期刊
ENERGY STORAGE MATERIALS
卷 55, 期 -, 页码 754-762出版社
ELSEVIER
DOI: 10.1016/j.ensm.2022.12.036
关键词
Zinc-ion microcapacitor; 3D network structure; manganese dioxide; MXene; Energy density
In this study, a flexible zinc ion microcapacitor (ZIMC) with a composite honeycomb three-dimensional (3D) network structure was creatively assembled using a low-cost blade-coating and foaming technique. The unique configuration of the electrodes provides a large specific surface area, more loading active materials, and fully exposed active sites, which facilitate the transport of electrons, ions, and electrolyte. Moreover, the composite honeycomb 3D network structure exhibits excellent mechanical properties and structural stability, making it highly promising for applications in wearable electronics.
The energy density and mechanical flexibility of the reported zinc ion microcapacitors (ZIMCs) require further improvement to meet the rapid development and modularization of miniaturized and self-powered electronic systems. Herein, a flexible ZIMC with composite honeycomb three-dimensional (3D) network structure was creatively assembled using a low-cost blade-coating and foaming technique. MnO2 and MXene uniformly coating onto this 3D network structure with in-plane open-holes were used as the cathode and anode, respectively. The unique configuration endows the electrodes with large specific surface area, more loading active materials and fully exposed active sites, which is conducive to electrons and ions transport and electrolyte penetration. And the specific capacitance of ZIMC can reach up to 264 mF cm (2), energy density with 132 mu Wh cm (2), power density with 1510 mu W cm (2). In addition, this composite honeycomb 3D network structure displays excellent mechanical property with tensile stress of 19.33 MPa and strain of 4.52%, which can buffer volume changes and enhance the structural stability of the device (the capacitance retention over 90% after 6700 cycles). Therefore, the development of electrode materials for ZIMC with this reliable and stable 3D network structure has great potential in the field of wearable electronics.
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