期刊
JOURNAL OF ENERGY STORAGE
卷 56, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.est.2022.105994
关键词
Energy storage materials; Electrodeposition; Energy and power density; Asymmetric supercapacitor
资金
- Defence Research and Development Organisation (DRDO), Ministry of Defence, Government of India [DFTM/02/3111/M/01/JCBCAT/1288/D, GAP219012]
- Basic Science Research Program through the National Research Foundation (NRF) of Korea - Ministry of Education [NRF-2019R1I1A3A02059471]
The effect of transition metal ions on the preparation of bimetallic/reduced graphene oxide composites was studied, and the results showed that the crystal structure, morphology, and electrochemical performance of the composites were largely dependent on the host metal ions. An asymmetric supercapacitor device with high specific capacitance, energy density, and power density was fabricated using the synthesized composites.
Development of additive-free electrode material on conductive substrates is a cost-effective strategy and is essential for the fabrication of high-performance supercapacitor. Herein, the effect of transition metal ions on the preparation of bimetallic (Ni & Mn)/reduced graphene oxide (RGO) composites through multi-step electrodeposition technique was extensively analysed. Two different composites; nickel manganese oxide/RGO (NiMn-G/ NF) and manganese nickel oxyhydroxide/RGO (MnNi-G/NF) were synthesized through step-wise electrodeposition technique. The NiMn-G/NF and MnNi-G/NF were prepared through interchanging the source of host transition metal ions (Ni and Mn). Various physicochemical characterization techniques confirmed that the crystal structure as well as the morphology and electrochemical performance of the composites were largely dependent on the host metal ions. The formation of surface functional groups may play a key role in the electrochemical performance of supercapacitors. The MnNi-G/NF electrode showed high specific capacitance of similar to 1525 F g(-1) at 1.5 A g(-1) current density compared to NiMn-G/NF (similar to 1312.5 F g(-1)) and other synthesized electrode materials. An asymmetric supercapacitor (ASC) device was fabricated using MnNi-G/NF as positive and thermally-RGO as negative electrode materials. The fabricated device exhibited highest specific capacitance of similar to 173.3 F g 1 at 2 A g 1 current density and maximum energy density of similar to 54.1 Wh kg(-1) and power density of 9 kW kg(-1).
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