相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Article
Chemistry, Multidisciplinary
Guojin Liang et al.
Summary: The article introduces a method to solve the irreversibility issue of zinc metal anodes through a solution-dipping approach that constructs a protective coating. The synergistic combination of electric conductive coatings, insulating coatings, and 3D structural frameworks enables highly reversible zinc metal anode chemistry with suppressed gas production and dendrite growth.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Physical
Daliang Han et al.
Summary: By using a low-cost ammonium acetate (NH4OAc) additive, a self-regulated zinc/electrolyte interface is built to address the issues of rapid performance deterioration of zinc anodes. The additive induces a dynamic electrostatic shielding layer around the zinc protuberance, promoting uniform zinc deposition, and acts as an interfacial pH buffer to suppress side reactions and precipitation of insoluble by-products. These findings pave the way for practical zinc batteries.
ADVANCED ENERGY MATERIALS
(2022)
Article
Green & Sustainable Science & Technology
Daliang Han et al.
Summary: Aqueous zinc batteries are safer than lithium-ion batteries, but their anodes are susceptible to dendrite failure and side reactions. The authors demonstrate a low-cost electrolyte that involves hydrate salt and organic solvent, proving to be non-flammable. The zinc battery cell delivers excellent performance even at low temperatures of -30 degrees Celsius.
NATURE SUSTAINABILITY
(2022)
Article
Chemistry, Multidisciplinary
Xueyu Nie et al.
Summary: It is reported that introducing cholinium cations into aqueous electrolytes enables a compact and non-dendritic Zn electrode with excellent electrochemical performances. The bulky cholinium cations create a leveling effect to homogenize Zn deposition and disrupt the original H-bonded network of water, reducing side reactions and promoting Zn2+ de-solvation. The optimized electrolyte shows remarkable Coulombic efficiency and cycling stability in Zn batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Fangwang Ming et al.
Summary: This work proposes a hybrid electrolyte induced by the salting-in effect as an effective strategy to achieve a highly reversible zinc anode with good stability and compatibility. By altering the solvation structure and reducing parasitic side reactions, this electrolyte ensures a stable zinc anode with excellent cycling stability.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Hongpeng Li et al.
Summary: A hierarchical confinement strategy using porous Co-embedded carbon cages is proposed to address the kinetics and stability issues of Zn capture in aqueous batteries. This strategy enables dendrite-free behavior with excellent kinetics and stable cycle life, pushing forward the next-generation high-performance ZABs.
Article
Multidisciplinary Sciences
Canpeng Li et al.
Summary: An 'all-in-one' (AIO) electrode was developed by combining structural design, interface modification, and electrolyte optimization, which can effectively improve the stability and performance of zinc-ion batteries.
NATIONAL SCIENCE REVIEW
(2022)
Article
Multidisciplinary Sciences
Huan Yu et al.
Summary: We developed a three-dimensional hybrid fiber host for high-performance Zn metal batteries, which enables homogeneous Zn deposition on the interior and exterior surfaces of the hollow fibers.
Article
Chemistry, Physical
Guoqiang Ma et al.
Summary: In this study, the stability of metallic zinc anode in aqueous batteries was significantly improved by using a non-concentrated aqueous zinc trifluoromethanesulfonate electrolyte with 1,2-dimethoxyethane additive. The introduction of DME disrupted the original hydrogen-bond network of water and created a unique Zn2+-solvation structure, effectively suppressing water-induced side reactions. The in-situ formation of an organic-inorganic hybrid interphase on the zinc anode further prevented water penetration and dendrite growth. This novel electrolyte enabled the zinc anodes to achieve unprecedented cycling stability and high reversibility.
ENERGY STORAGE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Lin Ma et al.
Summary: Research shows that using methanol as an electrolyte solvent in rechargeable zinc metal batteries improves performance and stability, effectively solving issues in the battery, and has good cycle life at extreme temperatures.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Physical
Meijia Qiu et al.
Summary: This article introduces a method to improve the long-term reversible plating/stripping of zinc anodes by introducing sorbitol as an additive. The research found that sorbitol can promote the preferred (002) orientation growth on the zinc anode surface, which facilitates stable inversion of the zinc deposition. Additionally, sorbitol modulates the solvation structure of Zn2+ and reduces common side reactions. Experimental results demonstrate the excellent stability of the zinc anode in zinc-zinc symmetric cells and other types of full cells.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Kai Yang et al.
