Solar-Driven Water Splitting in Photovoltaic Electrolysis Systems Using Copper Terpyridine Complexes as Oxygen Evolution Catalysts

Article Chemistry, Multidisciplinary

Enhanced Photoelectrochemical Water Splitting of Black Silicon Photoanode with pH-Dependent Copper-Bipyridine Catalysts

Jing-Xin Jian et al.

Summary: In this study, a bio-inspired copper-bipyridine catalyst was decorated on a nanoporous Si photoanode, resulting in high photocurrent density and pH-dependent water oxidation behavior.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Physical

Perfect Matching Factor between a Customized Double-Junction GaAs Photovoltaic Device and an Electrolyzer for Efficient Solar Water Splitting

Zaki N. Zahran et al.

Summary: A customized double-junction GaAs / GaAs photovoltaic (PV) device was matched with an efficient electrolyzer to achieve a perfect performance match. Under solar irradiation, the efficient and stable solar water splitting with high solar-to-hydrogen efficiency was demonstrated. This study highlights the importance of the perfect matching between the PV device and the electrolyzer, as well as the development of efficient electrolyzers, for improving the solar-to-hydrogen efficiency and stability.

ACS APPLIED ENERGY MATERIALS (2022)

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Article Chemistry, Physical

Surface engineering of nanoporous silicon photocathodes for enhanced photoelectrochemical hydrogen production

Jing-Xin Jian et al.

Summary: Surface-engineered nanoporous Si photocathodes with controllable surface morphologies were fabricated to enhance the efficiency of photoelectrochemical water splitting. The photocathodes exhibited improved light-harvesting efficiency, surface area, and electron transfer, resulting in significantly enhanced hydrogen production. The deposition of n-type TiO2 on the Si surface further increased charge separation and water splitting stability.

CATALYSIS SCIENCE & TECHNOLOGY (2022)

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Review Chemistry, Physical

Multifunctional materials for photo-electrochemical water splitting

P. Mary Rajaitha et al.

Summary: This review highlights the application of multifunctional materials in photo-electrochemical water splitting for efficient hydrogen production. Different types of water-splitting methods and the selection of multifunctional materials can lead to improved results.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Review Chemistry, Multidisciplinary

Homogeneous Catalysts Based on First-Row Transition-Metals for Electrochemical Water Oxidation

Lu-Hua Zhang et al.

Summary: The pursuit of renewable production of storable fuels through electrocatalysis, particularly with water oxidation catalysis, remains a key focus in the scientific community. The coupling of these redox transformations to renewable energy sources presents a carbon neutral solution for long-term energy storage, yet challenges such as scalability still need to be addressed.

CHEMSUSCHEM (2021)

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Article Chemistry, Multidisciplinary

Nanoporous Cubic Silicon Carbide Photoanodes for Enhanced Solar Water Splitting

Jing-Xin Jian et al.

Summary: Cubic silicon carbide (3C-SiC) shows promise as a photoelectrode material for solar water splitting due to its small band gap and ideal energy band positions, but typically experiences reduced photocurrent despite the presence of various oxygen-evolution-reaction (OER) cocatalysts.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Bioinspired Trinuclear Copper Catalyst for Water Oxidation with a Turnover Frequency up to 20000 s-1

Qi-Fa Chen et al.

Summary: Researchers have developed a copper cluster inspired by multicopper oxidases, which shows remarkable catalytic reactivity towards water oxidation for efficient four-electron reduction of O-2 to water. This synthetic mimic demonstrates the effectiveness of cooperation between multiple metals in regulating O-O bond formation in water oxidation catalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Flexible Ligand in a Molecular Cu Electrocatalyst Unfurls Bidirectional O2/H2O Conversion in Water

Afsar Ali et al.

Summary: The development of a stable molecular copper catalyst with a labile diimine-dioxime ligand framework enables rapid and complete electrocatalysis for both oxygen reduction and water oxidation. Computational investigations highlight the importance of the interactive ligand scaffold in accommodating variable oxidation states of copper and influencing the dynamics of O-O bond cleavage/formation during catalysis. This study establishes a template for designing molecular catalysts to mediate energy-relevant multi-electron/multi-proton reactions in both oxidizing and reducing environments.

