4.6 Article

Pressure-induced charge orders and their postulated coupling to magnetism in hexagonal multiferroic LuFe2O4

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Crystallographical and morphological changes in charge-ordering transition of RFe2O4 (R: Y, Lu) investigated by transmission electron microscopy

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Summary: Temperature dependence of charge-ordered crystal structures and domain structures in RFe2O4 (R: Y and Lu) was studied using energy-filtered transmission electron microscopy and conventional transmission electron microscopy. The results showed a transition from three-dimensional to two-dimensional charge ordering in both YFe2O4 and LuFe2O4 upon heating, with YFe2O4 exhibiting less anisotropic nanometer-scale charge-ordered domains compared to LuFe2O4. The findings indicate the significance of interchange interactions between Fe-O bilayers in addition to those within bilayers in the structural phase transitions associated with charge ordering in RFe2O4.

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