Summary: A triple-functional strategy is proposed to address the key challenges faced by aqueous Zn-ion batteries. By using a polyoxovanadate cluster as a Zn2+ host, the cathode, electrolyte, and metallic Zn anode can be simultaneously stabilized. The Zn//POV battery exhibits excellent cycling stability at high rates.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Wenjing Deng et al.
Summary: The study proposes a simple strategy to achieve high reversibility of metallic zinc in rechargeable batteries by introducing the organic solvent DMA as an electrolyte additive, which controls water activity, replaces water in Zn2+ solvation sheath, and reshapes the hydrogen-bonding network of water. This strategy enables remarkable suppression of water-involved hydrogen evolution and severe corrosion, leading to uniform deposition of zinc and long cycling life in batteries.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Guoqiang Ma et al.
Summary: A non-flammable, dilute, and hydrous organic electrolyte containing low-cost hydrated Zn(ClO4)2·6H2O dissolved in trimethyl phosphate (TMP) is reported in this study. It can stabilize the Zn anode and enhance the reversibility and electrochemical window of the battery. The Zn anode exhibits high efficiency, long-term cycling, and stable operation in this electrolyte.
Article
Electrochemistry
Ziqing Wang et al.
Summary: In this study, high-capacity and high-stability aqueous zinc-vanadium batteries were achieved by simultaneously regulating the ions in the electrolyte. Na+ cations suppressed cathode dissolution and restrained Zn dendrite growth, while ClO4- anions formed a protective layer to decrease Zn dendrites and H2 evolution. The battery exhibited durable performance during long-term cycling.
Article
Materials Science, Multidisciplinary
Yu Wang et al.
Summary: In this study, a hydrogen bond-anchored electrolyte is developed to limit water activity and expand the voltage window. The designed electrolyte suppresses the hydrogen evolution reaction and achieves stable performance in high-voltage aqueous batteries.
Article
Chemistry, Multidisciplinary
Junnan Hao et al.
Summary: A similar antisolvent strategy has been used to enhance Zn reversibility and suppress dendrite growth in Zn plating/stripping, with promising results shown in 50% methanol electrolyte. This low-cost strategy can be easily applied to other solvents, demonstrating practical universality and potential for enhancing performance in electrochemistry and energy storage research.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Xiaoxia Guo et al.
Summary: The study found that adding lithium chloride to the electrolyte can effectively suppress the formation of dendrites on the zinc anode, improving the stability and safety of the battery.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Xiaohui Zeng et al.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Vivek Verma et al.
Summary: Rechargeable zinc-ion batteries using ethylene glycol as the primary solvent show improved performance with expanded voltage stability windows, prolonged zinc stripping/plating stability, and increased cathode capacity retention compared to water-based counterparts. By investigating salt-solvent interactions at a molecular level, researchers provide insights into how chelation ability of ethylene glycol ligands reduces parasitic reactions and enhances electrochemical performances, offering guidelines for robust multivalent-ion battery systems.
CHEMISTRY OF MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Zhao Cai et al.
Summary: Metal anodes are a promising choice for high energy density rechargeable batteries, but face challenges like volume variation and side reactions. A novel interdigitated metal/solid electrolyte composite electrode was fabricated using a replacement reaction, providing a stable host structure and preventing side reactions. This design demonstrated stable electrochemical performance and low overpotential, outperforming other reported metal electrodes.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Cong Huang et al.
Summary: The research shows that saccharin (Sac) as an electrolyte additive can regulate the electrical double layer (EDL) structure on the zinc anode, forming a unique solid electrolyte interphase (SEI) that effectively modulates zinc deposition behavior and prevents side reactions, thus improving battery performance.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Huijun Yang et al.
Summary: The zeolite molecular sieve-modified aqueous electrolyte shows reduced water activity and side reactions, leading to improved performance at the electrolyte/electrode interface. This modification results in less hydrogen evolution and corrosion, as well as better cycle life and stability of the battery cells.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Xuan Qiu et al.
Summary: A new organic electrolyte containing zinc trifluoromethanesulfonate salt and a mixed solvent has been proposed for zinc batteries, which shows high ionic conductivity, wide potential window, and dendrite-free zinc plating/stripping. A 2 V zinc//polytriphenylamine composite battery fabricated with the optimized electrolyte exhibits high performance and long cycle life even with high mass-loading of PTPAn in the cathode and high zinc-utilization.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Multidisciplinary
Jiahao Liu et al.
Summary: This article focuses on constructing a theory-to-application methodology for aqueous sulfur-based batteries. Research reveals the complexity in the electrochemistry of aqueous sulfur-based batteries, which poses challenges and potential for future development. Further exploration in both theory and practice is needed for the future development direction.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Jin Han et al.