ACS CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Photoelectrochemical Water-Splitting Using CuO-Based Electrodes for Hydrogen Production: A Review

Roozbeh Siavash Moakhar et al.

Summary: This article comprehensively reviews the recent advancements in CuO-based photoelectrodes for PEC water-splitting applications, highlighting their high activity and promising physicochemical properties. Various synthesis methods, characterization techniques, and fundamental factors of CuO-based photoelectrodes are discussed in detail. Additionally, the PEC properties of CuO/2D materials are also evaluated, demonstrating their potential as nanocomposites for photocurrent-generating devices.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Consecutive Ligand-Based Electron Transfer in New Molecular Copper-Based Water Oxidation Catalysts

Marcos Gil-Sepulcre et al.

Summary: This study presents a new family of water oxidation catalyst ligands, and provides experimental and computational evidence supporting an all ligand-based process occurring at pH 11.6.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Inorganic & Nuclear

Homogeneous oxidative transformations mediated by copper catalyst systems

Lindie Marais et al.

Summary: Oxidative transformations involve converting organic substrates into oxygenates for pharmaceutical and chemistry industries. The mechanistic pathways of Cu-based catalyst systems include the initial oxidation state of copper, the redox lability of these oxidation states and the nature of the Cu-based active species.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Multidisciplinary Sciences

The polar oxy-metabolome reveals the 4-hydroxymandelate CoQ10 synthesis pathway

Robert S. Banh et al.

Summary: The study reveals a previously unknown protein HPDL's involvement in the biosynthesis of CoQ10, providing crucial insights into diseases related to HPDL deficiencies and cancers with HPDL overexpression.

NATURE (2021)

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Article Chemistry, Physical

Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex

Ana M. Geer et al.

Summary: This study presents a trinuclear copper(II) complex as a homogeneous electrocatalyst for water oxidation, exhibiting high catalytic activity and selectivity under different pH conditions. Experimental and computational studies provide insights into the relationship between the copper complex and the catalytic mechanism, highlighting the importance of phosphate and nitrogen-based ligands in facilitating proton transfer processes.

ACS CATALYSIS (2021)

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Review Chemistry, Physical

Recent advances in photo-assisted electrocatalysts for energy conversion

Haoyue Zhang et al.

Summary: Electrocatalysts play a crucial role in enhancing electrochemical energy conversion/storage technologies. Recent interest in photo-assisted electrocatalysis has provided new advantages for catalytic activity, but is still in the preliminary stage. This review summarizes three primary strategies for photo-assisted electrocatalysis, highlighting key challenges and possible research directions for the future.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Design of molecular water oxidation catalysts with earth-abundant metal ions

Mio Kondo et al.

Summary: The review discusses the frontier of water oxidation reactions mediated by first-row transition metal complexes. Special attention is given to the design of molecular structures of the catalysts and their reaction mechanisms, which are expected to serve as guiding principles for creating efficient and robust molecular catalysts for water oxidation using ubiquitous elements.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Applied

O-O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts

Xue-Peng Zhang et al.

Summary: Water oxidation is a crucial reaction in both natural and artificial energy conversion processes, with the formation of O-O bonds being a key step that determines the rate of the reaction. Developing efficient water oxidation catalysts is essential for achieving large-scale water splitting.

CHINESE JOURNAL OF CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J. Li et al.

Summary: The text emphasizes the importance of reliable water oxidation catalysts (WOCs) for artificial photosynthesis on a large scale. It discusses the evolution of WOC research into molecular and heterogeneous branches, as well as the growing need for knowledge transfer between these two fields. The review highlights recent developments in both molecular and heterogeneous WOCs, focusing on design principles, mechanistic insights, and the benefits of combining the best of both catalyst types.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Energy & Fuels

A Review of Recent Progress on Silicon Carbide for Photoelectrochemical Water Splitting

Jingxin Jian et al.

