.87%, yet both have been great improvement compared with the unrepaired coating. This work provides an effective and simple approach to repairing damaged coatings for high-temperature applications.(c) 2022 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

Polysiloxane (PSO) was used as the matrix and SiC-ZrB2 powder as the filler to repair prefabricated defects on the SiC-ZrB2/SiC coating of carbon/carbon (C/C) composites. Different treatment processes were applied to investigate their effects on the repair agents' chemical composition, microstructure, and oxidation resistance behavior. Both processes resulted in pyrolysis and the generation of SiOC ceramics, which were well combined with the original coating. The repaired coatings showed improved thermal stability and oxidation resistance compared to the unrepaired coating, providing an effective and simple approach for repairing damaged coatings in high-temperature applications.