期刊
JOURNAL OF RARE EARTHS
卷 34, 期 3, 页码 276-282出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1002-0721(16)60025-X
关键词
CeO2-ZrO2; composite oxide; catalyst; preparation; characterization; performance; rare earths
资金
- National Natural Science Foundation of China [51474133, 21407084]
- Talent Incubation Funding of School of Materials and Metallurgy [2014CY012]
The electrocatalytic activity and stability of Pt/C catalyst modified by using CeO2-ZrO2 mixed oxides for the alcohols electrochemical oxidation as probes were investigated. The catalyst samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical properties were measured by a three electrode system on electrochemical workstation (IVIUM). The results showed that the presence of CeO2-ZrO2 might be associated with the presence of Pt, which indicated that possibly there was synergistic effect between CeO2-ZrO2 and Pt nanoparticles. The electrocatalytic activity and stability of Pt-MOx/C (M= Ce, Zr) for methanol and ethanol oxidation was better than that of Pt-CeO2/C, which was attributed to that CeO2-ZrO2 composited oxides enhanced oxygen mobility and promoted oxygen storage capacity (OSC). Furthermore, the best performance was found when the molar ratio of CeO2 to ZrO2 was 2: 1 for the oxidation of methanol and ethanol. The forward peak current density of Pt-MOx/C (M= Ce, Zr, Ce: Zr= 2: 1) towards the methanol electrooxidation was about 3.8 times that of Pt-CeO2/C. Pt-MOx/C (M= Ce, Zr) appeared to be a promising and less expensive methanol oxidation anode catalyst.
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