SOLAR RRL (2020)

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Article Chemistry, Multidisciplinary

Redox Metal-Ligand Cooperativity Enables Robust and Efficient Water Oxidation Catalysis at Neutral pH with Macrocyclic Copper Complexes

Pablo Garrido-Barros et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Nanoscience & Nanotechnology

High Solar-to-Hydrogen Conversion Efficiency at pH 7 Based on a PV-EC Cell with an Oligomeric Molecular Anode

Yuanyuan Shi et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Review Chemistry, Multidisciplinary

Semiconductor nanocrystals for small molecule activation via artificial photosynthesis

Xu-Bing Li et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Energy & Fuels

Cubic SiC Photoanode Coupling with Ni:FeOOH Oxygen-Evolution Cocatalyst for Sustainable Photoelectrochemical Water Oxidation

Jingxin Jian et al.

SOLAR RRL (2020)

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Article Chemistry, Multidisciplinary

Two Trinuclear CuII Complexes: Effect of Phosphonate Ligand on the Magnetic Property and Electrocatalytic Reactivity for Water Oxidation

Jin-Miao Wang et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

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Review Chemistry, Multidisciplinary

Toward practical solar hydrogen production - an artificial photosynthetic leaf-to-farm challenge

Jin Hyun Kim et al.

CHEMICAL SOCIETY REVIEWS (2019)

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Review Chemistry, Multidisciplinary

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang et al.

CHEMICAL SOCIETY REVIEWS (2019)

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Article Chemistry, Physical

A nanostructured NiO/cubic SiC p-n heterojunction photoanode for enhanced solar water splitting

Jingxin Jian et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

A Bio-inspired Cu4O4 Cubane: Effective Molecular Catalysts for Electrocatalytic Water Oxidation in Aqueous Solution

Xin Jiang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Inorganic & Nuclear

A Tricopper(I) Complex Competent for O Atom Transfer, C-H Bond Activation, and Multiple O-2 Activation Steps

Brian J. Cook et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Mimicking the Key Functions of Photosystem II in Artificial Photosynthesis for Photoelectrocatalytic Water Splitting

Sheng Ye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Inorganic & Nuclear

Electrocatalytic Water Oxidation by an Unsymmetrical Di-Copper Complex

Qin-Qin Hu et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Electrocatalytic Water Oxidation by a Homogeneous Copper Catalyst Disfavors Single-Site Mechanisms

Sara J. Koepke et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand

Katherine J. Fisher et al.

ACS CATALYSIS (2017)

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Article Chemistry, Physical

Single Electron Transfer Steps in Water Oxidation Catalysis. Redefining the Mechanistic Scenario

Ignacio Funes-Ardoiz et al.

ACS CATALYSIS (2017)

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Article Chemistry, Multidisciplinary

Recent Progress in Energy-Driven Water Splitting

Si Yin Tee et al.

ADVANCED SCIENCE (2017)

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Article Chemistry, Multidisciplinary

Lowering water oxidation overpotentials using the ionisable imidazole of copper(2-(2'-pyridyl) imidazole)

Leea A. Stott et al.

CHEMICAL COMMUNICATIONS (2017)

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Review Chemistry, Multidisciplinary

Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity

Courtney E. Elwell et al.

CHEMICAL REVIEWS (2017)

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Article Chemistry, Multidisciplinary

In situ generated highly active copper oxide catalysts for the oxygen evolution reaction at low overpotential in alkaline solutions

Xiang Liu et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Multidisciplinary

Pyrolyzed cobalt porphyrin-based conjugated mesoporous polymers as bifunctional catalysts for hydrogen production and oxygen evolution in water

Hongxing Jia et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Multidisciplinary

Comparison of H-2 photogeneration by [FeFe]-hydrogenase mimics with CdSe QDs and Ru(bpy)(3)Cl-2 in aqueous solution

Jing-Xin Jian et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

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Article Chemistry, Physical

A nickel (II) PY5 complex as an electrocatalyst for water oxidation

Lei Wang et al.

