期刊
ACS OMEGA
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.2c04496
关键词
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资金
- Key Specialized Research and Development Breakthrough Program in Henan province [222102320088]
- Young Talent Enterprise Cooperative Innovation Team [32320399]
- National Natural Science Foundation of China [52174262]
- National Key R&D Program of China [2021 YFC2902604]
- Key Specialized Research and Development Breakthrough Program in Henan province [212102310378]
- Cultivation Project of Fundamental Research for Young Teachers in Zhengzhou University [JC21549022]
- Key Scientific Research Program Plan of Colleges and Universities in Henan Province [21B530007]
In this study, a Bi2O3/BiOCl heterojunction with high photocatalytic activity was constructed. However, the photocatalytic performance decreased after repeated testing. The adsorption of RhB molecules on the active sites of BBOC was identified as the cause of the decline. The spent BBOC can be reactivated through calcination, leading to the recovery of its high photocatalytic activity.
With the rapid development of industry, bismuth-based semiconductors have been widely used for the photocatalytic degradation of organic contaminants discharged into wastewater. Herein, a Bi2O3/BiOCl (BBOC) heterojunction was constructed with high photocatalytic activity toward Rhodamine B (RhB) in the first cycle of the photocatalysis test, while the photocatalytic performance was drastically reduced after repeated testing. The adsorbed RhB molecules occupying the facial active sites of BBOC contributed to the decline of photocatalytic activity. The spent BBOC can be reactivated by the decomposition of the adsorbed RhB and the introduction of oxygen vacancies during calcination under an air atmosphere. The BBOC thus recovered exhibited a superior apparent rate constant of 0.08087 min-1 compared with 0.05228 min-1 of pristine BBOC. This study provided an effective strategy to investigate the deactivation/activation mechanism of bismuth-based heterojunction photocatalysts.
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