Summary: By developing an artificial ZnF2 layer on the surface of Zn metal anode, researchers have successfully addressed the limitation of zinc batteries' lifespan. This artificial layer suppresses dendrite growth and facilitates zinc insertion and transport through an interstitial diffusion mechanism. This improvement has been demonstrated by the long-term cycling and high capacity retention achieved by zinc-zincF2/MnO2 full cells.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Xinhua Zheng et al.
Summary: This review focuses on the problems and solutions in the Zn electrodeposition process in rechargeable zinc-ion batteries (ZIBs), aiming to provide practical strategies for the future development of stable ZIBs.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Shengli Di et al.
Summary: By pre-cycling Zn electrodes in an organic electrolyte, a stable organic-inorganic hybrid SEI layer can be formed on the Zn electrode, effectively reducing dendrite growth and water-induced side reactions in aqueous batteries, and improving the stability and lifespan of Zn electrodes.
ENERGY STORAGE MATERIALS
(2021)
Article
Electrochemistry
Xiulei Ji
Summary: Molten ZnCl2 hydrates are ionic liquids with intriguing physical and electrochemical properties, suitable for use as electrolytes in Zn metal batteries. Understanding the properties of molten ZnCl2 hydrates is crucial for designing high-performance electrolytes.
Article
Chemistry, Multidisciplinary
Yunpei Zhu et al.
Summary: High-concentration aqueous Zn2+ electrolyte using a supporting Na salt is efficient in addressing performance degradation issues in Zn-ion batteries without sacrificing power densities, cycling stability, and safety. A unique interphase formed on the Zn anode enables reversible and uniform Zn plating, while a cathode of sodium vanadate shows improved performance in a Zn-sodium vanadate battery with concentrated bi-cation electrolyte. This work offers new insights into electrolyte engineering for achieving high-performance aqueous batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Yuzhu Chu et al.
Summary: The in situ construction of a composite SEI mainly composed of Zn-3(PO4)(2) and ZnF2 (ZCS) effectively suppresses Zn dendrite growth and accelerates Zn2+ transference and deposition kinetics in aqueous Zn-ion batteries. By taking advantage of the instability of KPF6 in an aqueous environment, an in situ ZCS is successfully built on the Zn anode through a PF6- anion-induced chemical strategy, showing enhanced reversibility and excellent electrochemical performance. This work not only paves a new way for designing a desirable SEI on the Zn anode, but also may guide the interface engineering of other systems to overcome intrinsic defects in constructing favorable interphases.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Yang Dong et al.
Summary: This study presents a non-concentrated aqueous electrolyte composed of 2m zinc trifluoromethanesulfonate and the organic dimethyl carbonate additive, which can stabilize the zinc electrochemistry and improve the coulombic efficiency of the zinc anode. Furthermore, this electrolyte can sustain stable operation of rechargeable aqueous zinc batteries when paired with various cathode materials. Rational electrolyte design with organic solvent additives could lead to the development of better aqueous batteries.
Review
Multidisciplinary Sciences
Dongliang Chao et al.
Article
Chemistry, Multidisciplinary
Longsheng Cao et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Chemistry, Physical
Wuhai Yang et al.
Article
Chemistry, Multidisciplinary
Gang Liu et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Energy & Fuels
Lin Ma et al.
Article
Chemistry, Multidisciplinary
Longsheng Cao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Review
Chemistry, Multidisciplinary
Ning Zhang et al.
CHEMICAL SOCIETY REVIEWS
(2020)
Article
Chemistry, Physical
Yang Dong et al.
JOURNAL OF MATERIALS CHEMISTRY A
(2020)
Article
Chemistry, Multidisciplinary
Jaeho Shin et al.
Article
Chemistry, Multidisciplinary
Ahmad Naveed et al.
ADVANCED MATERIALS
(2019)
Article
Nanoscience & Nanotechnology
Ning Zhang et al.
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Multidisciplinary Sciences
Huayu Qiu et al.
NATURE COMMUNICATIONS
(2019)
Article
Chemistry, Multidisciplinary
Ahmad Naveed et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2019)
Review
Chemistry, Physical
Xiaohui Zeng et al.
ENERGY STORAGE MATERIALS
(2019)
Article
Chemistry, Physical
Fei Wang et al.
Article
Nanoscience & Nanotechnology
Sang-Don Han et al.
ACS APPLIED MATERIALS & INTERFACES
(2016)