JOURNAL OF CATALYSIS (2016)

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Review Chemistry, Multidisciplinary

Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities

Joan Serrano-Plana et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

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Review Chemistry, Multidisciplinary

Highly Efficient Bioinspired Molecular Ru Water Oxidation Catalysts with Negatively Charged Backbone Ligands

Lele Duan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

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Article Chemistry, Multidisciplinary

Electrocatalytic Water Oxidation by a Dinuclear Copper Complex in a Neutral Aqueous Solution

Xiao-Jun Su et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Article Chemistry, Multidisciplinary

Electrocatalytic water oxidation by CuII complexes with branched peptides

Jozsef S. Pap et al.

CHEMICAL COMMUNICATIONS (2015)

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Review Chemistry, Multidisciplinary

Molecular Catalysts for Water Oxidation

James D. Blakemore et al.

CHEMICAL REVIEWS (2015)

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Article Chemistry, Multidisciplinary

Redox Non-innocent Ligand Controls Water Oxidation Overpotential in a New Family of Mononuclear Cu-Based Efficient Catalysts

Pablo Garrido-Barros et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Multidisciplinary Sciences

Native structure of photosystem II at 1.95 angstrom resolution viewed by femtosecond X-ray pulses

Michihiro Suga et al.

NATURE (2015)

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Review Chemistry, Multidisciplinary

Enhancement of the Efficiency of Photocatalytic Reduction of Protons to Hydrogen via Molecular Assembly

Li-Zhu Wu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

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Article Chemistry, Multidisciplinary

Single-Site Copper(II) Water Oxidation Electrocatalysis: Rate Enhancements with HPO42- as a Proton Acceptor at pH 8

Michael K. Coggins et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Article Chemistry, Multidisciplinary

A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential

Teng Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Multidisciplinary

A mononuclear copper electrocatalyst for both water reduction and oxidation

Ling-Zhi Fu et al.

RSC ADVANCES (2014)

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Review Chemistry, Multidisciplinary

Structure-function analyses of solar fuels catalysts using in situ X-ray scattering

Karen L. Mulfort et al.

CHEMICAL SOCIETY REVIEWS (2013)

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Article Chemistry, Multidisciplinary

Electrocatalytic Water Oxidation with a Copper(II) Polypeptide Complex

Ming-Tian Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Multidisciplinary Sciences

Chitosan confinement enhances hydrogen photogeneration from a mimic of the diiron subsite of [FeFe]-hydrogenase

Jing-Xin Jian et al.

NATURE COMMUNICATIONS (2013)

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Article Chemistry, Multidisciplinary

A cobalt(II) quaterpyridine complex as a visible light-driven catalyst for both water oxidation and reduction

Chi-Fai Leung et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Article Chemistry, Multidisciplinary

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

Lele Duan et al.

NATURE CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

A soluble copper-bipyridine water-oxidation electrocatalyst

Shoshanna M. Barnett et al.

NATURE CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

Morphology effect on the luminescent property and antibacterial activity of coordination polymer particles with identical crystal structures

Kuaibing Wang et al.

CRYSTENGCOMM (2011)

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Article Chemistry, Inorganic & Nuclear

Anionic effects on the formation of tridentate 4′-chloro-2,2′:6′,2-terpyridine copper(II) complexes having 1:1 or 1:2 ratio of metal and ligand and their crystal symmetry

Wei Huang et al.

INORGANICA CHIMICA ACTA (2009)

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Review Chemistry, Multidisciplinary

O2 and N2O activation by bi-, tri-, and tetranuclear Cu clusters in biology

Edward I. Solomon et al.

ACCOUNTS OF CHEMICAL RESEARCH (2007)

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Review Chemistry, Multidisciplinary

Recent developments in the supramolecular chemistry of terpyridine-metal complexes

H Hofmeier et al.

CHEMICAL SOCIETY REVIEWS (2004)

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Solar-Driven Water Splitting in Photovoltaic Electrolysis Systems Using Copper Terpyridine Complexes as Oxygen Evolution Catalysts

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